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Volume 42
Main Index

Issue 1


Nitrite Catalyzes Reductive Nitrosylation of the Water-Soluble Ferri-Heme Model FeIII(TPPS) to FeII(TPPS)(NO)
Bernadette O. Fernandez, Ivan M. Lorkovi, and Peter C. Ford
pp 2 - 4; DOI:
10.1021/ic020519r
PDF
Creating New Binding Sites in Ligands and Metal Complexes Using the Negishi Cross-Coupling Reaction
Yuan-Qing Fang, Matthew I. J. Polson, and Garry S. Hanan
pp 5 - 7; DOI:
10.1021/ic026043t
PDF
A Novel Nonlinear Optical Crystal for the IR Region: Noncentrosymmetrically Crystalline CsCdBr3 and Its Properties
Peng Ren, Jingui Qin, and Chuangtian Chen
pp 8 - 10; DOI:
10.1021/ic025813y
PDF
Synthesis and Reactions of Cubane-Type Iron-Sulfur-Phosphine Clusters, Including Soluble Clusters of Nuclearities 8 and 16
Hong-Cai Zhou and R. H. Holm
pp 11 - 21; DOI:
10.1021/ic020464t
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Correlations of Synthetic, Spectroscopic, Structural, and Speciation Studies in the Biologically Relevant Cobalt(II)-Citrate System: The Tale of the First Aqueous Dinuclear Cobalt(II)-Citrate Complex
N. Kotsakis, C. P. Raptopoulou, V. Tangoulis, A. Terzis, J. Giapintzakis, T. Jakusch, T. Kiss, and A. Salifoglou
pp 22 - 31; DOI:
10.1021/ic011272l
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Intrinsic Acid-Base Properties of Purine Derivatives in Aqueous Solution and Comparison of the Acidifying Effects of Platinum(II) Coordinated to N1 or N7: Acidifying Effects Are Reciprocal and the Proton "Outruns" Divalent Metal Ions
Rolf Griesser, Gunnar Kampf, Larisa E. Kapinos, Seiji Komeda, Bernhard Lippert, Jan Reedijk, and Helmut Sigel
pp 32 - 41; DOI:
10.1021/ic020535o
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Fe(III) Coordination Properties of a New Saccharide-Based Exocyclic Trihydroxamate Analogue of Ferrichrome
Suraj Dhungana, Susanne Heggemann, Peter Gebhardt, Ute Möllmann, and Alvin L. Crumbliss
pp 42 - 50; DOI:
10.1021/ic025647u
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Pendant Cyclodicarbaphosphazatriene-Containing Monomers and Polymers: Synthesis, Crystal Structures and Polymerization Behavior of [NC(NMe2)]2[NP(O-C6H4-p-C6H4-p-CH=CH2)(X)], X = Cl, OCH2CF3, OC6H5, OC6H4-m-CH3, OC6H4-p-Br
Vadapalli Chandrasekhar, Arunachalampillai Athimoolam, Narreddula Dastagiri Reddy, Selvarajan Nagendran, Alexander Steiner, Stefano Zacchini, and Raymond Butcher
pp 51 - 59; DOI:
10.1021/ic025940u
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"True" Inorganic Heterocycles: Structures and Stability of Group 13-15 Analogues of Benzene and Their Dimers
Alexey Y. Timoshkin and Gernot Frenking
pp 60 - 69; DOI:
10.1021/ic020361a
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Deprotonation of Zinc(II)-Water and Zinc(II)-Alcohol and Nucleophilicity of the Resultant Zinc(II) Hydroxide and Zinc(II) Alkoxide in Double-Functionalized Complexes: Theoretical Studies on Models for Hydrolytic Zinc Enzymes
Jiang Xia, Yan-bo Shi, Yong Zhang, Qiang Miao, and Wen-xia Tang
pp 70 - 77; DOI:
10.1021/ic020040z
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Kinetics and Mechanisms of S(IV) Reductions of Bromite and Chlorite Ions
Kara E. Huff Hartz, Jeffrey S. Nicoson, Lu Wang, and Dale W. Margerum
pp 78 - 87; DOI:
10.1021/ic020475m
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Synthesis, Separation, and Assignment of the Seven Geometric Isomers of [Co(dien)(ibn)Cl]2+
Tao Zhu and W. Gregory Jackson
pp 88 - 95; DOI:
10.1021/ic0202460
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Arene-Ruthenium Complexes of an Acyclic Thiolate-Thioether and Tridentate Thioether Derivatives Resulting from Ring-Closure Reactions
Richard Y. C. Shin, Martin A. Bennett, Lai Yoong Goh, Wei Chen, David C. R. Hockless, Weng Kee Leong, Kazushi Mashima, and Anthony C. Willis
pp 96 - 106; DOI:
10.1021/ic0203419
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Benzene Thermal Conversion to Nanocrystalline Indium Nitride from Sulfide at Low Temperature
Jianping Xiao, Yi Xie, Rui Tang, and Wei Luo
pp 107 - 111; DOI:
10.1021/ic0258330
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Synthesis and Spectroscopic Characterization of Silver(I) Complexes with the Bis(1,2,4-triazol-1-yl)alkane Ligand tz2(CH2). X-ray Structures of Two- and Three-Dimensional Coordination Polymers
Effendy, Fabio Marchetti, Claudio Pettinari, Riccardo Pettinari, Brian W. Skelton, and Allan H. White
pp 112 - 117; DOI:
10.1021/ic025981q
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Bond Valence Sums in Coordination Chemistry. The Calculation of the Oxidation State of Cerium in Complexes Containing Cerium Bonded Only to Oxygen
Petra L. Roulhac and Gus J. Palenik
pp 118 - 121; DOI:
10.1021/ic025980y
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Syntheses and Structures of Isoindoline Complexes of Zn(II) and Cu(II): An Unexpected Trinuclear Zn(II) Complex
Oren P. Anderson, Agnete la Cour, Andrew Dodd, Andrew D. Garrett, and Mark Wicholas
pp 122 - 127; DOI:
10.1021/ic011246n
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Self-Assembled Supramolecular M9 (Mn(II), Fe(III), Zn(II)), M5 (Fe(III)), and [M3]2 (Pb(II)) Complexes: Structural, Magnetic, and Mössbauer Properties
Laurence K. Thompson, Liang Zhao, Zhiqiang Xu, David O. Miller, and William M. Reiff
pp 128 - 139; DOI:
10.1021/ic020468y
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Light-Induced Metastable Linkage Isomers of Ruthenium Sulfur Dioxide Complexes
Andrey Yu. Kovalevsky, Kimberly A. Bagley, Jacqueline M. Cole, and Philip Coppens
pp 140 - 147; DOI:
10.1021/ic025997g
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Structural Variations Across the Lanthanide Series of Macrocyclic DOTA Complexes: Insights into the Design of Contrast Agents for Magnetic Resonance Imaging
F. Benetollo, G. Bombieri, L. Calabi, S. Aime, and M. Botta
pp 148 - 157; DOI:
10.1021/ic025790n
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Novel One-Dimensional Tubelike and Two-Dimensional Polycatenated Metal-Organic Frameworks
Jian Fan, Hui-Fang Zhu, Taka-aki Okamura, Wei-Yin Sun, Wen-Xia Tang, and Norikazu Ueyama
pp 158 - 162; DOI:
10.1021/ic020461g
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Formation of Racemate and Mesocate Complexes from an Achiral Tripodal Ligand Containing Three Benzimidazole Groups
Yue-Peng Cai, Cheng-Yong Su, Chun-Long Chen, Yue-Ming Li, Bei-Sheng Kang, Albert S. C. Chan, and Wolfgang Kaim
pp 163 - 168; DOI:
10.1021/ic025934y
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Syntheses, Crystal Structures, and Luminescent Properties of Lanthanide Complexes with Tripodal Ligands Bearing Benzimidazole and Pyridine Groups
Xiao-Ping Yang, Bei-Sheng Kang, Wai-Kwok Wong, Cheng-Yong Su, and Han-Qin Liu
pp 169 - 179; DOI:
10.1021/ic025799p
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Synthesis, Structure, and Magnetic Properties of [MnIII(salpn)NCS]n, a Helical Polymer, and the Dimer [MnIII(salpn)NCS]2. Weak Ferromagnetism in [MnIII(salpn)NCS]n Related to the Strong Magnetic Anisotropy in Jahn-Teller Mn(III) (salpnH2 = N,N'-Bis(salicylidene)-1,3-diaminopropane)
S. Sailaja, K. Rajender Reddy, M. V. Rajasekharan, C. Hureau, E. Rivière, J. Cano, and J.-J. Girerd
pp 180 - 186; DOI:
10.1021/ic0256617
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Trans Cis Isomerization of trans-[(dppm)2Ru(H)(L)][BF4] (L = P(OR)3) Complexes: Preparation of cis-[(dppm)2Ru(2-H2)(L)][BF4]2
Nisha Mathew, Balaji R. Jagirdar, and Anupama Ranganathan
pp 187 - 197; DOI:
10.1021/ic020082n
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Ruthenium Complexes of 2-[(4-(Arylamino)phenyl)azo]pyridine Formed via Regioselective Phenyl Ring Amination of Coordinated 2-(Phenylazo)pyridine: Isolation of Products, X-ray Structure, and Redox and Optical Properties
Chayan Das, Amrita Saha, Chen-Hsiung Hung, Gene-Hsiang Lee, Shie-Ming Peng, and Sreebrata Goswami
pp 198 - 204; DOI:
10.1021/ic0203724
PDF
Syntheses, Structures, and Characterization of New Lead(II)-Tellurium(IV)-Oxide Halides: Pb3Te2O6X2 and Pb3TeO4X2 (X = Cl or Br)
Yetta Porter and P. Shiv Halasyamani
pp 205 - 209; DOI:
10.1021/ic025750j
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Synthesis and Coordination Chemistry of the First C2-Chiral Bisoxazine Ligand
Clément Mazet and Lutz H. Gade
pp 210 - 215; DOI:
10.1021/ic025947b
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[Ni(Et2PCH2NMeCH2PEt2)2]2+ as a Functional Model for Hydrogenases
Calvin J. Curtis, Alex Miedaner, Rebecca Ciancanelli, William W. Ellis, Bruce C. Noll, M. Rakowski DuBois, and Daniel L. DuBois
pp 216 - 227; DOI:
10.1021/ic020610v
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Europium Ion Catalyzed Methanolysis of Esters at Neutral %@mt;sys@% %@mh;-%pxwidth@%%@sx@%%@bold@%s%@rsf@%%@be@%%@bold@%s%@rsf@%%@sxx@%%@mx@% pH and Ambient Temperature. Catalytic Involvement of Eu3+(CH3O-)(CH3OH)x
Alexei A. Neverov, Graham Gibson, and R. S. Brown
pp 228 - 234; DOI:
10.1021/ic0203769
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Different Oxidation States of Copper(I, I/II, II) Thiocyanate Complexes Containing 1,2,4-Triazole as a Bridging Ligand: Syntheses, Crystal Structures, and Magnetic Properties of 2-D Polymer CuI(admtrz)SCN, Linear Trinuclear [CuI2CuII(admtrz)6(SCN)2](ClO4)2, and Triangular Trinuclear [CuII3(admtrz)4(SCN)3(3-OH)(H2O)](ClO4)2·H2O (admtrz = 4-Amino-3,5-dimethyl-1,2,4-triazole)
Jia-Cheng Liu, Guo-Cong Guo, Jin-Shun Huang, and Xiao-Zeng You
pp 235 - 243; DOI:
10.1021/ic0258173
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Migratory Insertion of Hydrogen Isocyanide in the Pentacyano(methyl)cobaltate(III) Anion
Pauli Kofod, Pernille Harris, and Sine Larsen
pp 244 - 249; DOI:
10.1021/ic020353u
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Issue 2


A Novel Dinuclear Species in the Aqueous Distribution of Aluminum in the Presence of Citrate
Maria Dakanali, Catherine P. Raptopoulou, Aristidis Terzis, Andrea Lakatos, Istvan Banyai, Tamas Kiss, and Athanasios Salifoglou
pp 252 - 254; DOI:
10.1021/ic0258025
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NMR Evaluation of the Configurational Stability of Cu(I) Complexes
Valérie Desvergnes-Breuil, Virginie Hebbe, Christiane Dietrich-Buchecker, Jean-Pierre Sauvage, and Jérôme Lacour
pp 255 - 257; DOI:
10.1021/ic0259890
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Tantalizing Chemistry of the Half-Sandwich Silylhydride Complexes of Niobium: Identification of Likely Intermediates on the Way to Agostic Complexes
Georgii I. Nikonov, Philip Mountford, and Stuart R. Dubberley
pp 258 - 260; DOI:
10.1021/ic026017v
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Supramolecular Assembly of Trimeric Gold(I) Pyrazolates through Aurophilic Attractions
Guang Yang and Raphael G. Raptis
pp 261 - 263; DOI:
10.1021/ic026051+
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Tantalum Amido and Imido Complexes Supported by Tris[(2-indolyl)methyl]amine, a Tetradentate Trianionic Ligand with Reduced -Donor Character
Joseph M. Tanski and Gerard Parkin
pp 264 - 266; DOI:
10.1021/ic026182a
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The First Structurally Characterized Nonorganometallic Titanium(III) Alkoxo-Bridged Dinuclear Complexes
Józef Utko, Szymon Przybylak, Lucjan B. Jerzykiewicz, Krzysztof Mierzwicki, Zdzisaw Latajka, and Piotr Sobota
pp 267 - 269; DOI:
10.1021/ic020622g
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Selective One-Electron Reduction of Nitrosomonas europaea Hydroxylamine Oxidoreductase with Nitric Oxide
Maria Zulema Cabail and A. Andrew Pacheco
pp 270 - 272; DOI:
10.1021/ic025779n
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Intramolecular Excimer Formation in a Naphthalene-Appended Dinuclear Iron-Oxo Complex
Laura B. Picraux, Brandon T. Weldon, and James K. McCusker
pp 273 - 282; DOI:
10.1021/ic026054m
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"Stapled" Bis(phthalocyaninato)niobium(IV), Pc2Nb: X-ray Crystal Structure, Chemical and Electrochemical Behavior, and Theoretical Studies. Perspectives for the Use of Pc2Nb (Thin Films) as an "Optically Passive Electrode" in Electrochromic Devices
Elvira M. Bauer, Maria Pia Donzello, Claudio Ercolani, Enrico Masetti, Stefania Panero, Giampaolo Ricciardi, Angela Rosa, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 283 - 293; DOI:
10.1021/ic020098d
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Synthesis and Characterization of New Coordination Polymers Generated from Oxadiazole-Containing Organic Ligands and Inorganic Silver(I) Salts
Yu-Bin Dong, Jian-Ping Ma, Ru-Qi Huang, Mark D. Smith, and Hans-Conrad zur Loye
pp 294 - 300; DOI:
10.1021/ic0204225
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Platinum(IV)-Mediated Nitrile-Sulfimide Coupling: A Route to Heterodiazadienes
Anastassiya V. Makarycheva-Mikhailova, Nadezhda A. Bokach, Vadim Yu. Kukushkin, Paul F. Kelly, Liam M. Gilby, Maxim L. Kuznetsov, Kathryn E. Holmes, Matti Haukka, Jonathan Parr, Julia M. Stonehouse, Mark R. J. Elsegood, and Armando J. L. Pombeiro
pp 301 - 311; DOI:
10.1021/ic025960w
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Inner-Sphere Complexation of Cobalt(II) 2,9-Dimethyl-1,10-phenanthroline ([Co(neo)]2+) with Commercial and Sol-Gel Derived Silica Gel Surfaces
Colleen M. Taylor, Stephen P. Watton, Peter A. Bryngelson, and Michael J. Maroney
pp 312 - 320; DOI:
10.1021/ic025824r
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Monometallic and Dimetallic Ruthenium(II)-Terpyridine Complexes Employing the Tetradentate Ligands Dipyridylpyrazolyl, Dipyridyloxadiazole, and Their Dimethyl Derivatives
Vincent J. Catalano and Tegan J. Craig
pp 321 - 334; DOI:
10.1021/ic020489s
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Compositional and 2H NMR Studies of Bis(benzene)chromium Composites of Mesoporous Vanadium-Niobium Mixed Oxides
Xun He, Andy Y. H. Lo, Michel Trudeau, Robert W. Schurko, and David Antonelli
pp 335 - 347; DOI:
10.1021/ic020559v
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Ni(II), Cu(II), and Zn(II) Dinuclear Metal Complexes with an Aza-Phenolic Ligand: Crystal Structures, Magnetic Properties, and Solution Studies
Elisabetta Berti, Andrea Caneschi, Carole Daiguebonne, Paolo Dapporto, Mauro Formica, Vieri Fusi, Luca Giorgi, Annalisa Guerri, Mauro Micheloni, Paola Paoli, Roberto Pontellini, and Patrizia Rossi
pp 348 - 357; DOI:
10.1021/ic0204070
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(Arene)tricarbonylchromium Complexes Synthesized on NaX Zeolite: Solid-State NMR and DRIFTS Studies
William M. Shirley, Stanley P. Scoville, and Lawrence H. Merwin
pp 358 - 364; DOI:
10.1021/ic020512+
PDF
Spectroscopic Studies of the Effect of Ligand Donor Strength on the Fe-NO Bond in Intradiol Dioxygenases
Erik C. Wasinger, Mindy I. Davis, Monita Y. M. Pau, Allen M. Orville, Jeffrey M. Zaleski, Britt Hedman, John D. Lipscomb, Keith O. Hodgson, and Edward I. Solomon
pp 365 - 376; DOI:
10.1021/ic025906f
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Further Structural and Magnetic Studies of Tricopper Dipyridylamido Complexes
John F. Berry, F. Albert Cotton, Peng Lei, and Carlos A. Murillo
pp 377 - 382; DOI:
10.1021/ic025957c
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The First Oxygen-Bonded Sulfenate Ion: Crystal and Molecular Structures of Bis(ethylenediamine)(2-pyridinesulfenato-O)cobalt(III) and Bis(ethylenediamine)(2-pyridinesulfinato-O)cobalt(III)
W. G. Jackson, A. F. M. M. Rahman, and D. C. Craig
pp 383 - 388; DOI:
10.1021/ic020207o
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Reactions of Tris(amino)phosphines with Arylsulfonyl Azides: Product Dependency on Tris(amino)phosphine Structure
Natesan Thirupathi, Xiaodong Liu, and John G. Verkade
pp 389 - 397; DOI:
10.1021/ic025920s
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Nature of Copper(II)-Lanthanide(III) Magnetic Interactions and Generation of a Large Magnetic Moment with Magnetic Anisotropy of 3d-4f Cyclic Cylindrical Tetranuclear Complexes [CuIILLnIII(hfac)2]2, (H3L = 1-(2-Hydroxybenzamido)-2-(2-hydroxy-3-methoxybenzylideneamino)ethane and Hhfac = Hexafluoroacetylacetone, LnIII = Eu, Gd, Tb, Dy)
Takafumi Kido, Yuichi Ikuta, Yukinari Sunatsuki, Yoshihiro Ogawa, Naohide Matsumoto, and Nazzareno Re
pp 398 - 408; DOI:
10.1021/ic026045d
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Organically Templated Vanadyl Selenites with Layered Structures
Intyaj Pasha, Amitava Choudhury, and C. N. R. Rao
pp 409 - 415; DOI:
10.1021/ic020479r
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The (SO2)2N3- Anion
Karl O. Christe, Michael Gerken, Ralf Haiges, Stefan Schneider, Thorsten Schroer, Irena Tsyba, and Robert Bau
pp 416 - 419; DOI:
10.1021/ic0259078
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Configurational Stability of Chlorophosphines
Stéphane Humbel, Cyrille Bertrand, Christophe Darcel, Christophe Bauduin, and Sylvain Jugé
pp 420 - 427; DOI:
10.1021/ic026128u
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Synthesis, Crystal Structures, and Magnetic Properties of Three Novel Ferrocenecarboxylato-Bridged Lanthanide Dimers
Hongwei Hou, Gang Li, Linke Li, Yu Zhu, Xiangru Meng, and Yaoting Fan
pp 428 - 435; DOI:
10.1021/ic025753w
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Experimental and Theoretical Study of the Interaction of CO2 with -Al2O3
Maurizio Casarin, Daniele Falcomer, Antonella Glisenti, and Andrea Vittadini
pp 436 - 445; DOI:
10.1021/ic0257773
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Computational Study of the Non-Heme Iron Active Site in Superoxide Reductase and Its Reaction with Superoxide
Radu Silaghi-Dumitrescu, Ioan Silaghi-Dumitrescu, Eric D. Coulter, and Donald M. Kurtz, Jr.
pp 446 - 456; DOI:
10.1021/ic025684l
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Hydrothermal Preparation, Structures, and NLO Properties of the Rare Earth Molybdenyl Iodates, RE(MoO2)(IO3)4(OH) [RE = Nd, Sm, Eu]
Thomas C. Shehee, Richard E. Sykora, Kang M. Ok, P. Shiv Halasyamani, and Thomas E. Albrecht-Schmitt
pp 457 - 462; DOI:
10.1021/ic025992j
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Synthesis, Crystal Structure, and Magnetic Properties of an Alkoxo-Hydroxo-Bridged Octanuclear Copper(II) Complex Showing Chemically Significant Hydrogen-Bonding Interactions Involving a Metallamacrocyclic Core
Arindam Mukherjee, Indranil Rudra, Munirathinam Nethaji, Suryanarayanasastry Ramasesha, and Akhil R. Chakravarty
pp 463 - 468; DOI:
10.1021/ic020399n
PDF
Electronic Structure and Reactivity of High-Spin Iron-Alkyl- and -Pterinperoxo Complexes
Nicolai Lehnert, Kiyoshi Fujisawa, and Edward I. Solomon
pp 469 - 481; DOI:
10.1021/ic020496g
PDF
Supramolecular Assembly and Solution Properties of Bis(bipyridyl)ruthenium(II) Coordination Complexes of Aryl(2-pyridyl)methanones
Daniel L. Reger, James R. Gardinier, Mark D. Smith, and Perry J. Pellechia
pp 482 - 491; DOI:
10.1021/ic026018n
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Regioselective Cleavage of Myoglobin with Copper(II) Compounds at Neutral pH
Lin Zhang, Yuhua Mei, Yu Zhang, Shuan Li, Xiaojuan Sun, and Longgen Zhu
pp 492 - 498; DOI:
10.1021/ic025619b
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Hydrolysis of Phosphodiesters by Diiron Complexes: Design of Nonequivalent Iron Sites in Purple Acid Phosphatase Models
François Verge, Colette Lebrun, Marc Fontecave, and Stéphane Ménage
pp 499 - 507; DOI:
10.1021/ic025866f
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Kinetic Study of the Effects of Inhibitors on the Catalyzed Dehydration of HCO3- by Copper(II) Complexes [TpPh]CuX (X- = OH-, N3-, NCS-)
Ying-Ji Sun, Lei Z. Zhang, Peng Cheng, Hua-Kuan Lin, Shi-Ping Yan, Wei Sun, Dai-Zheng Liao, Zong-Hui Jiang, and Pan-Wen Shen
pp 508 - 515; DOI:
10.1021/ic025926h
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Coordination Chemistry of the Water-Soluble Ligand TPPTP and Formation of a [Mo(CO)5(m-TPPTP)] Monolayer on an Alumina Surface
Brandy A. Harper, D. Andrew Knight, Clifford George, Susan L. Brandow, Walter J. Dressick, Charles S. Dalcey, and Terence L. Schull
pp 516 - 524; DOI:
10.1021/ic025862a
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Experimental and Theoretical Investigations of Lithium and Magnesium Derivatives of Bis(tert-butylamido)cyclodiphosph(III/V)- and (V/V)azane Mono- and Ditellurides
Glen G. Briand, Tristram Chivers, Masood Parvez, and Gabriele Schatte
pp 525 - 531; DOI:
10.1021/ic020562e
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Electronic Structures and Nonlinear Optical Properties of Trinuclear Transition Metal Clusters M-(-S)-M' (M = Mo, W; M' = Cu, Ag, Au)
Xihua Chen, Kechen Wu, Jaap G. Snijders, and Chensheng Lin
pp 532 - 540; DOI:
10.1021/ic025649e
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Molecular, 1D, and 2D Systems Built from Phenylcyanamido Ligands. Syntheses, Crystal Structures, and Characterization of Their Magnetic Properties
Albert Escuer, Núria Sanz, Ramon Vicente, and Franz A. Mautner
pp 541 - 551; DOI:
10.1021/ic025931l
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From Metallacyclophanes to 1-D Coordination Polymers: Role of Anions in Self-Assembly Processes of Copper(II) and 2,5-Bis(3-pyridyl)-1,3,4-oxadiazole
Miao Du, Xian-He Bu, Zheng Huang, Shen-Tan Chen, Ya-Mei Guo, Carmen Diaz, and Joan Ribas
pp 552 - 559; DOI:
10.1021/ic025851h
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Aurophilicity-Coordination Interplay in the Design of Cyano-Bridged Nickel(II)-Gold(I) Bimetallic Assemblies: Structural and Computational Studies of the Gold(I)-Gold(I) Interactions
Enrique Colacio, Francesc Lloret, Raikko Kivekäs, José Suárez-Varela, Markku R. Sundberg, and Rolf Uggla
pp 560 - 565; DOI:
10.1021/ic025949w
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Optically Active 4- and 5-Coordinate Transition Metal Complexes of Bifurcated Dipeptide Schiff Bases
Robin Polt, Brian D. Kelly, Brian D. Dangel, Udaya Bhaskar Tadikonda, Regina E. Ross, Arnold M. Raitsimring, and Andrei V. Astashkin
pp 566 - 574; DOI:
10.1021/ic025996o
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Activation Parameters for the Reactive Intermediates Relevant to Carbonylation Catalysts Based on Cobalt Carbonyls1
Steve M. Massick, Torsten Büttner, and Peter C. Ford
pp 575 - 580; DOI:
10.1021/ic020567b
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Carbon Dioxide/Epoxide Coupling Reactions Utilizing Lewis Base Adducts of Zinc Halides as Catalysts. Cyclic Carbonate versus Polycarbonate Production
Donald J. Darensbourg, Samuel J. Lewis, Jody L. Rodgers, and Jason C. Yarbrough
pp 581 - 589; DOI:
10.1021/ic0259641
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The Electronic Structure and Spectrum of Mo(CN)83-
M. F. A. Hendrickx, L. F. Chibotaru, and A. Ceulemans
pp 590 - 597; DOI:
10.1021/ic0258734
PDF
Synthesis, Structural and Spectroscopic Properties of Two New Ethylenediamine-Templated Gallophosphate-Oxalate Layered Materials
Maja Mrak, Uwe Kolitsch, Christian Lengauer, Veneslav Kaui, and Ekkehart Tillmanns
pp 598 - 604; DOI:
10.1021/ic025663r
PDF
Tuning the Properties of the Osmium Nitrido Group in TpOs(N)X2 by Changing the Ancillary Ligand
Ahmad Dehestani, Werner Kaminsky, and James M. Mayer
pp 605 - 611; DOI:
10.1021/ic0260264
PDF
A Guest-Induced Assembly of a Molecular Box from Methylcobaloxime and 1, 4-Phenylenebisboronic Acid
Renata Dreos, Giorgio Nardin, Lucio Randaccio, Patrizia Siega, and Giovanni Tauzher
pp 612 - 617; DOI:
10.1021/ic025909s
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Kinetics and Mechanism of the Cobalt Phthalocyanine Catalyzed Reduction of Nitrite and Nitrate by Dithionite in Aqueous Solution
Evgeny V. Kudrik, Sergei V. Makarov, Achim Zahl, and Rudi van Eldik
pp 618 - 624; DOI:
10.1021/ic020290f
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Metal Complexes with 2,3-Bis(diphenylphosphino)-1,4-diazadiene Ligands: Synthesis, Structures, and an Intramolecular Metal-Mediated [4 + 2] Cycloaddition Employing a Benzene Ring as a Dienophile
Dirk Walther, Stefan Liesicke, Lars Böttcher, Reinald Fischer, Helmar Görls, and Gavin Vaughan
pp 625 - 632; DOI:
10.1021/ic020534w
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Syntheses, Structures, and Electronic Interactions of Dicyanamide/Tricyanomethanide-Bridged Binuclear Organometallic Complexes
Li-Yi Zhang, Lin-Xi Shi, and Zhong-Ning Chen
pp 633 - 640; DOI:
10.1021/ic025879t
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Synthesis and Characterization of Heterodinuclear Ln3+-Fe3+ and Ln3+-Co3+ Complexes, Bridged by Cyanide Ligand (Ln3+ = Lanthanide Ions). Nature of the Magnetic Interaction in the Ln3+-Fe3+ Complexes
Albert Figuerola, Carmen Diaz, Joan Ribas, Vassilis Tangoulis, Jaume Granell, Francesc Lloret, José Mahía, and Miguel Maestro
pp 641 - 649; DOI:
10.1021/ic025669g
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2.4 Å Crystal Structure of an Oxaliplatin 1,2-d(GpG) Intrastrand Cross-Link in a DNA Dodecamer Duplex
Bernhard Spingler, Douglas A. Whittington, and Stephen J.Lippard:
pp 650 - 650; DOI:
10.1021/ic020708+
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Issue 3


Hierarchical Assembly of Homochiral Porous Solids Using Coordination and Hydrogen Bonds
Yong Cui, Helen L. Ngo, Peter S. White, and Wenbin Lin
pp 652 - 654; DOI:
10.1021/ic025932d
PDF
The Fascinating Noncentrosymmetric Copper(II) Phosphates Synthesized via CsCl Salt-Inclusion
Qun Huang and Shiou-Jyh Hwu
pp 655 - 657; DOI:
10.1021/ic026060i
PDF
Toward an Arsenic Analogue of Hittorf's Phosphorus: Mixed Pnicogen Chains in Cu2P1.8As1.2I2
Buddhimathie Jayasekera, Jennifer A. Aitken, Mary Jane Heeg, and Stephanie L. Brock
pp 658 - 660; DOI:
10.1021/ic0258936
PDF
Isolation of the Novel Dirhodium(II/II) Thiolate Compound Rh2(1-C6H5S)2(-C6H5S)2(bpy)2
Karn Sorasaenee, José Ramón Galán-Mascarós, and Kim R. Dunbar
pp 661 - 663; DOI:
10.1021/ic020630x
PDF
Molecular Motions in the Solid State: the Thermochromic Nitro-Nitrito Interconversion in Nickel(II) Bis(diamine) Complexes
Marta Ansa Hortalá, Luigi Fabbrizzi, Francesco Foti, Maurizio Licchelli, Antonio Poggi, and Michele Zema
pp 664 - 666; DOI:
10.1021/ic026085h
PDF
Novel Double Insertion of Carbon Disulfide into Two Ru-H Bonds of [(dppm)2Ru(H)2] (dppm = Ph2PCH2PPh2): Synthesis and Crystal Structure of a Methanedithiolate Complex
Thirumanavelan Gandhi, Munirathinam Nethaji, and Balaji R. Jagirdar
pp 667 - 669; DOI:
10.1021/ic0260320
PDF
The First Structurally Confirmed Paddlewheel Compound with an M27+ Core: [Os2(hpp)4Cl2](PF6)
F. Albert Cotton, Naresh S. Dalal, Penglin Huang, Carlos A. Murillo, Ashley C. Stowe, and Xiaoping Wang
pp 670 - 672; DOI:
10.1021/ic026250t
PDF
Synthesis and Crystal Structure of Unprecedented Phosphine Adducts of d1-Aryl Imido-Vanadium(IV) Complexes
Christian Lorber, Robert Choukroun, and Bruno Donnadieu
pp 673 - 675; DOI:
10.1021/ic026089m
PDF
A New Metal-Organic Open Framework Consisting of Threefold Parallel Interwoven (6,3) Nets
Myunghyun Paik Suh, Hye Jin Choi, Soon Mog So, and B. Moon Kim
pp 676 - 678; DOI:
10.1021/ic025983a
PDF
Electronic Structure Contributions to Electron-Transfer Reactivity in Iron-Sulfur Active Sites: 1. Photoelectron Spectroscopic Determination of Electronic Relaxation
Pierre Kennepohl and Edward I. Solomon
pp 679 - 688; DOI:
10.1021/ic020330f
PDF
Electronic Structure Contributions to Electron-Transfer Reactivity in Iron-Sulfur Active Sites: 2. Reduction Potentials
Pierre Kennepohl and Edward I. Solomon
pp 689 - 695; DOI:
10.1021/ic0203318
PDF
Electronic Structure Contributions to Electron-Transfer Reactivity in Iron-Sulfur Active Sites: 3. Kinetics of Electron Transfer
Pierre Kennepohl and Edward I. Solomon
pp 696 - 708; DOI:
10.1021/ic0203320
PDF
Magneto-Structural Correlations in 2D and 3D Extended Structures of Manganese(II)-Malonate Systems
Tapas Kumar Maji, Saugata Sain, Golam Mostafa, Tian-Huey Lu, Joan Ribas, Montserrat Monfort, and Nirmalendu Ray Chaudhuri
pp 709 - 716; DOI:
10.1021/ic020238j
PDF
Structural and Spectroscopic Studies of Nickel(II) Complexes with a Library of Bis(oxime)amine-Containing Ligands
Michael J. Goldcamp, Sara E. Edison, Leah N. Squires, Dell T. Rosa, Neil K. Vowels, Nathan L. Coker, Jeanette A. Krause Bauer, and Michael J. Baldwin
pp 717 - 728; DOI:
10.1021/ic025860q
PDF
Thallium -Cation Complexation by Calix[4]tubes: 205Tl NMR and X-ray Evidence
Susan E. Matthews, Nicholas H. Rees, Vitor Felix, Michael G. B. Drew, and Paul D. Beer
pp 729 - 734; DOI:
10.1021/ic025884x
PDF
Investigation of the Extraction Complexes of Light Lanthanides(III) with Bis(2,4,4-trimethylpentyl)dithiophosphinic Acid by EXAFS, IR, and MS in Comparison with the Americium(III) Complex
Tian Guoxin, Zhu Yongjun, Xu Jingming, Zhang Ping, Hu Tiandou, Xie Yaning, and Zhang Jing
pp 735 - 741; DOI:
10.1021/ic025783z
PDF
Solution-State and Solid-State Structural Characterization of Complexes of a New Macrocyclic Ligand Containing the 1,5-Diazacyclooctane Subunit
Chuanjiang Hu, Thoi D. Nguyen, Paul S. Wagenknecht, and Lawrence C. Nathan
pp 742 - 749; DOI:
10.1021/ic020495o
PDF
Binuclear Manganese Compounds of Potential Biological Significance. 1. Syntheses and Structural, Magnetic, and Electrochemical Properties of Dimanganese(II) and -(II,III) Complexes of a Bridging Unsymmetrical Phenolate Ligand
Lionel Dubois, Dao-Feng Xiang, Xian-Shi Tan, Jacques Pécaut, Peter Jones, Stéphane Baudron, Laurent Le Pape, Jean-Marc Latour, Carole Baffert, Sylvie Chardon-Noblat, Marie-Noëlle Collomb, and Alain Deronzier
pp 750 - 760; DOI:
10.1021/ic020354m
PDF
Synthesis, Crystal Structure, and Magnetic Properties of {[Cu(oxbe)]Mn(H2O)[Cu(oxbe)(DMF)]}n·nDMF·nH2O: From Dissymmetrical Mononuclear Entities to a 3D Heterometallic Supramolecular Coordination Polymer
Shuang-Quan Zang, Ruo-Jie Tao, Qing-Lun Wang, Ning-Hai Hu, Yan-Xiang Cheng, Jing-Yang Niu, and Dai-Zheng Liao
pp 761 - 766; DOI:
10.1021/ic020491j
PDF
Structure and Reactivity of a Chromium(V) Glutathione Complex1
Aviva Levina, Lianbo Zhang, and Peter A. Lay
pp 767 - 784; DOI:
10.1021/ic020621o
PDF
Ruthenium(II) Complexes Containing 8-(Dimethylphosphino)quinoline (Me2Pqn): Preparation, Crystal Structures, and Electrochemical and Spectroscopic Properties of [Ru(bpy or phen)3-n(Me2Pqn)n](PF6)2 (bpy = 2,2'-Bipyridine; phen = 1,10-Phenanthroline; n = 1, 2, or 3)
Takayoshi Suzuki, Takashi Kuchiyama, Shinobu Kishi, Sumio Kaizaki, Hideo D. Takagi, and Masako Kato
pp 785 - 795; DOI:
10.1021/ic020344l
PDF
Synthesis and Reactions of Molybdenum Triamidoamine Complexes Containing Hexaisopropylterphenyl Substituents
Dmitry V. Yandulov, Richard R. Schrock, Arnold L. Rheingold, Christopher Ceccarelli, and William M. Davis
pp 796 - 813; DOI:
10.1021/ic020505l
PDF
Peripheral Metal-Ion Binding to Tris(thia-oxo crown) Porphyrazines
Sarah L. J. Michel, Anthony G. M. Barrett, and Brian M. Hoffman
pp 814 - 820; DOI:
10.1021/ic025639d
PDF
New Heterometallic Coordination Polymers Self-Assembled from Copper(II) Nitrate and (Diamine)PtII(pyridinecarboxylates)2
Rita Song, Kwan Mook Kim, and Youn Soo Sohn
pp 821 - 826; DOI:
10.1021/ic0204777
PDF
The Effect of a 3-Benzyl Group on the Coordination Chemistry of Homoscorpionate Ligands
Arnold L. Rheingold, Lev. N. Zakharov, and Swiatoslaw Trofimenko
pp 827 - 833; DOI:
10.1021/ic0205280
PDF
Factors Affecting the Electrochemical and Spectroelectrochemical Properties of Diruthenium(III,II) Complexes Containing Four Identical Unsymmetrical Bridging Ligands
Karl M. Kadish, Li-Lun Wang, Antoine Thuriere, Eric Van Caemelbecke, and John L. Bear
pp 834 - 843; DOI:
10.1021/ic020590x
PDF
Subtle Role of Polyatomic Anions in Molecular Construction: Structures and Properties of AgX Bearing 2,4'-Thiobis(pyridine) (X- = NO3-, BF4-, ClO4-, PF6-, CF3CO2-, and CF3SO3-)
Ok-Sang Jung, Yun Ju Kim, Young-A Lee, Ki-Min Park, and Shim Sung Lee
pp 844 - 850; DOI:
10.1021/ic025935q
PDF
Theoretical Study of Mixed MLaX4 (M = Na, K, Cs; X = F, Cl, Br, I) Rare Earth/Alkali Metal Halide Complexes
Cornelis Petrus Groen, Ad Oskam, and Attila Kovács
pp 851 - 858; DOI:
10.1021/ic0260973
PDF
Spectroscopic and Computational Studies of a Ni+-CO Model Complex: Implications for the Acetyl-CoA Synthase Catalytic Mechanism
Jennifer L. Craft, Beaven S. Mandimutsira, Koyu Fujita, Charles G. Riordan, and Thomas C. Brunold
pp 859 - 867; DOI:
10.1021/ic020441e
PDF
Century-Known Copper Salt Cu(OAc)(OMe) Proven To Be a Unique Magnetic Lattice Composed of Tetranuclear Copper(II) Species with a Rare Binding Mode of the Acetate Anion
Iryna A. Koval, Patrick Gamez, Olivier Roubeau, Willem L. Driessen, Martin Lutz, Anthony L. Spek, and Jan Reedijk
pp 868 - 872; DOI:
10.1021/ic026034k
PDF
Synthesis and Characterization of Chiral Tetraaza Macrocyclic Nickel(II) and Palladium(II) Complexes
Guodong Du, Arkady Ellern, and L. Keith Woo
pp 873 - 877; DOI:
10.1021/ic025818v
PDF
Stabilization of Duplex DNA Structure and Suppression of Transcription in Vitro by Bis(quinone diimine) Complexes of Rhodium(III) and Ruthenium(II)
Patty K.-L. Fu, Patricia M. Bradley, and Claudia Turro
pp 878 - 884; DOI:
10.1021/ic020338p
PDF
Five Different Fluxional Processes in Polyfluorophenyl Palladium(II) Complexes with 2,4,6-Tris(3,5-dimethylpyrazol-1-yl)-1,3,5-triazine. The Driving Effect of the Solvent
M. Carmen Carrión, Ana Guerrero, Félix A. Jalón, Blanca R. Manzano, Antonio de la Hoz, Rosa M. Claramunt, Viktor Milata, and José Elguero
pp 885 - 895; DOI:
10.1021/ic020522a
PDF
A Route to 1,2,4-Oxadiazoles and Their Complexes via Platinum-Mediated 1,3-Dipolar Cycloaddition of Nitrile Oxides to Organonitriles
Nadezhda A. Bokach, Anatolii V. Khripoun, Vadim Yu. Kukushkin, Matti Haukka, and Armando J. L. Pombeiro
pp 896 - 903; DOI:
10.1021/ic026103v
PDF
Synthesis and Characterization of Transition-Metal Zintl Phases: K10NbInAs6 and K9Nb2As6
Franck Gascoin and Slavi C. Sevov
pp 904 - 907; DOI:
10.1021/ic020557a
PDF
Hydrothermal Syntheses and Crystal Structures of Complex-Linked Three-Dimensional Coordination Vanadium Selenites: M(4,4'-bipy)(H2O)V2Se2O10 (M = Co, Ni)
Zhimin Dai, Xiaobo Chen, Zhan Shi, Dong Zhang, Guanghua Li, and Shouhua Feng
pp 908 - 912; DOI:
10.1021/ic026037x
PDF
Synthesis, Crystal Structures, and Third-Order Nonlinear Optical Properties of a Series of Ferrocenyl Organometallics
Gang Li, Yinglin Song, Hongwei Hou, Linke Li, Yaoting Fan, Yu Zhu, Xiangru Meng, and Liwei Mi
pp 913 - 920; DOI:
10.1021/ic0258633
PDF
Large-Scale Synthesis of Tungsten Oxide Nanowires with High Aspect Ratio
Xiao-Lin Li, Jun-Feng Liu, and Ya-Dong Li
pp 921 - 924; DOI:
10.1021/ic025955s
PDF

Issue 4


Infrared Activity of Symmetric Bridging Ligand Modes in Pyrazine-Bridged Hexaruthenium Mixed-Valence Clusters
Casey H. Londergan, J. Catherine Salsman, Silvia Ronco, and Clifford P. Kubiak
pp 926 - 928; DOI:
10.1021/ic0261629
PDF
A Mono-Diazenide Complex from Perrhenate: Toward a New Core for Rhenium Radiopharmaceuticals
Andrew R. Cowley, Jonathan R. Dilworth, and Paul S. Donnelly
pp 929 - 931; DOI:
10.1021/ic025995w
PDF
Perfluoroalkyl-Substituted Triazapentadienes and Their Metal Complexes
A. R. Siedle, Robert J. Webb, Fred E. Behr, Richard A. Newmark, David A. Weil, Kristin Erickson, Roberta Naujok, Myles Brostrom, Mark Mueller, Shih-Hung Chou, and Victor G. Young, Jr.
pp 932 - 934; DOI:
10.1021/ic020550t
PDF
Photochromic Isomerization of a Dinuclear Molybdenum Complex with Ethylene-1,2-Dithiolate and Disulfur Ligands: X-ray Structures of the Two Isomers
Takashi Shibahara, Masanobu Tsuboi, Shinsuke Nakaoka, and Yasuhiro Ide
pp 935 - 937; DOI:
10.1021/ic020380k
PDF
Formation of a Stable Cyano-Bridged Dinuclear Iron Cluster Following Oxidation of the Superoxide Reductases from Treponema pallidum and Desulfovibrio vulgaris with K3Fe(CN)6
Françoise Auchère, Patrícia Raleiras, Linda Benson, Sergei Yu. Venyaminov, Pedro Tavares, José J. G. Moura, Isabel Moura, and Frank Rusnak
pp 938 - 940; DOI:
10.1021/ic0262886
PDF
Unprecedented Reactivity of the Bridged Borylene Complexes [-BCl{(5-C5H4Me)Mn(CO)2}2] toward Pyridine
Holger Braunschweig, Miriam Colling, and Chunhua Hu
pp 941 - 943; DOI:
10.1021/ic0262738
PDF
Photoluminescent Metal-Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates
Wei Chen, Jia-Yu Wang, Cheng Chen, Qi Yue, Hong-Ming Yuan, Jie-Sheng Chen, and Su-Ning Wang
pp 944 - 946; DOI:
10.1021/ic025871j
PDF
Crystal Growth of Novel Osmium-Containing Triple Perovskites
Katharine E. Stitzer, Ahmed El Abed, Mark D. Smith, Matthew J. Davis, Seung-Joo Kim, Jacques Darriet, and Hans-Conrad zur Loye
pp 947 - 949; DOI:
10.1021/ic026124p
PDF
Synthesis and Characterization of Rhenium(V) Oxo Complexes with N-[N-(3-Diphenylphosphinopropionyl)glycyl]cysteine Methyl Ester. X-ray Crystal Structure of {ReO[Ph2P(CH2)2C(O)-Gly-Cys-OMe(P,N,N,S)]}
Roberta Visentin, Raffaella Rossin, Maria Cecilia Giron, Alessandro Dolmella, Giuliano Bandoli, and Ulderico Mazzi
pp 950 - 959; DOI:
10.1021/ic025859r
PDF
Water Displacement by Cyanogold Complexes in Binuclear Nickel(II) Compounds Based on Bridging Oxalate. Synthesis, Structural Diversity, Magnetic Properties, and DFT Calculations
Pablo Vitoria, Iñaki Muga, Juan M. Gutiérrez-Zorrilla, Antonio Luque, Pascual Román, Luis Lezama, F. Javier Zúniga, and Javier I. Beitia
pp 960 - 969; DOI:
10.1021/ic0203217
PDF
Synthesis and X-ray Crystal Structure of [(THF)Zn(O2(OH)SiR)]4 (R = (2,6-i-Pr2C6H3)N(SiMe3)): Enroute to Larger Aggregates
Ganapathi Anantharaman, Herbert W. Roesky, Hans-Georg Schmidt, Mathias Noltemeyer, and Jiri Pinkas
pp 970 - 973; DOI:
10.1021/ic020514u
PDF
A Complete Family of Isostructural Cluster Compounds with Cubane-like M3S4M' Cores (M = Mo, W; M' = Ni, Pd, Pt): Comparative Crystallography and Electrochemistry
Konrad Herbst, Piero Zanello, Maddalena Corsini, Nicola D'Amelio, Lutz Dahlenburg, and Michael Brorson
pp 974 - 981; DOI:
10.1021/ic0205379
PDF
A High-Pressure Iron K-Edge X-ray Absorption Spectral Study of the Spin-State Crossover in {Fe[HC(3,5-(CH3)2pz)3]2}I2 and {Fe[HC(3,5-(CH3)2pz)3]2}(BF4)2
Cristina Piquer, Fernande Grandjean, Olivier Mathon, Sakura Pascarelli, Daniel L. Reger, Christine A. Little, and Gary J. Long
pp 982 - 985; DOI:
10.1021/ic0204530
PDF
Structural and Physical Properties of the Ferromagnetic Tris-Dithiooxalato Compounds, A[MIICrIII(C2S2O2)3], with A+ = N(n-CnH2n+1)4+ (n = 3-5) and P(C6H5)4+ and MII = Mn, Fe, Co, and Ni
Justin M. Bradley, Simon G. Carling, Dirk Visser, Peter Day, Dimitri Hautot, and Gary J. Long
pp 986 - 996; DOI:
10.1021/ic020302x
PDF
Ground-State Stability and Rotational Activation Parameters for Individual Rotamers of (R,S,S,R)-(N,N'-Dimethyl-2,3-diaminobutane)PtG2 Complexes (G = 9-EtG, 3'-GMP, and 5'-GMP)
Gianpiero Colonna, Nicola G. Di Masi, Luigi G. Marzilli, and Giovanni Natile
pp 997 - 1005; DOI:
10.1021/ic020506d
PDF
31P NMR Spectroscopy as a Powerful Tool for the Determination of Enantiomeric Excess and Absolute Configurations of -Amino Acids
Judith Bravo, Carlos Cativiela, Julio E. Chaves, Rafael Navarro, and Esteban P. Urriolabeitia
pp 1006 - 1013; DOI:
10.1021/ic0204878
PDF
Aqueous Synthesis of Derivatized Cyclopentadienyl Complexes of Technetium and Rhenium Directed toward Radiopharmaceutical Application
Jonathan Bernard, Kirstin Ortner, Bernhard Spingler, H.-J. Pietzsch, and Roger Alberto
pp 1014 - 1022; DOI:
10.1021/ic0204575
PDF
A New Zinc(II) Fluorophore 2-(9-Anthrylmethylamino)ethyl-Appended 1,4,7,10-Tetraazacyclododecane
Shin Aoki, Saori Kaido, Haruto Fujioka, and Eiichi Kimura
pp 1023 - 1030; DOI:
10.1021/ic020545p
PDF
Electrochemical and Spectroelectrochemical Studies on UO2(saloph)L (saloph = N,N'-Disalicylidene-o-phenylenediaminate, L = Dimethyl Sulfoxide or N,N-Dimethylformamide)
Koichiro Mizuoka, Seong-Yun Kim, Miki Hasegawa, Toshihiko Hoshi, Gunzo Uchiyama, and Yasuhisa Ikeda
pp 1031 - 1038; DOI:
10.1021/ic0260926
PDF
5' Modification of Duplex DNA with a Ruthenium Electron Donor-Acceptor Pair Using Solid-Phase DNA Synthesis
Natia L. Frank and Thomas J. Meade
pp 1039 - 1044; DOI:
10.1021/ic025567q
PDF
Dinuclear Cyano Complexes of Cobalt(III) and Iron(III) Containing Noninnocent 1,2,4,5-Tetrakis(2-pyridinecarboxamido)benzene Bridging Ligands
Udo Beckmann, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt
pp 1045 - 1056; DOI:
10.1021/ic020518z
PDF
Cationic -Phenylplatinum(II) Complexes with Carboxylic Acid Functionality: pKa Determinations and X-ray Structures
Michael G. Crisp, Edward R. T. Tiekink, and Louis M. Rendina
pp 1057 - 1063; DOI:
10.1021/ic025776a
PDF
Heterobimetallic Oxalato-Bridged MIIReIV Complexes (M = Mn, Fe, Co, Ni): Synthesis, Crystal Structure, and Magnetic Properties
Raúl Chiozzone, Ricardo González, Carlos Kremer, Giovanni De Munno, Donatella Armentano, Francesc Lloret, Miguel Julve, and Juan Faus
pp 1064 - 1069; DOI:
10.1021/ic0205942
PDF
Coordination of BF4- to Oxovanadium(V) Complexes, Evidenced by the Redox Potential of Oxovanadium(IV/V) Couples in CH2Cl2
Kenichi Oyaizu, Eniya Listiani Dewi, and Eishun Tsuchida
pp 1070 - 1075; DOI:
10.1021/ic0205987
PDF
Reduction Pathway of End-On Coordinated Dinitrogen. 3.
Kay H. Horn, Nicolai Lehnert, and Felix Tuczek
pp 1076 - 1086; DOI:
10.1021/ic020458x
PDF
Nitrogen Ligands on Phosphorus(III) Lewis Acceptors: A Versatile New Synthetic Approach to Unusual N-P Structural Arrangements
Neil Burford, Pierre Losier, Andrew D. Phillips, Paul J. Ragogna, and T. Stanley Cameron
pp 1087 - 1091; DOI:
10.1021/ic026090l
PDF
Syntheses, Reactivity, and Crystal Structures of Molybdenum Complexes with Pyridine-2-thionate (pyS)-Containing Ligands: Crystal Structures of [Mo(3-C3H5)(CO)2]2(-1,2-pyS)2, exo-[Mo(3-C3H5)(CO)(2-pyS)(2-dppe)], [Mo(CO)3(1-SC5H4NH)(2-dppm)], and [Mo(CO)(2-pyS)2(2-dppm)]
Kuang-Hway Yih, Gene-Hsiang Lee, and Yu Wang
pp 1092 - 1100; DOI:
10.1021/ic020579x
PDF
Synthesis, Crystal Structure, and Characterization of the First Nb3 Triangular Cluster Compound Bonded to Fluorine Ligands: Association of Nb3IiFi3Fa8La Units and NbIVL6 Octahedra with L = O and F
S. Cordier, O. Hernandez, J.-Y. Thépot, A. I. Shames, and C. Perrin
pp 1101 - 1106; DOI:
10.1021/ic025667w
PDF
A Novel Hexanuclear Mixed Oxidation State CuII4CuI2 Cluster Complex Exhibiting Weak Ferromagnetic Exchange
Zhiqiang Xu, Laurence K. Thompson, David O. Miller, Eliseo Ruiz, and Santiago Alvarez
pp 1107 - 1111; DOI:
10.1021/ic0204631
PDF
Anion Dependent Structures of Luminescent Silver(I) Complexes
Corey Seward, Jacquelyn Chan, Datong Song, and Suning Wang
pp 1112 - 1120; DOI:
10.1021/ic020480q
PDF
Mixed Valence in YBaFe2O5
Patrick M. Woodward and Pavel Karen
pp 1121 - 1129; DOI:
10.1021/ic026022z
PDF
Double-Stranded W/Ag/S Chain Structure Generated from [syn-{WO(NCS)2}2(-S)2] Building Blocks
Wenjian Zhang, Xintao Wu, Biao Wu, Shuyan Yu, Gabriella Santoni, and Dieter Rehder
pp 1130 - 1134; DOI:
10.1021/ic020510p
PDF
Heteropolymolybdates of Phosphate, Phosphonate, and Phosphite Functionalized by Glycine
Ulrich Kortz, Jacqueline Vaissermann, René Thouvenot, and Pierre Gouzerh
pp 1135 - 1139; DOI:
10.1021/ic0261427
PDF
Tris(tert-butoxy)siloxy Derivatives of Boron, Including the Boronous Acid HOB[OSi(OtBu)3]2 and the Metal (Siloxy)boryloxide Complex Cp2Zr(Me)OB[OSi(OtBu)3]2: A Remarkable Crystal Structure with 18 Independent Molecules in Its Asymmetric Unit
Kyle L. Fujdala, Allen G. Oliver, Frederick J. Hollander, and T. Don Tilley
pp 1140 - 1150; DOI:
10.1021/ic0205482
PDF
Nickel(II) Macrocyclic Complexes with Long Alkyl Pendant Chain: Synthesis, X-ray Structure, and Anion Exchange Property in the Solid State
Hye Jin Choi and Myunghyun Paik Suh
pp 1151 - 1157; DOI:
10.1021/ic025971p
PDF
Polyoxomolybdates Functionalized with Phosphonocarboxylates
Ulrich Kortz, Catherine Marquer, René Thouvenot, and Martine Nierlich
pp 1158 - 1162; DOI:
10.1021/ic026140m
PDF
Multi-Iron Tungstodiarsenates. Synthesis, Characterization, and Electrocatalytic Studies of -(FeIIIOH2)2FeIII2(As2W15O56)212-
Israel Martyr Mbomekalle, Bineta Keita, Louis Nadjo, Patrick Berthet, Kenneth I. Hardcastle, Craig L. Hill, and Travis M. Anderson
pp 1163 - 1169; DOI:
10.1021/ic0261169
PDF
An Organically Templated Cobalt-Vanadium Oxide with Cage Units: Hydrothermal Synthesis and X-ray Structural Characterization of (C2H10N2)[Co2(C2O4)V4O12]
Guanghua Li, Zhan Shi, Yaohua Xu, and Shouhua Feng
pp 1170 - 1174; DOI:
10.1021/ic025808u
PDF
The Solid State Structure of [B10H11]- and Its Dynamic NMR Spectra in Solution
Sheldon G. Shore, Ewan J. M. Hamilton, Adam N. Bridges, Joseph Bausch, Jeanette A. Krause-Bauer, Danan Dou, Jianping Liu, Shengming Liu, Bin Du, Heather Hall, Edward A. Meyers, and Karl E. Vermillion
pp 1175 - 1186; DOI:
10.1021/ic020540s
PDF
Magnetic Superstructures of Cupric Oxide CuO as Ordered Arrangements of One-Dimensional Antiferromagnetic Chains
H.-J. Koo and M.-H. Whangbo
pp 1187 - 1192; DOI:
10.1021/ic020576k
PDF
Structural Modulation of Cu(I) and Cu(II) Complexes of Sterically Hindered Tripyridine Ligands by the Bridgehead Alkyl Groups
Masahito Kodera, Yuuji Kajita, Yoshimitsu Tachi, and Koji Kano
pp 1193 - 1203; DOI:
10.1021/ic026008m
PDF
New Insights into an Old Reaction. High-Resolution X-ray Powder Diffraction of Wiberg's Aminoalane Intermediate
Robert Dinnebier and Jens Müller
pp 1204 - 1210; DOI:
10.1021/ic026146b
PDF
Iron-Arylimide Clusters [Fem(NAr)nCl4]2- (m, n = 2, 2; 3, 4; 4, 4) from a Ferric Amide Precursor: Synthesis, Characterization, and Comparison to Fe-S Chemistry
Jeremiah S. Duncan, Tamim M. Nazif, Atul K. Verma, and Sonny C. Lee
pp 1211 - 1224; DOI:
10.1021/ic025825j
PDF
Kinetics and Mechanisms of the Oxidation of Phenols by a trans-Dioxoruthenium(VI) Complex
Douglas T. Y. Yiu, Mendy F. W. Lee, William W. Y. Lam, and Tai-Chu Lau
pp 1225 - 1232; DOI:
10.1021/ic026184v
PDF
Solution Chemistry of Uranyl Ion with Iminodiacetate and Oxydiacetate: A Combined NMR/EXAFS and Potentiometry/Calorimetry Study
J. Jiang, J. C. Renshaw, M. J. Sarsfield, F. R. Livens, D. Collison, J. M. Charnock, and H. Eccles
pp 1233 - 1240; DOI:
10.1021/ic020460o
PDF
Complexation of the Triply-Bonded Dirhenium(II) Complex Re2Cl4(-dppm)2 (dppm = Ph2PCH2PPh2) by Up to Three Acetylene Molecules
Mani Ganesan, Keng-Yu Shih, Phillip E. Fanwick, and Richard A. Walton
pp 1241 - 1247; DOI:
10.1021/ic020532b
PDF
Realizing Green Phosphorescent Light-Emitting Materials from Rhenium(I) Pyrazolato Diimine Complexes
Sudhir Ranjan, Shen-Yi Lin, Kuo-Chu Hwang, Yun Chi, Wei-Li Ching, Chao-Shiuan Liu, Yu-Tai Tao, Chin-Hsiung Chien, Shie-Ming Peng, and Gene-Hsiang Lee
pp 1248 - 1255; DOI:
10.1021/ic0259181
PDF
51V Solid-State Magic Angle Spinning NMR Spectroscopy and DFT Studies of Oxovanadium(V) Complexes Mimicking the Active Site of Vanadium Haloperoxidases
Neela Pooransingh, Ekaterina Pomerantseva, Martin Ebel, Sven Jantzen, Dieter Rehder, and Tatyana Polenova
pp 1256 - 1266; DOI:
10.1021/ic026141e
PDF
Inhibition of Transcription in Vitro by Anticancer Active Dirhodium(II) Complexes
Karn Sorasaenee, Patty K.-L. Fu, Alfredo M. Angeles-Boza, Kim R. Dunbar, and Claudia Turro
pp 1267 - 1271; DOI:
10.1021/ic020591p
PDF
Insertion of Carbon Fragments into P(III)-N Bonds in Aminophosphines and Aminobis(phosphines): Synthesis, Reactivity, and Coordination Chemistry of Resulting Phosphine Oxide Derivatives. Crystal and Molecular Structures of (Ph2P(O)CH2)2NR (R = Me, nPr, nBu), Ph2P(O)CH(OH)nPr, and cis-[MoO2Cl2{(Ph2P(O)CH2)2NEt-O,O}]
Srinivasan Priya, Maravanji S. Balakrishna, Joel T. Mague, and Shaikh M. Mobin
pp 1272 - 1281; DOI:
10.1021/ic026118t
PDF
Platinum and Palladium Imido and Oxo Complexes with Small Natural Bite Angle Diphosphine Ligands
U. Anandhi, Todd Holbert, Dennis Lueng, and Paul R. Sharp
pp 1282 - 1295; DOI:
10.1021/ic025987f
PDF
Chalcogenide-Halides of Niobium (V). 1. Gas-Phase Structures of NbOBr3, NbSBr3, and NbSCl3. 2. Matrix Infrared Spectra and Vibrational Force Fields of NbOBr3, NbSBr3, NbSCl3, and NbOCl3
Izabela Nowak, Elizabeth M. Page, David A. Rice, Alan D. Richardson, Richard J. French, Kenneth Hedberg, and J. Steven Ogden
pp 1296 - 1305; DOI:
10.1021/ic020405f
PDF
Novel Pb and Zn Coordination Polymers: Synthesis, Molecular Structures, and Third-Order Nonlinear Optical Properties
Xiangru Meng, Yinglin Song, Hongwei Hou, Yaoting Fan, Gang Li, and Yu Zhu
pp 1306 - 1315; DOI:
10.1021/ic0259282
PDF
Metal-Dependent Ferro- Versus Antiferromagnetic Interactions in Molecular Crystals of Square Planar {M(II) Imino-Nitroxide Radical} Complexes (M = Pt, Pd)
Mohammed Fettouhi, Bassam El Ali, Mohammed Morsy, Stéphane Golhen, Lahcène Ouahab, Boris Le Guennic, Jean-Yves Saillard, Nathalie Daro, Jean-Pascal Sutter, and Edmond Amouyal
pp 1316 - 1321; DOI:
10.1021/ic0255813
PDF
First Example of 3-Sulfido Bridged Mixed-Valent Triruthenium Complex Triangle RuIII2RuII(O,O-acetylacetonate)3(-O,O,-C-acetylacetonate)3(3-S) (1) Incorporating Simultaneous O,O- and -C-Bonded Bridging Acetylacetonate Units. Synthesis, Crystal Structure, and Spectral and Redox Properties
Srikanta Patra, Biplab Mondal, Biprajit Sarkar, Mark Niemeyer, and Goutam Kumar Lahiri
pp 1322 - 1327; DOI:
10.1021/ic026221i
PDF
Germanium-Rich Pentaruthenium Carbonyl Clusters Including Ru5(CO)11(-GePh2)4(5-C) and Its Reactions with Hydrogen
Richard D. Adams, Burjor Captain, and Wei Fu
pp 1328 - 1333; DOI:
10.1021/ic020655w
PDF
Stability of the Gold(I)-Phosphine Bond. A Comparison with Other Group 11 Elements
Peter Schwerdtfeger, Holger L. Hermann, and Hubert Schmidbaur
pp 1334 - 1342; DOI:
10.1021/ic026098v
PDF
Aqua Ions. 1. The Structures of the [Ru(OH2)6]3+ and [V(OH2)6]3+ Cations in Aqueous Solution: An EPR and UV-Vis Study
Stefan Dolder, David Spichiger, and Philip L. W. Tregenna-Piggott
pp 1343 - 1349; DOI:
10.1021/ic025962g
PDF
Aqua Ions. 2. Structural Manifestations of the Jahn-Teller Effect in the -Alums
Philip L. W. Tregenna-Piggott, Hans-Peter Andres, Garry J. McIntyre, Stephen P. Best, Chick C. Wilson, and John A. Cowan
pp 1350 - 1365; DOI:
10.1021/ic0259639
PDF
K2MM'3Se6 (M = Cu, Ag; M' = Ga, In), A New Series of Metal Chalcogenides with Chain-Sublayer-Chain Slabs: 1[M'Se4]-2[(MSe4)(M'Se4)]-1[M'Se4]
Hong-Wei Ma, Guo-Cong Guo, Ming-Sheng Wang, Guo-Wei Zhou, Shan-Hou Lin, Zhen-Chao Dong, and Jin-Shun Huang
pp 1366 - 1370; DOI:
10.1021/ic025936i
PDF
Redox Active Macrocyclic Receptors for Neutral Guests
Paul V. Bernhardt and Elizabeth J. Hayes
pp 1371 - 1377; DOI:
10.1021/ic026000c
PDF
Enantiospecific Synthesis of and [Ru(bpy)2ppy]+ and [Ru(bpy)2quo]+ (bpy = 2,2'-Bipyridine, ppy = Phenylpyridine-H+, quo = 8-Hydroxyquinolate): 1H and 13C NMR Studies and X-ray Structure Determination of rac-[Ru(bpy)2quo]PF6
Muriel Brissard, Odile Convert, Michel Gruselle, Carine Guyard-Duhayon, and René Thouvenot
pp 1378 - 1385; DOI:
10.1021/ic026121c
PDF
Forty-Five Years of Chemical Discovery Including a Golden Quarter-Century
John P. Fackler, Jr.:
pp 1386 - 1386; DOI:
10.1021/ic020722m
PDF

Issue 5


Applications of High-Field (W-Band) EPR to M-M Bonded Units (M = Cr, Mo): The First Confirmed Oxidation of a Cr24+ Paddlewheel Complex to a Stable Isostructural Cr25+ Product
F. Albert Cotton, Naresh S. Dalal, Elizabeth A. Hillard, Penglin Huang, Carlos A. Murillo, and Chris M. Ramsey
pp 1388 - 1390; DOI:
10.1021/ic0260670
PDF
A Monomeric Imidazol-2-ylidene-Silver(I) Chloride Complex: Synthesis, Structure, and Solid State 109Ag and 13C CP/MAS NMR Characterization
Taramatee Ramnial, Colin D. Abernethy, Mark D. Spicer, Iain D. McKenzie, Ian D. Gay, and Jason A. C. Clyburne
pp 1391 - 1393; DOI:
10.1021/ic0262381
PDF
Room Temperature Phosphorescence from a Platinum(II) Diimine Bis(pyrenylacetylide) Complex
Irina E. Pomestchenko, Charles R. Luman, Muriel Hissler, Raymond Ziessel, and Felix N. Castellano
pp 1394 - 1396; DOI:
10.1021/ic0261631
PDF
Anion Receptors: A New Class of Amide/Quaternized Amine Macrocycles and the Chelate Effect
Md. Alamgir Hossain, Sung Ok Kang, Douglas Powell, and Kristin Bowman-James
pp 1397 - 1399; DOI:
10.1021/ic0263140
PDF
[(CH3)3NCH2CH2NH3]SnI4: A Layered Perovskite with Quaternary/Primary Ammonium Dications and Short Interlayer Iodine-Iodine Contacts
Zhengtao Xu, David B. Mitzi, and David R. Medeiros
pp 1400 - 1402; DOI:
10.1021/ic0261981
PDF
High-Nuclearity Metal-Cyanide Clusters: Synthesis, Magnetic Properties, and Inclusion Behavior of Open-Cage Species Incorporating [(tach)M(CN)3] (M = Cr, Fe, Co) Complexes
Jenny Y. Yang, Matthew P. Shores, Jennifer J. Sokol, and Jeffrey R. Long
pp 1403 - 1419; DOI:
10.1021/ic026065f
PDF
Solution Chemistry of Copper(II)-Gentamicin Complexes: Relevance to Metal-Related Aminoglycoside Toxicity
Wojciech Lesniak, Wesley R. Harris, Joslyn Yudenfreund Kravitz, Jochen Schacht, and Vincent L. Pecoraro
pp 1420 - 1429; DOI:
10.1021/ic025965t
PDF
Syntheses and Characterization of Two Dioxygen-Reactive Dinuclear Macrocyclic Schiff-Base Copper(I) Complexes
Diana Utz, Frank W. Heinemann, Frank Hampel, David T. Richens, and Siegfried Schindler
pp 1430 - 1436; DOI:
10.1021/ic025731+
PDF
Titanium Alkoxides as Initiators for the Controlled Polymerization of Lactide
Youngjo Kim, G. K. Jnaneshwara, and John G. Verkade
pp 1437 - 1447; DOI:
10.1021/ic026139n
PDF
Photophysics and Redox Behavior of Chiral Transition Metal Polymers
Jason A. Barron, Samantha Glazier, Stefan Bernhard, Kazutake Takada, Paul L. Houston, and Héctor D. Abruña
pp 1448 - 1455; DOI:
10.1021/ic020691v
PDF
Iron Hemiporphycene as a Functional Prosthetic Group for Myoglobin
Saburo Neya, Kiyohiro Imai, Hiroshi Hori, Haruto Ishikawa, Koichiro Ishimori, Daichi Okuno, Shigenori Nagatomo, Tyuji Hoshino, Masayuki Hata, and Noriaki Funasaki
pp 1456 - 1461; DOI:
10.1021/ic020504t
PDF
A Ferromagnetically Coupled CrCu3 Tetramer and GdCu4 Pentamer with a [15]N4 Macrocylic Ligand Incorporating an Oxamido Bridge
Lei Zhang, Shi-Bin Wang, Guang-Ming Yang, Jin-kui Tang, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, and Peng Cheng
pp 1462 - 1466; DOI:
10.1021/ic020466d
PDF
Laves-Phase Structural Changes in the System CaAl2-xMgx
Shahrad Amerioun, Sergei I. Simak, and Ulrich Häussermann
pp 1467 - 1474; DOI:
10.1021/ic020596m
PDF
Flux Synthesis of the Noncentrosymmetric Cluster Compounds Cs2SnAs2Q9 (Q = S, Se) Containing Two Different Polychalcoarsenite -[AsQ4]3- and [AsQ5]3- Ligands
Ratnasabapathy G. Iyer, Junghwan Do, and Mercouri G. Kanatzidis
pp 1475 - 1482; DOI:
10.1021/ic0260771
PDF
Symmetric and Asymmetric Dinuclear Manganese(IV) Complexes Possessing a [MnIV2(-O)2(-O2CMe)]3+ Core and Terminal Cl- Ligands
Sumit Bhaduri, Anastasios J. Tasiopoulos, Milissa A. Bolcar, Khalil A. Abboud, William E. Streib, and George Christou
pp 1483 - 1492; DOI:
10.1021/ic020570v
PDF
New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3, and (C4N3OH7)2·ZnHPO3·H2O
William T. A. Harrison, Rachel M. Yeates, Mark L. F. Phillips, and Tina M. Nenoff
pp 1493 - 1498; DOI:
10.1021/ic020593+
PDF
Crystal and Molecular Structures of Alkali Oxalates: First Proof of a Staggered Oxalate Anion in the Solid State
Robert E. Dinnebier, Sascha Vensky, Martin Panthöfer, and Martin Jansen
pp 1499 - 1507; DOI:
10.1021/ic0205536
PDF
Oxovanadium(IV) and -(V) Complexes of Dithiocarbazate-Based Tridentate Schiff Base Ligands: Syntheses, Structure, and Photochemical Reactivity of Compounds Involving Imidazole Derivatives as Coligands
Satyabrata Samanta, Dipesh Ghosh, Suman Mukhopadhyay, Akira Endo, Timothy J. R. Weakley, and Muktimoy Chaudhury
pp 1508 - 1517; DOI:
10.1021/ic020438v
PDF
Photoinduced Chemical Reactions on Natural Single Crystals and Synthesized Crystallites of Mercury(II) Sulfide in Aqueous Solution Containing Naturally Occurring Amino Acids
Bonamali Pal, Shigeru Ikeda, and Bunsho Ohtani
pp 1518 - 1524; DOI:
10.1021/ic025916g
PDF
Synthesis, Characterization, and Photophysical Studies of New Bichromophoric Ruthenium(II) Complexes
Idalina M. M. de Carvalho, ĂŤcaro de Sousa Moreira, and Marcelo H. Gehlen
pp 1525 - 1531; DOI:
10.1021/ic025831f
PDF
Characterization of the Low-Energy Electronic Excited States of Benzoyl-Substituted Ferrocenes
Wei Ding, Cynthia T. Sanderson, Richard C. Conover, Michael K. Johnson, I. Jonathan Amster, and Charles Kutal
pp 1532 - 1537; DOI:
10.1021/ic020639z
PDF
The Arrangement of First- and Second-Shell Water Molecules in Trivalent Aluminum Complexes: Results from Density Functional Theory and Structural Crystallography
Charles W. Bock, George D. Markham, Amy K. Katz, and Jenny P. Glusker
pp 1538 - 1548; DOI:
10.1021/ic020602e
PDF
Lanthanum Gallium Bismuthide, LaGaBi2
Mark G. Morgan, Meitian Wang, Wing Yan Chan, and Arthur Mar
pp 1549 - 1555; DOI:
10.1021/ic020413w
PDF
Syntheses of a Cp'Re=S Derivative and More Complex Products
S. H. Pawlicki, B. C. Noll, J. A. Kanney, and M. Rakowski DuBois
pp 1556 - 1563; DOI:
10.1021/ic0206241
PDF
Chiral Direction and Interconnection of Helical Three-Connected Networks in Metal-Organic Frameworks
T. J. Prior and M. J. Rosseinsky
pp 1564 - 1575; DOI:
10.1021/ic025775i
PDF
dlf Complexes with Uniform Coordination Geometry: Structural and Magnetic Properties of an LnNi2 Core Supported by a Heptadentate Amine Phenol Ligand
Simon R. Bayly, Zhiquiang Xu, Brian O. Patrick, Steven J. Rettig, Maren Pink, Robert C. Thompson, and Chris Orvig
pp 1576 - 1583; DOI:
10.1021/ic0205278
PDF
Syntheses, Crystal Engineering, and Magnetic Property of a Dicyanamide Bridged Three-Dimensional Manganese(II)-Nitronyl Nitroxide Coordination Polymer Derived from a New Radical
Hsin-Huang Lin, Sasankasekhar Mohanta, Chin-Jhan Lee, and Ho-Hsiang Wei
pp 1584 - 1589; DOI:
10.1021/ic025768u
PDF
H-Bonding Dependent Structures of (NH4+)3H+(SO42-)2. Mechanisms of Phase Transitions
Paulina M. Dominiak, Joanna Herold, Waclaw Kolodziejski, and Krzysztof Woniak
pp 1590 - 1598; DOI:
10.1021/ic025705b
PDF
The Electronic Spectrum of Re2Cl82-: A Theoretical Study
Laura Gagliardi and Björn O. Roos
pp 1599 - 1603; DOI:
10.1021/ic0261068
PDF
Zinc-Bound Thiolate-Disulfide Exchange: A Strategy for Inhibiting Metallo--lactamases
Heidi Boerzel, Margery Koeckert, Weiming Bu, Bernhard Spingler, and Stephen J. Lippard
pp 1604 - 1615; DOI:
10.1021/ic025624f
PDF
First Anionic 1,10-Phenanthroline-2,9-dicarboxylate Containing Metal Complex Obtained from a Novel 1:1 Proton-Transfer Compound: Synthesis, Characterization, Crystal Structure, and Solution Studies
A. Moghimi, R. Alizadeh, A. Shokrollahi, H. Aghabozorg, M. Shamsipur, and A. Shockravi
pp 1616 - 1624; DOI:
10.1021/ic025725d
PDF
Substantial Increase of the Ordering Temperature for {MnII/MoIII(CN)7}-Based Magnets as a Function of the 3d Ion Site Geometry: Example of Two Supramolecular Materials with Tc = 75 and 106 K
Stéfania Tanase, Floriana Tuna, Philippe Guionneau, Thierry Maris, Guillaume Rombaut, Corine Mathonière, Marius Andruh, Olivier Kahn, and Jean-Pascal Sutter
pp 1625 - 1631; DOI:
10.1021/ic025990z
PDF
Monitoring the Redox-Driven Assembly/Disassembly of a Dicopper(I) Helicate with an Auxiliary Fluorescent Probe
Valeria Amendola, Luigi Fabbrizzi, Piersandro Pallavicini, Elisabetta Sartirana, and Angelo Taglietti
pp 1632 - 1636; DOI:
10.1021/ic026061a
PDF
Assembly of Discrete, One-, Two-, and Three-Dimensional Silver(I) Supramolecular Complexes Containing Encapsulated Acetylide Dianion with Nitrogen-Donor Spacers
Quan-Ming Wang and Thomas C. W. Mak
pp 1637 - 1643; DOI:
10.1021/ic026019f
PDF
Electronic Structure of Iron Chlorins: Characterization of Bis(L-valine methyl ester)(meso-tetraphenylchlorin)iron(III)triflate and Bis(L-valine methyl ester)(meso-tetraphenylchlorin)iron(II)
Gérard Simonneaux, Marwan Kobeissi, and Loîc Toupet
pp 1644 - 1651; DOI:
10.1021/ic026039h
PDF
[Mo5VMo7VIO30(BPO4)2(O3P-Ph)6]5-: A Phenyl-Substituted Molybdenum(V/VI) Boro-Phosphate Polyoxometalate
Capucine Sassoye, Kieran Norton, and Slavi C. Sevov
pp 1652 - 1655; DOI:
10.1021/ic020635u
PDF
Hydrogen-Bonded Extended Arrays of the [Re6(3-Se)8]2+ Core-Containing Clusters
Hugh D. Selby, Bryan K. Roland, Michael D. Carducci, and Zhiping Zheng
pp 1656 - 1662; DOI:
10.1021/ic0261326
PDF
Photothermally Induced Bergman Cyclization of Metalloenediynes via Near-Infrared Ligand-to-Metal Charge-Transfer Excitation
Brian J. Kraft, Nicole L. Coalter, Mahendra Nath, Aurora E. Clark, Allen R. Siedle, John C. Huffman, and Jeffrey M. Zaleski
pp 1663 - 1672; DOI:
10.1021/ic0207045
PDF
Synthesis and Structure of [meso-Triarylcorrolato]silver(III)
Christian Brückner, Cheri A. Barta, Raymond P. Briñas, and Jeanette A. Krause Bauer
pp 1673 - 1680; DOI:
10.1021/ic0261171
PDF
Reaction of (-Oxo)diiron(III) Core with CO2 in N-Methylimidazole: Formation of Mono(-carboxylato)(-oxo)diiron(III) Complexes with N-Methylimidazole as Ligands
Dana S. Marlin, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 1681 - 1687; DOI:
10.1021/ic0206140
PDF
Electronic Tuning of the Lability of Pt(II) Complexes through -Acceptor Effects. Correlations between Thermodynamic, Kinetic, and Theoretical Parameters
Andreas Hofmann, Deogratius Jaganyi, Orde Q. Munro, Günter Liehr, and Rudi van Eldik
pp 1688 - 1700; DOI:
10.1021/ic020605r
PDF
Bonding Coordination Requirements Induce Antiferromagnetic Coupling between m-Phenylene Bridged o-Iminosemiquinonato Diradicals
Andrea Dei, Dante Gatteschi, Claudio Sangregorio, Lorenzo Sorace, and Maria G. F. Vaz
pp 1701 - 1706; DOI:
10.1021/ic026160o
PDF
Dinitrogen Formation by Oxidative Intramolecular N---N Coupling in cis,cis-[(bpy)2(NH3)RuORu(NH3)(bpy)2]4+
Osamu Ishitani, Emiko Ando, and Thomas J. Meyer
pp 1707 - 1710; DOI:
10.1021/ic026096a
PDF
Encapsulation of Cobalt Phthalocyanine in Zeolite-Y: Evidence for Nonplanar Geometry
Saumi Ray and S. Vasudevan
pp 1711 - 1719; DOI:
10.1021/ic026129m
PDF
Nickel Complexes of a Bulky -Diketiminate Ligand
Nathan A. Eckert, Emily M. Bones, Rene J. Lachicotte, and Patrick L. Holland
pp 1720 - 1725; DOI:
10.1021/ic025986n
PDF
Stability of Divalent Europium in an Ionic Liquid: Spectroscopic Investigations in 1-Methyl-3-butylimidazolium Hexafluorophosphate
Isabelle Billard, Gilles Moutiers, Alexandre Labet, Antoine El Azzi, Clotilde Gaillard, Clarisse Mariet, and Klaus Lützenkirchen
pp 1726 - 1733; DOI:
10.1021/ic0260318
PDF
Mn~2.4Mo6O9: First Example of Empty Twin Chains of Edge-Sharing M6 Octahedra in Transition Metal Cluster Chemistry
Nicolas Barrier, Patrick Gougeon, Richard Retoux, and Henri Leligny
pp 1734 - 1738; DOI:
10.1021/ic0260365
PDF
Synthesis, Structure, and Magnetic Properties of Two New Vanadocarboxylates with Three-Dimensional Hybrid Frameworks
K. Barthelet, D. Riou, M. Nogues, and G. Férey
pp 1739 - 1743; DOI:
10.1021/ic026175m
PDF
Generation of a Peroxynitrato Metal Complex from Nitrogen Dioxide and Coordinated Superoxide
Oleg Pestovsky and Andreja Bakac
pp 1744 - 1750; DOI:
10.1021/ic026315s
PDF
Syntheses, Structures, and Dynamic Behavior of Chiral Racemic Organoantimony and -bismuth Compounds RR'SbCl, RR'BiCl, and RR'SbM [R = 2-(Me2NCH2)C6H4, R' = CH(Me3Si)2, M = H, Li, Na]
Hans J. Breunig, Ioan Ghesner, Mihaiela E. Ghesner, and Enno Lork
pp 1751 - 1757; DOI:
10.1021/ic026231j
PDF
Syntheses and Structures of Metallocene Methyltrihydroborate Derivativies: Cp2ZrCl{(-H)2BHCH3}, Cp2Zr{(-H)2BHCH3}2, and Cp2Ti{(-H)2BHCH3}
Fu-Chen Liu, Ko-Yu Chen, Jung-Hua Chen, Gene-Hsian Lee, and Shie-Ming Peng
pp 1758 - 1763; DOI:
10.1021/ic020597e
PDF
New Low-Temperature Preparations of Some Simple and Mixed Co and Ni Dispersed Sulfides and Their Chemical Behavior in Reducing Atmosphere
I. Bezverkhyy, M. Danot, and P. Afanasiev
pp 1764 - 1768; DOI:
10.1021/ic026024j
PDF
Synthesis and Molecular Structure of the Dihydrobis(thioxotriazolinyl)borato Complexes of Zinc(II), Bismuth(III), and Nickel(II). M···H-B Interaction Studied by Ab Initio Calculations
Roberto Cammi, Maurizio Lanfranchi, Luciano Marchiò, Clara Mora, Cristiano Paiola, and Maria Angela Pellinghelli
pp 1769 - 1778; DOI:
10.1021/ic025870r
PDF
Synthesis and Structure of Sr3GaN3 and Sr6GaN5: Strontium Gallium Nitrides with Isolated Planar [GaN3]6- Anions
Dong Gon Park, Zoltán A. Gál, and Francis J. DiSalvo
pp 1779 - 1785; DOI:
10.1021/ic025874w
PDF
Computational Study of the Non-Heme Iron Active Site in Superoxide Reductase and Its Reaction with Superoxide.
Radu Silaghi-Dumitrescu, Ioan Silaghi-Dumitrescu, Eric D.Coulter, and Donald M. Kurtz, Jr.:
pp 1786 - 1786; DOI:
10.1021/ic034072d
PDF

Issue 6


Direct Observation of Fine Structure Transitions in a Paramagnetic Nickel(II) Complex Using Far-Infrared Magnetic Spectroscopy: A New Method for Studying High-Spin Transition Metal Complexes
Suriyakan Vongtragool, Boris Gorshunov, Martin Dressel, J. Krzystek, David M. Eichhorn, and Joshua Telser
pp 1788 - 1790; DOI:
10.1021/ic030013o
PDF
First Radical Cation Salt of Paramagnetic Transition Metal Complex Containing TTF as Ligand, [CuII(hfac)2(TTF-py)2](PF6)·2CH2Cl2 (hfac = Hexafluoroacetylacetonate and TTF-py = 4-(2-Tetrathiafulvalenyl-ethenyl)pyridine)
Fatima Setifi, Lahcène Ouahab, Stéphane Golhen, Yukihiro Yoshida, and Gunzi Saito
pp 1791 - 1793; DOI:
10.1021/ic026211h
PDF
Synthesis and Characterization of an Open Framework Gallium Selenide: Ga4Se7(en)2·(enH)2
Yajie Dong, Qing Peng, Ruji Wang, and Yadong Li
pp 1794 - 1796; DOI:
10.1021/ic0262536
PDF
Synthesis and Structure of KBGe2O6: The First Chiral Zeotype Borogermanate with 7-Ring Channels
Zhi-En Lin, Jie Zhang, and Guo-Yu Yang
pp 1797 - 1799; DOI:
10.1021/ic020511h
PDF
Reversible Binding of Dioxygen by the Copper(I) Complex with Tris(2-dimethylaminoethyl)amine (Me6tren) Ligand
Markus Weitzer, Siegfried Schindler, Georg Brehm, Siegfried Schneider, Esther Hörmann, Bernhard Jung, Susan Kaderli, and Andreas D. Zuberbühler
pp 1800 - 1806; DOI:
10.1021/ic025941m
PDF
Copper(I)-Dioxygen Reactivity of [(L)CuI]+ (L = Tris(2-pyridylmethyl)amine): Kinetic/Thermodynamic and Spectroscopic Studies Concerning the Formation of Cu-O2 and Cu2-O2 Adducts as a Function of Solvent Medium and 4-Pyridyl Ligand Substituent Variations
Christiana Xin Zhang, Susan Kaderli, Miguel Costas, Eun-il Kim, Yorck-Michael Neuhold, Kenneth D. Karlin, and Andreas D. Zuberbühler
pp 1807 - 1824; DOI:
10.1021/ic0205684
PDF
Synthesis and Spectroelectrochemical Studies of Mixed Heteroleptic Chelate Complexes of Ruthenium(II) with 1,8-Bis(2-pyridyl)-3,6-dithiaoctane (pdto) and Substituted 1,10-Phenanthrolines
Luis A. Ortiz-Frade, Lena Ruiz-Ramírez, Ignacio González, Armando Marín-Becerra, Manuel Alcarazo, José G. Alvarado-Rodriguez, and Rafael Moreno-Esparza
pp 1825 - 1834; DOI:
10.1021/ic025849q
PDF
Synthesis and Structure of the Metallic K6Tl17: A Layered Tetrahedral Star Structure Related to That of Cr3Si
Stefan Kaskel, Zhen-Chao Dong, Michael T. Klem, and John D. Corbett
pp 1835 - 1841; DOI:
10.1021/ic020667h
PDF
Half-Sandwich Titanium(IV) Complexes with Kläui's Tripod Ligand
Tony C. H. Lam, Eddie Y. Y. Chan, Wing-Leung Mak, Samuel M. F. Lo, Ian D. Williams, Wing-Tak Wong, and Wa-Hung Leung
pp 1842 - 1847; DOI:
10.1021/ic020287w
PDF
Synthesis, Crystal Structures, and Magnetic Properties of Two Cyano-Bridged Tungstate(V)-Manganese(II) Bimetallic Magnets
You Song, Shin-ichi Ohkoshi, Yoichi Arimoto, Hidetake Seino, Yasushi Mizobe, and Kazuhito Hashimoto
pp 1848 - 1856; DOI:
10.1021/ic025959x
PDF
Dioxo-Bridged Dinuclear Manganese(III) and -(IV) Complexes of Pyridyl Donor Tripod Ligands: Combined Effects of Steric Substitution and Chelate Ring Size Variations on Structural, Spectroscopic, and Electrochemical Properties
Yilma Gultneh, Teshome B. Yisgedu, Yohannes T. Tesema, and Ray J. Butcher
pp 1857 - 1867; DOI:
10.1021/ic020131w
PDF
Ruthenium(III) Polyaminocarboxylate Complexes: Efficient and Effective Nitric Oxide Scavengers
Beth R. Cameron, Marilyn C. Darkes, Helen Yee, Micki Olsen, Simon P. Fricker, Renato T. Skerlj, Gary J. Bridger, Nathan A. Davies, Michael T. Wilson, David J. Rose, and Jon Zubieta
pp 1868 - 1876; DOI:
10.1021/ic020219+
PDF
Zinc(II)-Templated Synthesis of a [2]-Catenane Consisting of a 2,2',6',2' '-Terpyridine-Incorporating Cycle and a 1,10-Phenanthroline-Containing Ring
Christine Hamann, Jean-Marc Kern, and Jean-Pierre Sauvage
pp 1877 - 1883; DOI:
10.1021/ic020381c
PDF
Kinetics of Oxygen Exchange between the Two Isomers of Bisulfite Ion, Disulfite Ion (S2O52-), and Water As Studied by Oxygen-17 Nuclear Magnetic Resonance Spectroscopy
David A. Horner and Robert E. Connick
pp 1884 - 1894; DOI:
10.1021/ic020692n
PDF
Synthesis, X-ray Crystal Structure, and Redox and Electronic Properties of Iron(III)-Polyimidazole Complexes Relevant to the Metal Sites of Iron Proteins
Anne-Sophie Chauvin, Yves-Michel Frapart, Jacqueline Vaissermann, Bruno Donnadieu, Jean-Pierre Tuchagues, Jean-Claude Chottard, and Yun Li
pp 1895 - 1900; DOI:
10.1021/ic020401a
PDF
Spectroscopic and Thermal Investigations of the Fluoroaluminate Complex Formation in NaF-KF and LiF-NaF-KF Eutectics
J. H. von Barner, C. Bessada, and R. W. Berg
pp 1901 - 1907; DOI:
10.1021/ic020305+
PDF
Electronic Structure of ReO3Me by Variable Photon Energy Photoelectron Spectroscopy, Absorption Spectroscopy and Density Functional Calculations
Monica de Simone, Marcello Coreno, Jennifer C. Green, Sean McGrady, and Helen Pritchard
pp 1908 - 1918; DOI:
10.1021/ic020547+
PDF
Solid-State Chelation of Metal Ions by Ethylenediaminetetraacetate Intercalated in a Layered Double Hydroxide
Konstantin A. Tarasov, Dermot O'Hare, and Vitaly P. Isupov
pp 1919 - 1927; DOI:
10.1021/ic0203926
PDF
Syntheses and Structures of Photochromic Silver(I) Coordination Polymers with cis-1,2-Dicyano-1,2-bis(2,4,5-trimethyl-3-thienyl)ethene
Hisashi Konaka, Liang Ping Wu, Megumu Munakata, Takayoshi Kuroda-Sowa, Masahiko Maekawa, and Yusaku Suenaga
pp 1928 - 1934; DOI:
10.1021/ic020525n
PDF
Synthesis and Characterization of Optically Active and Racemic Forms of Cyclometalated Rh(III) Complexes. An Experimental and Theoretical Emission Study
Liana Ghizdavu, Olivier Lentzen, Stephan Schumm, André Brodkorb, Cécile Moucheron, and Andrée Kirsch-De Mesmaeker
pp 1935 - 1944; DOI:
10.1021/ic020435i
PDF
Electrochemical and Spectral Studies on the Reductive Nitrosylation of Water-Soluble Iron Porphyrin
Natalia S. Trofimova, Alexander Y. Safronov, and Osamu Ikeda
pp 1945 - 1951; DOI:
10.1021/ic025830n
PDF
Synthesis, Structure, and Dissociation Equilibrium of [Co(5-C5H5)(Se2C6H4)]2, a Novel Metalladiselenolene Complex
Satoru Habe, Teppei Yamada, Takuya Nankawa, Jun Mizutani, Masaki Murata, and Hiroshi Nishihara
pp 1952 - 1955; DOI:
10.1021/ic025865n
PDF
Self-Assembly in Palladium(II) and Platinum(II) Chemistry: The Biomimetic Approach
Zengquan Qin, Michael C. Jennings, and Richard J. Puddephatt
pp 1956 - 1965; DOI:
10.1021/ic020322z
PDF
Small Organoselenium Molecules. 1. Dimethyl Selenoxide: Structure, Complexation, and Gas-Phase Transformation
Evgeny V. Dikarev, Marina A. Petrukhina, Xiaojie Li, and Eric Block
pp 1966 - 1972; DOI:
10.1021/ic020556i
PDF
The Crystal Structure and Magnetic Properties of a New Ferrimagnetic Semiconductor: Ca21Mn4Sb18
Aaron P. Holm, Marilyn M. Olmstead, and Susan M. Kauzlarich
pp 1973 - 1981; DOI:
10.1021/ic020530r
PDF
Structure and Bonding in Solution of Dioxouranium(VI) Oxalate Complexes: Isomers and Intramolecular Ligand Exchange
Valérie Vallet, Henry Moll, Ulf Wahlgren, Zoltán Szabó, and Ingmar Grenthe
pp 1982 - 1993; DOI:
10.1021/ic026068s
PDF
Coordination Properties of Tris(2-carboxyethyl)phosphine, a Newly Introduced Thiol Reductant, and Its Oxide
Artur Krel, Rafa Latajka, Grzegorz D. Bujacz, and Wojciech Bal
pp 1994 - 2003; DOI:
10.1021/ic025969y
PDF
Amine-Templated Linear Vanadium Sulfates with Different Chain Structures
Geo Paul, Amitava Choudhury, R. Nagarajan, and C. N. R. Rao
pp 2004 - 2013; DOI:
10.1021/ic020645v
PDF
Molecular Precursors for Ferroelectric Materials: Synthesis and Characterization of Bi2M2(-O)(sal)4(Hsal)4(OEt)2 and BiM4(-O)4(sal)4(Hsal)3(OiPr)4 (sal = O2CC6H4O, Hsal = O2CC6H4OH) (M = Nb, Ta)
John H. Thurston and Kenton H. Whitmire
pp 2014 - 2023; DOI:
10.1021/ic026108s
PDF
Synthesis and Structural Characterization of a Novel Mixed-Valent CuIICuICuII Triangular Metallomacrocycle Using an Imine-Based Rigid Ligand
Guo Dong, Qian Chun-qi, Duan Chun-ying, Pang Ke-liang, and Meng Qing-jin
pp 2024 - 2030; DOI:
10.1021/ic0260668
PDF
Semiconducting Perovskites (2-XC6H4C2H4NH3)2SnI4 (X = F, Cl, Br): Steric Interaction between the Organic and Inorganic Layers
Zhengtao Xu, David B. Mitzi, Christos D. Dimitrakopoulos, and Karen R. Maxcy
pp 2031 - 2039; DOI:
10.1021/ic0261474
PDF
Synthesis, Structure, and Spectroscopic, Photochemical, Redox, and Catalytic Properties of Ruthenium(II) Isomeric Complexes Containing Dimethyl Sulfoxide, Chloro, and the Dinucleating Bis(2-pyridyl)pyrazole Ligands
Cristina Sens, Montserrat Rodríguez, Isabel Romero, Antoni Llobet, Teodor Parella, B. Patrick Sullivan, and Jordi Benet-Buchholz
pp 2040 - 2048; DOI:
10.1021/ic026114o
PDF
Cu(II) Complexes with Heterocyclic Substituted Thiosemicarbazones: The Case of 5-Formyluracil. Synthesis, Characterization, X-ray Structures, DNA Interaction Studies, and Biological Activity
Monica Baldini, Marisa Belicchi-Ferrari, Franco Bisceglie, Giorgio Pelosi, Silvana Pinelli, and Pieralberto Tarasconi
pp 2049 - 2055; DOI:
10.1021/ic026131d
PDF
Complexing Ability of the Versatile, Redox-Active, 3-[3-(Diphenylphosphino)propylthio]-3',4,4'-trimethyl-tetrathiafulvalene Ligand
Pascal Pellon, Grégory Gachot, Jérome Le Bris, Stéphane Marchin, Roger Carlier, and Dominique Lorcy
pp 2056 - 2060; DOI:
10.1021/ic026186f
PDF
Luminescent nido-Carborane-Diphosphine Anions [(PR2)2C2B9H10]- (R = Ph, iPr). Modification of Their Luminescence Properties upon Formation of Three-Coordinate Gold(I) Complexes
Olga Crespo, M. Concepción Gimeno, Peter G. Jones, Antonio Laguna, José M. López-de-Luzuriaga, Miguel Monge, Juan L. Pérez, and Miguel A. Ramón
pp 2061 - 2068; DOI:
10.1021/ic0259843
PDF
Unprecedented Chemical Transformation of Benzaldehyde Semicarbazone Mediated by Osmium
Parna Gupta, Falguni Basuli, Shie-Ming Peng, Gene-Hsiang Lee, and Samaresh Bhattacharya
pp 2069 - 2074; DOI:
10.1021/ic026154s
PDF
Porphyrins Linked Directly to the 5,5' Positions of 2,2'-Bipyridine: A New Supramolecular Building Block and Switch
Kai Fan Cheng, Charles Michael Drain, and Klaus Grohmann
pp 2075 - 2083; DOI:
10.1021/ic025985v
PDF
Syntheses and X-ray Structures of Monocyclic, Bicyclic, and Spirocyclic Gallium and Indium Boraamidinates
Tristram Chivers, Chantall Fedorchuk, Gabriele Schatte, and Masood Parvez
pp 2084 - 2093; DOI:
10.1021/ic0206286
PDF
Remarkable Dynamical Opening and Closing of Platinum and Palladium Pentaruthenium Carbido Carbonyl Cluster Complexes
Richard D. Adams, Burjor Captain, Wei Fu, Perry J. Pellechia, and Mark D. Smith
pp 2094 - 2101; DOI:
10.1021/ic020656o
PDF
Solid-State and Solution Studies of {Lnn(SiW11O39)} Polyoxoanions: An Example of Building Block Condensation Dependent on the Nature of the Rare Earth
Pierre Mialane, Laurent Lisnard, Alain Mallard, Jérôme Marrot, Elisabeth Antic-Fidancev, Patrick Aschehoug, Daniel Vivien, and Francis Sécheresse
pp 2102 - 2108; DOI:
10.1021/ic020486f
PDF
Versatile Ligand Behavior of Hydrotris(4-ethyl-3-methyl-5-thioxo-1,2,4-triazolyl)borate. Syntheses and Crystal Structures of Cu(I) and Bi(III) Complexes
Maria Careri, Lisa Elviri, Maurizio Lanfranchi, Luciano Marchiò, Clara Mora, and Maria Angela Pellinghelli
pp 2109 - 2114; DOI:
10.1021/ic025939v
PDF
1H,1H,2H,2H-Perfluoroalkyl-Functionalization of Ni(II), Pd(II), and Pt(II) Mono- and Diphosphine Complexes: Minimizing the Electronic Consequences for the Metal Center
Elwin de Wolf, Ad J. M. Mens, Onno L. J. Gijzeman, Joop H. van Lenthe, Leonardus W. Jenneskens, Berth-Jan Deelman, and Gerard van Koten
pp 2115 - 2124; DOI:
10.1021/ic025770l
PDF
Understanding Structure Does Not Always Explain Reactivity: A Phosphinoamide Anion Reacts as an Iminophosphide Anion
Zhaofu Fei, Rosario Scopelliti, and Paul J. Dyson
pp 2125 - 2130; DOI:
10.1021/ic0262841
PDF
Synthesis and Characterization of Trifluoromethyl Fluoroformyl Peroxycarbonate, CF3OC(O)OOC(O)F
Maximiliano A. Burgos Paci, Plácido García, Fabio E. Malanca, Gustavo A. Argüello, and Helge Willner
pp 2131 - 2135; DOI:
10.1021/ic0261528
PDF
[Cu(H4C3N2S)Cl2]n, an Unprecedented Diazole-Bridged One-Dimensional Copper Halide: Synthesis, Structure, and Magnetic Properties
Jun-Ling Song, Zhen-Chao Dong, Hui-Yi Zeng, Wen-Bo Zhou, Takashi Naka, Qiang Wei, Jiang-Gao Mao, Guo-Cong Guo, and Jin-Shun Huang
pp 2136 - 2140; DOI:
10.1021/ic025976m
PDF
Three- and Four-Coordinate Gold(I) Complexes of 3,6-Bis(diphenylphosphino)pyridazine: Monomers, Polymers, and a Metallocryptand Cage
Vincent J. Catalano, Mark A. Malwitz, Stephen J. Horner, and John Vasquez
pp 2141 - 2148; DOI:
10.1021/ic020601m
PDF
Homoleptic Group 12 Metal Bis(mercaptoimidazolyl)borate Complexes M(BmR)2 (M = Zn, Cd, Hg)
Hamsell M. Alvarez, Thuy B. Tran, Mary A. Richter, Dania M. Alyounes, Daniel Rabinovich, Joseph M. Tanski, and Mariusz Krawiec
pp 2149 - 2156; DOI:
10.1021/ic025780m
PDF
Mixed Dinitrogen-Organocyanamide Complexes of Molybdenum(0) and Their Protic Conversion into Hydrazide and Amidoazavinylidene Derivatives
Sónia M. P. R. M. Cunha, M. Fátima C. Guedes da Silva, and Armando J. L. Pombeiro
pp 2157 - 2164; DOI:
10.1021/ic026176e
PDF
Structural Diversity and Polytypism of Lead Phenylphosphonates: BING-6 and BING-9
Dat T. Tran, Yi-Sheng Kam, Peter Y. Zavalij, and Scott R. J. Oliver
pp 2165 - 2172; DOI:
10.1021/ic0261023
PDF

Issue 7


Synthesis of Uniform CoTe and NiTe Semiconductor Nanocluster Wires through a Novel Coreduction Method
Qing Peng, Yajie Dong, and Yadong Li
pp 2174 - 2175; DOI:
10.1021/ic0262031
PDF
Enhancement of the Phosphorescence of Organic Luminophores upon Interaction with a Mercury Trifunctional Lewis Acid
Mohammad A. Omary, Refaie M. Kassab, Mason R. Haneline, O. Elbjeirami, and François P. Gabbaï
pp 2176 - 2178; DOI:
10.1021/ic034066h
PDF
Self-Assembly of a Polar Open-Framework Uranyl Vanadyl Hexaoxoiodate(VII) Constructed Entirely from Distorted Octahedral Building Units in the First Uranium Hexaoxoiodate: K2[(UO2)2(VO)2(IO6)2O]·H2O
Richard E. Sykora and Thomas E. Albrecht-Schmitt
pp 2179 - 2181; DOI:
10.1021/ic026290x
PDF
Hydrogen-Bonded Superstructures of a Small Host Molecule and Lanthanide Aquo Ions
Ruksanna Ahmad, Ina Dix, and Michaele J. Hardie
pp 2182 - 2184; DOI:
10.1021/ic026071b
PDF
Models for the Lower S States of Photosystem II: A Trinuclear Mixed-Valent MnII/MnIV/MnII Complex
Maria Alexiou, Catherine Dendrinou-Samara, Anastasia Karagianni, Subhashis Biswas, Curtis M. Zaleski, Jeff Kampf, Derek Yoder, James E. Penner-Hahn, Vincent L. Pecoraro, and Dimitris P. Kessissoglou
pp 2185 - 2187; DOI:
10.1021/ic026050h
PDF
Ozone-Water 1:1 Complexes O3-H2O: An Ab Initio Study
Hiroto Tachikawa and Shigeaki Abe
pp 2188 - 2190; DOI:
10.1021/ic0207101
PDF
Hydrogenation and Carbon-Sulfur Bond Hydrogenolysis of Benzothiophene Promoted by Re2(CO)10 and H4Re4(CO)12
Michael A. Reynolds, Ilia A. Guzei, and Robert J. Angelici
pp 2191 - 2193; DOI:
10.1021/ic034035m
PDF
Coordination-Synchronized Trans-Cis Photoisomerization of Bipyridylazobenzene Driven by a Cu(II)/Cu(I) Redox Change
Shoko Kume, Masato Kurihara, and Hiroshi Nishihara
pp 2194 - 2196; DOI:
10.1021/ic034132f
PDF
Uranyl Coordination Environment in Hydrophobic Ionic Liquids: An in Situ Investigation
Ann E. Visser, Mark P. Jensen, Ivan Laszak, Kenneth L. Nash, Gregory R. Choppin, and Robin D. Rogers
pp 2197 - 2199; DOI:
10.1021/ic026302e
PDF
Characterization of Metal Centers in Bioinorganic Complexes Using Ab Initio Calculations of 113Cd Chemical Shifts
Srikanth S. Kidambi and Ayyalusamy Ramamoorthy
pp 2200 - 2202; DOI:
10.1021/ic026165l
PDF
Formation of a Cationic Gold(I) Complex and Disulfide by Oxidation of the Antiarthritic Gold Drug Auranofin
Ahmed A. Mohamed, Jinhua Chen, Alice E. Bruce, Mitchell R. M. Bruce, Jeanette A. Krause Bauer, and David T. Hill
pp 2203 - 2205; DOI:
10.1021/ic026057z
PDF
Lanthanide-Transition Heterometallic Extended Structures with Novel Orthogonal Metalloligand as Building Block
Zheng He, Cheng He, En-Qing Gao, Zhe-Ming Wang, Xiao-Fan Yang, Chun-Sheng Liao, and Chun-Hua Yan
pp 2206 - 2208; DOI:
10.1021/ic026271n
PDF
1H and 19F PGSE Diffusion Studies on Iridium PHOX Complexes: Counterion and Solvent Dependences
Eloísa Martínez-Viviente and Paul S. Pregosin
pp 2209 - 2214; DOI:
10.1021/ic0206600
PDF
Trivalent Lanthanide Interactions with a Terdentate Bis(dialkyltriazinyl)pyridine Ligand Studied by Electrospray Ionization Mass Spectrometry
Sonia Colette, Badia Amekraz, Charles Madic, Laurence Berthon, Gérard Cote, and Christophe Moulin
pp 2215 - 2226; DOI:
10.1021/ic025894y
PDF
Unusual Aryl-Porphyrin Rotational Barriers in Peripherally Crowded Porphyrins
Craig J. Medforth, Raid E. Haddad, Cinzia M. Muzzi, Neal R. Dooley, Laurent Jaquinod, David C. Shyr, Daniel J. Nurco, Marilyn M. Olmstead, Kevin M. Smith, Jian-Guo Ma, and John A. Shelnutt
pp 2227 - 2241; DOI:
10.1021/ic010958a
PDF
Thermically and Electrochemically Induced Isomerization of a (Bis(ferrocene)-cyclam)copper(II) Complex
Christophe Bucher, Jean-Claude Moutet, Jacques Pécaut, Guy Royal, Eric Saint-Aman, Fabrice Thomas, Stéphane Torelli, and Mihaela Ungureanu
pp 2242 - 2252; DOI:
10.1021/ic020632h
PDF
A New Quasi-One-Dimensional Ternary Chalcogenide: Synthesis, Crystal Structure, and Electronic Structure of Nb1+xV1-xS5 (x = 0.18)
Hoseop Yun, Geanha Ryu, Stephen Lee, and Roald Hoffmann
pp 2253 - 2260; DOI:
10.1021/ic0205334
PDF
Verdazyl Radicals as Oligopyridine Mimics: Structures and Magnetic Properties of M(II) Complexes of 1,5-Dimethyl-3-(2,2'-bipyridin-6-yl)-6-oxoverdazyl (M = Mn, Ni, Cu, Zn)
Tosha M. Barclay, Robin G. Hicks, Martin T. Lemaire, and Laurence K. Thompson
pp 2261 - 2267; DOI:
10.1021/ic020520q
PDF
Modeling Anhydrous and Aqua Copper(II) Amino Acid Complexes: A New Molecular Mechanics Force Field Parametrization Based on Quantum Chemical Studies and Experimental Crystal Data
Jasmina Sabolovi, Christofer S. Tautermann, Thomas Loerting, and Klaus R. Liedl
pp 2268 - 2279; DOI:
10.1021/ic025967d
PDF
Incorporation of Aluminum in the Calcium Silicate Hydrate (C-S-H) of Hydrated Portland Cements: A High-Field 27Al and 29Si MAS NMR Investigation
Morten Daugaard Andersen, Hans J. Jakobsen, and Jrgen Skibsted
pp 2280 - 2287; DOI:
10.1021/ic020607b
PDF
Photochemical Investigation of Roussin's Red Salt Esters: Fe2(-SR)2(NO)4
Christa L. Conrado, James L. Bourassa, Christian Egler, Stephen Wecksler, and Peter C. Ford
pp 2288 - 2293; DOI:
10.1021/ic020309e
PDF
Metalloantimalarials: Targeting of P. falciparum Strains with Novel Iron(III) and Gallium(III) Complexes of an Amine Phenol Ligand
Scott E. Harpstrite, Alicia A. Beatty, Silvia D. Collins, Anna Oksman, Daniel E. Goldberg, and Vijay Sharma
pp 2294 - 2300; DOI:
10.1021/ic034036e
PDF
Importance of the C-H···N Weak Hydrogen Bonding on the Coordination Structures of Manganese(III) Porphyrin Complexes
Akira Ikezaki and Mikio Nakamura
pp 2301 - 2310; DOI:
10.1021/ic0206138
PDF
Structure and Magnetic Properties of Tetraarylporphinatomagnesium(II) Electron Transfer Salts of 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane, TCNQF4
Wendy Hibbs, Atta M. Arif, Mark Botoshansky, Menahem Kaftory, and Joel S. Miller
pp 2311 - 2322; DOI:
10.1021/ic020494w
PDF
Homochiral Column Structure of rac- and -Tris(ethylenediamine)cobalt(III) Cyclotriphosphate Dihydrate in Crystal Structures and Cation-Anion Association in Aqueous Solution
Toshio Nakashima, Junichi Mishiro, Masami Ito, Genichiro Kura, Yuichi Ikuta, Naohide Matsumoto, Kiyohiko Nakajima, and Masaaki Kojima
pp 2323 - 2330; DOI:
10.1021/ic0260623
PDF
Novel Inorganic-Organic-Layered Structures: Crystallographic Understanding of Both Phase and Morphology Formations of One-Dimensional CdE (E = S, Se, Te) Nanorods in Ethylenediamine
Zhao-Xiang Deng, Libo Li, and Yadong Li
pp 2331 - 2341; DOI:
10.1021/ic025846d
PDF
Equilibrium, 1H and 13C NMR Spectroscopy, and X-ray Diffraction Studies on the Complexes Bi(DOTA)- and Bi(DO3A-Bu)
Éva Csajbók, Zsolt Baranyai, István Bányai, Erno Brücher, Róbert Király, Anke Müller-Fahrnow, Johannes Platzek, Bernd Radüchel, and Martina Schäfer
pp 2342 - 2349; DOI:
10.1021/ic0261272
PDF
Complexation of Beryllium(II) Ion by Phosphinate Ligands in Aqueous Solution. Synthesis and XRPD Structure Determination of Be[(PhPO2)2CH2](H2O)2
Franco Cecconi, Sixto Dominguez, Norberto Masciocchi, Stefano Midollini, Angelo Sironi, and Alberto Vacca
pp 2350 - 2356; DOI:
10.1021/ic0261979
PDF
A Vanadium(IV) Phosphite with a Pillared Layered Structure: Hydrothermal Synthesis and Characterization of (VO)4(4,4'-bpy)2(HPO3)4
Zhan Shi, Guanghua Li, Dong Zhang, Jia Hua, and Shouhua Feng
pp 2357 - 2361; DOI:
10.1021/ic0261676
PDF
Syntheses and Oxidation of Methyloxorhenium(V) Complexes with Tridentate Ligands
Xiaopeng Shan, Arkady Ellern, Ilia A. Guzei, and James H. Espenson
pp 2362 - 2367; DOI:
10.1021/ic026174u
PDF
29Si Chemical Shift Anisotropies in Calcium Silicates from High-Field 29Si MAS NMR Spectroscopy
Michael Ryan Hansen, Hans J. Jakobsen, and Jrgen Skibsted
pp 2368 - 2377; DOI:
10.1021/ic020647f
PDF
Novel Titanium Compounds for Metal-Organic Chemical Vapor Deposition of Titanium Dioxide Films with an Ultrahigh Deposition Rate
Kyoungja Woo, Wan In Lee, Jong Seung Lee, and Sang Ook Kang
pp 2378 - 2383; DOI:
10.1021/ic0256967
PDF
Rh(I) Coordination Chemistry of Chiral -Aminophosphine(6-arene)chromium Tricarbonyl Ligands
Jean-Michel Camus, Jacques Andrieu, Rinaldo Poli, Philippe Richard, Clara Baldoli, and Stefano Maiorana
pp 2384 - 2390; DOI:
10.1021/ic025588k
PDF
Dimorphism of a New CuI Coordination Polymer:Synthesis, Crystal Structures and Properties of Catena[CuI(2-Iodopyrazine-N)] and Poly[CuI(2-2-Iodopyrazine-N,N')]
Christian Näther, Mario Wriedt, and Inke Jess
pp 2391 - 2397; DOI:
10.1021/ic026007u
PDF
FTIR Spectroscopic Studies of the Stabilities and Reactivities of Hydrogen-Terminated Surfaces of Silicon Nanowires
X. H. Sun, S. D. Wang, N. B. Wong, D. D. D. Ma, S. T. Lee, and Boon K. Teo
pp 2398 - 2404; DOI:
10.1021/ic020723e
PDF
Nanostructured Magnetic Cuprate Cluster: Synthesis, Structure, UV-Vis Spectroscopy, and Magnetic Properties of a New Copper(II) Arsenate NaCuAsO4 Containing Discrete [Cu4O16]24- Clusters
Mutlu Ulutagay-Kartin, Shiou-Jyh Hwu, and Jeffrey A. Clayhold
pp 2405 - 2409; DOI:
10.1021/ic026169q
PDF
Aggregation of PMe3-Stabilized Molybdenum Sulfides and the Catalytic Dehydrogenation of H2S
Daniel E. Schwarz, Thomas B. Rauchfuss, and Scott R. Wilson
pp 2410 - 2417; DOI:
10.1021/ic026215m
PDF
Oxidation of Ni3(dpa)4Cl2 and Cu3(dpa)4Cl2: Nickel-Nickel Bonding Interaction, but No Copper-Copper Bonds
John F. Berry, F. Albert Cotton, Lee M. Daniels, Carlos A. Murillo, and Xiaoping Wang
pp 2418 - 2427; DOI:
10.1021/ic0262740
PDF
Synthesis and Characterization of Three Novel Cation-Containing (NH4+/C3H7NH3+/NH3+C2H4NH3+) Aluminum Diphosphonates
Howard G. Harvey, Simon J. Teat, Chiu C. Tang, Lachlan M. Cranswick, and Martin P. Attfield
pp 2428 - 2439; DOI:
10.1021/ic020641q
PDF
Determination of Ligand-Field Parameters and f-Electronic Structures of Double-Decker Bis(phthalocyaninato)lanthanide Complexes
Naoto Ishikawa, Miki Sugita, Tomoko Okubo, Naohiro Tanaka, Tomochika Iino, and Youkoh Kaizu
pp 2440 - 2446; DOI:
10.1021/ic026295u
PDF
Conformations and Energetics of Sulfur and Selenium Diimides
Heikki M. Tuononen, Reijo J. Suontamo, Jussi U. Valkonen, Risto S. Laitinen, and Tristram Chivers
pp 2447 - 2454; DOI:
10.1021/ic026247+
PDF
Microscopic Approach to the Pseudo-Spin-1/2 Hamiltonian for Kramers Doublets in Exchange Coupled Co(II) Pairs
Andrei V. Palii, Boris S. Tsukerblat, Eugenio Coronado, Juan M. Clemente-Juan, and Juan J. Borrás-Almenar
pp 2455 - 2458; DOI:
10.1021/ic0259686
PDF
A Novel Open Framework Uranyl Molybdate: Synthesis and Structure of (NH4)4[(UO2)5(MoO4)7](H2O)5
S. V. Krivovichev, C. L. Cahill, and P. C. Burns
pp 2459 - 2464; DOI:
10.1021/ic020516e
PDF
Lattice Energy Estimation for Inorganic Ionic Crystals
Daotan Liu, Siyuan Zhang, and Zhijian Wu
pp 2465 - 2469; DOI:
10.1021/ic025902a
PDF
Fe(II) and Fe(III) Mononuclear Complexes with a Pentadentate Ligand Built on the 1,3-Diaminopropane Unit. Structures and Spectroscopic and Electrochemical Properties. Reaction with H2O2
Véronique Balland, Frédéric Banse, Elodie Anxolabéhère-Mallart, Morten Ghiladi, Tony A. Mattioli, Christian Philouze, Geneviève Blondin, and Jean-Jacques Girerd
pp 2470 - 2477; DOI:
10.1021/ic025905n
PDF
Growth of Compound BiIII- VIA-VIIA Crystals with Special Morphologies under Mild Conditions.
Yi Xie, Liying Zhu, Xiuwen Zheng, Xin Yin, and Xiaobo Tian
pp 2478 - 2478; DOI:
10.1021/ic030002v
PDF
Synthesis and Reactions of Cubane-Type Iron-Sulfur-Phosphine Clusters, Including Soluble Clusters of Nuclearities 8 and 16
Hong-Cai Zhou and R. H. Holm:
pp 2478 - 2478; DOI:
10.1021/ic030059h
PDF

Issue 8


"The Frontiers of Inorganic Chemistry"-A Workshop
Richard Eisenberg
pp 2479 - 2479; DOI:
10.1021/ic030078r
PDF
Crystal Structure and Magnetic Properties of Gd2([18]crown-6)2(OH)2(CH3CN)2[Ni(dmit)2]4 Complex Having f- and -Spins
Sadafumi Nishihara, Tomoyuki Akutagawa, Tatsuo Hasegawa, and Takayoshi Nakamura
pp 2480 - 2482; DOI:
10.1021/ic026204t
PDF
Efficient Visible Light Induced Nuclease Activity of a Ternary Mono-1,10-phenanthroline Copper(II) Complex Containing 2-(Methylthio)ethylsalicylaldimine
Shanta Dhar and Akhil R. Chakravarty
pp 2483 - 2485; DOI:
10.1021/ic026241k
PDF
Excited-State Acid-Base Chemistry: Evidence for a Dissociative Excited State
Jianwei Fan, Roy Helmy, Abe Kassis, Amanda Grunseich, Peter Mangubat, Charles Hicks, Nathan Stevens, and Harry D. Gafney
pp 2486 - 2488; DOI:
10.1021/ic030055c
PDF
Requirements for Functional Models of the Iron Hydrogenase Active Site: D2/H2O Exchange Activity in {(-SMe)(-pdt)[Fe(CO)2(PMe3)]2+}[BF4-]
Irene P. Georgakaki, Matthew L. Miller, and Marcetta Y. Darensbourg
pp 2489 - 2494; DOI:
10.1021/ic026005+
PDF
Investigating the Stability of the Peroxide Bridge in (-oxo)- and Bis(-oxo)manganese Clusters
Christopher D. Delfs and Robert Stranger
pp 2495 - 2503; DOI:
10.1021/ic0205740
PDF
Structures and Bonding of the Sandwich Complexes [Ti(5-E5)2]2- (E = CH, N, P, As, Sb): A Theoretical Study
Matthias Lein, Jan Frunzke, and Gernot Frenking
pp 2504 - 2511; DOI:
10.1021/ic020592h
PDF
Magnetic Studies on Hexaiodorhenate(IV) Salts of Univalent Cations. Spin Canting and Magnetic Ordering in K2[ReI6] with Tc = 24 K
Ricardo González, Raúl Chiozzone, Carlos Kremer, Giovanni De Munno, Francesco Nicolò, Francesc Lloret, Miguel Julve, and Juan Faus
pp 2512 - 2518; DOI:
10.1021/ic020531j
PDF
Heterodimetallic Compounds Assembled from Ferrocenedicarboxylato and Ferrocenecarboxylato Ligands
Guo Dong, Li Yu-ting, Duan Chun-ying, Mo Hong, and Meng Qing-jin
pp 2519 - 2530; DOI:
10.1021/ic0205132
PDF
Synthesis and Spectroscopic and Structural Studies of a New Cadmium(II)-Citrate Aqueous Complex. Potential Relevance to Cadmium(II)-Citrate Speciation and Links to Cadmium Toxicity
M. Dakanali, E. T. Kefalas, C. P. Raptopoulou, A. Terzis, T. Mavromoustakos, and A. Salifoglou
pp 2531 - 2537; DOI:
10.1021/ic0205029
PDF
Polymorphism of Heptalithium Nitridovanadate(V) Li7[VN4]
R. Niewa, D. Zherebtsov, and Z. Hu
pp 2538 - 2544; DOI:
10.1021/ic020653b
PDF
Syntheses of Two New 1D and 3D Networks of Cu(II) and Co(II) Using Malonate and Urotropine as Bridging Ligands: Crystal Structures and Magnetic Studies
Sanjit Konar, Partha Sarathi Mukherjee, Michael G. B. Drew, Joan Ribas, and Nirmalendu Ray Chaudhuri
pp 2545 - 2552; DOI:
10.1021/ic020549u
PDF
Construction of the Multidecker Anthracene-Silver(I) System by Intramolecular - Interactions
Megumu Munakata, Liang Ping Wu, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Yusaku Suenaga, Tetsuhiro Ohta, and Hisashi Konaka
pp 2553 - 2558; DOI:
10.1021/ic020379l
PDF
Novel Routes to Cu(salicylaldimine) Covalently Bound to Silica: Combined Pulse EPR and in Situ Attenuated Total Reflection-IR Studies of the Immobilization
Eamonn F. Murphy, Davide Ferri, Alfons Baiker, Sabine Van Doorslaer, and Arthur Schweiger
pp 2559 - 2571; DOI:
10.1021/ic020298p
PDF
New Rh(I) and Rh(III) Bisimidazol-2-ylidene Complexes: Synthesis, Reactivity, and Molecular Structures
Macarena Poyatos, Mercedes Sanaú, and Eduardo Peris
pp 2572 - 2576; DOI:
10.1021/ic026212+
PDF
The Effect of Ligand Scaffold Size on the Stability of Tripodal Hydroxypyridonate Gadolinium Complexes
Brendon O'Sullivan, Dan M. J. Doble, Marlon K. Thompson, Carsten Siering, Jide Xu, Mauro Botta, Silvio Aime, and Kenneth N. Raymond
pp 2577 - 2583; DOI:
10.1021/ic0261575
PDF
Compositional and Structural Variety of Diphenyllead(IV) Complexes Obtained by Reaction of Diphenyllead Dichloride with Thiosemicarbazones
José S. Casas, Eduardo E. Castellano, J. Ellena, María S. García Tasende, Agustín Sánchez, José Sordo, and María J. Vidarte
pp 2584 - 2595; DOI:
10.1021/ic026219r
PDF
Reactions of the Perfluoroalkyltriazapentadiene Ph2N3C2(C3F7)2H with Acids, Bases, and Water
A. R. Siedle, Robert J. Webb, Myles Brostrom, Shih-Hung Chou, David A. Weil, Richard A. Newmark, Fred E. Behr, and Victor G. Young, Jr.
pp 2596 - 2601; DOI:
10.1021/ic020716q
PDF
Structural and Magnetic Behavior of the Kinked Chain Cu(hfac)2(tan) and Its Relevance to Cu(NO3)2(tan) (hfac = Hexafluoroacetylacetonate; tan = 1,4,5-Triazanaphthalene)
Jamie L. Manson
pp 2602 - 2605; DOI:
10.1021/ic026159p
PDF
Structure, Stability, and Electronic and NMR Properties of Various Oxo- and Nitrido-Derivatives of [L(Salen)Mn(III)]+, Where L = None and Imidazole. A Density Functional Study
Ilja V. Khavrutskii, Djamaladdin G. Musaev, and Keiji Morokuma
pp 2606 - 2621; DOI:
10.1021/ic026094q
PDF
The Structure of the FeNO Group in Two Metastable States (MS1 and MS2) of the Nitroprusside Anion in Na2[Fe(CN)5NO]·2H2O. Infrared Spectra and Quantum Chemistry Calculations for the Normal and the 15NO and N18O Isotopic Substituted Substance
M. E. Chacón Villalba, Jorge A. Güida, Eduardo L. Varetti, and Pedro J. Aymonino
pp 2622 - 2627; DOI:
10.1021/ic026095i
PDF
Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies
Amanda C. Bean, Tyler A. Sullens, Wolfgang Runde, and Thomas E. Albrecht-Schmitt
pp 2628 - 2633; DOI:
10.1021/ic0262076
PDF
Relative Stability in - and -Wells-Dawson Heteropolyanions: A DFT Study of [P2M18O62]n- (M = W and Mo) and [P2W15V3O62]n-
Xavier López, Carles Bo, Josep-M. Poblet, and José Pedro Sarasa
pp 2634 - 2638; DOI:
10.1021/ic0262280
PDF
End-On and Side-On Peroxo Derivatives of Non-Heme Iron Complexes with Pentadentate Ligands: Models for Putative Intermediates in Biological Iron/Dioxygen Chemistry
Gerard Roelfes, Vladislav Vrajmasu, Kui Chen, Raymond Y. N. Ho, Jan-Uwe Rohde, Charon Zondervan, Rene M. la Crois, Ebe P. Schudde, Martin Lutz, Anthony L. Spek, Ronald Hage, Ben L. Feringa, Eckard Münck, and Lawrence Que, Jr.
pp 2639 - 2653; DOI:
10.1021/ic034065p
PDF
AgC(CN)3-Based Coordination Polymers
Brendan F. Abrahams, Stuart R. Batten, Bernard F. Hoskins, and Richard Robson
pp 2654 - 2664; DOI:
10.1021/ic026189s
PDF
Thorium(IV) Complexes of Bidentate Hydroxypyridinonates1
Jide Xu, Donald W. Whisenhunt, Jr., Alan C. Veeck, Linda C. Uhlir, and Kenneth N. Raymond
pp 2665 - 2674; DOI:
10.1021/ic0259888
PDF
Li, Ti(III), and Ti(IV) Trisamidotriazacyclononane Complexes. Syntheses, Reactivity, and Structures
Alberto R. Dias, Ana M. Martins, José R. Ascenso, Humberto Ferreira, M. Teresa Duarte, and Rui T. Henriques
pp 2675 - 2682; DOI:
10.1021/ic026161g
PDF
Synthesis and Characterization of (Octaaryltetraazaporphyrinato)indium(III) Complexes for Optical Limiting
Sergej Vagin, Markus Barthel, Danilo Dini, and Michael Hanack
pp 2683 - 2694; DOI:
10.1021/ic0205738
PDF
Structural Analyses and Magnetic Properties of 3D Coordination Polymeric Networks of Nickel(II) Maleate and Manganese(II) Adipate with the Flexible 1,2-Bis(4-pyridyl)ethane Ligand
Partha Sarathi Mukherjee, Sanjit Konar, Ennio Zangrando, Talal Mallah, Joan Ribas, and Nirmalendu Ray Chaudhuri
pp 2695 - 2703; DOI:
10.1021/ic026150n
PDF
Model Complexes for Metallated Polythiophenes: Gold(I) and Palladium(II) Complexes of Bis(diphenylphosphino)oligothiophenes
Olivier Clot, Yumi Akahori, Carolyn Moorlag, Daniel B. Leznoff, Michael O. Wolf, Raymond J. Batchelor, Brian O. Patrick, and Mikita Ishii
pp 2704 - 2713; DOI:
10.1021/ic0258328
PDF
Rapid Solid-State Metathesis Routes to Aluminum Nitride
Rebecca A. Janes, Madeleine A. Low, and Richard B. Kaner
pp 2714 - 2719; DOI:
10.1021/ic026143z
PDF
A New Type of Anionic Metal Dicyanamide Extended Networks through [Cu(N4-macrocycle)]2+ Cation Templation. Structure and Magnetic Properties
Enrique Colacio, Francesc Lloret, Ikram Ben Maimoun, Raikko Kivekäs, Reijo Sillanpää, and José Suárez-Varela
pp 2720 - 2724; DOI:
10.1021/ic026234w
PDF
Bond Valence Sums in Coordination Chemistry. The Calculation of the Oxidation State of Samarium in Complexes Containing Samarium Bonded Only to Oxygen
Gus J. Palenik
pp 2725 - 2728; DOI:
10.1021/ic025880s
PDF
New High-Dimensional Networks Based on Polyoxometalate and Crown Ether Building Blocks
Yangguang Li, Na Hao, Enbo Wang, Mei Yuan, Changwen Hu, Ninghai Hu, and Hengqing Jia
pp 2729 - 2735; DOI:
10.1021/ic026172+
PDF
Aggregation Patterns in ,'-Stabilized Carbanions: Assembly of a Sodium Cage Polymer by Slip-Stacking of Dimers
Kenneth W. Henderson, Alan R. Kennedy, and Dugald J. MacDougall
pp 2736 - 2741; DOI:
10.1021/ic026194w
PDF
Two New Groups of Homoleptic Rare Earth Pyridylbenzimidazolates: (NC12H8(NH)2)[Ln(N3C12H8)4] with Ln = Y, Tb, Yb, and [Ln(N3C12H8)2(N3C12H9)2][Ln(N3C12H8)4](N3C12H9)2 with Ln = La, Sm, Eu
Klaus Müller-Buschbaum and Catharina C. Quitmann
pp 2742 - 2750; DOI:
10.1021/ic020681u
PDF
A Density Functional Evaluation of an Fe(III)-Fe(IV) Model Diiron Cluster: Comparisons with Ribonucleotide Reductase Intermediate X
Wen-Ge Han, Timothy Lovell, Tiqing Liu, and Louis Noodleman
pp 2751 - 2758; DOI:
10.1021/ic020465l
PDF
Localized versus Delocalized Bonding in the K5Bi4 Metallic Salt
Antonio Rodríguez-Fortea and Enric Canadell
pp 2759 - 2763; DOI:
10.1021/ic026156c
PDF
Redox-Adaptable Copper Hosts. Pyridazine-Linked Cryptands Accommodate Copper in a Range of Redox States
Sally Brooker, Janna D. Ewing, Tanya K. Ronson, Charles J. Harding, Jane Nelson, and David J. Speed
pp 2764 - 2773; DOI:
10.1021/ic0261124
PDF
Evaluation of [Co(gly)3]- as a 35Cl- NMR Shift Reagent for Cellular Studies
Conrad F. Diven, Fei Wang, Abde M. Abukhdeir, Wajeeh Salah, Brian T. Layden, Carlos F. G. C. Geraldes, and Duarte Mota de Freitas
pp 2774 - 2782; DOI:
10.1021/ic0258680
PDF
Dinuclear Iron(II)-Cyanocarbonyl Complexes Linked by Two/Three Bridging Ethylthiolates: Relevance to the Active Site of [Fe] Hydrogenases
Wen-Feng Liaw, Wen-Ting Tsai, Hung-Bin Gau, Chien-Ming Lee, Shin-Yuan Chou, Wen-Yuan Chen, and Gene-Hsiang Lee
pp 2783 - 2788; DOI:
10.1021/ic0261225
PDF
Blue Luminescent Rigid Molecular Rods Bearing N-7-Azaindolyl and 2,2'-Dipyridylamino and Their Zn(II) and Ag(I) Complexes
Youngjin Kang, Corey Seward, Datong Song, and Suning Wang
pp 2789 - 2797; DOI:
10.1021/ic0262637
PDF
Syntheses and Structural Characterization of the Heavier Alkali-Metal Stannates Bearing the Tripodal Triamino Framework: Structural Trends in the Series of [MeSi{SiMe2N(4-CH3C6H4)}3Sn][M] (M = Na, K, Rb)
Matthias Lutz, Matti Haukka, Tapani A. Pakkanen, and Lutz H. Gade
pp 2798 - 2804; DOI:
10.1021/ic026226f
PDF
Amidines Derived from Pt(IV)-Mediated Nitrile-Amino Alcohol Coupling and Their Zn(II)-Catalyzed Conversion into Oxazolines
Anastassiya V. Makarycheva-Mikhailova, Vadim Yu. Kukushkin, Alexey A. Nazarov, Dmitrii A. Garnovskii, Armando J. L. Pombeiro, Matti Haukka, Bernhard K. Keppler, and Markus Galanski
pp 2805 - 2813; DOI:
10.1021/ic034070t
PDF
High-Pressure Raman Spectroscopic Study of the Ammonia-Borane Complex. Evidence for the Dihydrogen Bond
Simon Trudel and Denis F. R. Gilson
pp 2814 - 2816; DOI:
10.1021/ic026275s
PDF

Issue 9


Toward Novel DNA Binding Metal Complexes: Structure and Basic Kinetic Data of [M(9MeG)2(CH3OH)(CO)3]+ (M = 99Tc, Re)
Fabio Zobi, Bernhard Spingler, Thomas Fox, and Roger Alberto
pp 2818 - 2820; DOI:
10.1021/ic030028m
PDF
Selective Ligation to Sterically Isolated Metallophthalocyanines
Mutsumi Kimura, Ayumu Sakaguchi, Kazuchika Ohta, Kenji Hanabusa, Hirofusa Shirai, and Nagao Kobayashi
pp 2821 - 2823; DOI:
10.1021/ic026149o
PDF
Cerium(III) and Neodymium(III) Amides Derived from a Chelating 2-Pyridyl Amido Ligand
Steven C. F. Kui, Hung-Wing Li, and Hung Kay Lee
pp 2824 - 2826; DOI:
10.1021/ic0340534
PDF
Novel Layered Ruthenium Diphosphonate Containing a Mixed Valent Diruthenium Paddlewheel Core
Xiao-Yi Yi, Li-Min Zheng, Wei Xu, and Shouhua Feng
pp 2827 - 2829; DOI:
10.1021/ic034069u
PDF
Direct Ion Exchange of Tris(2,2'-bipyridine)ruthenium(II) into an -Zirconium Phosphate Framework
Angel A. Martí and Jorge L. Colón
pp 2830 - 2832; DOI:
10.1021/ic025548g
PDF
Structural Measure of Metal-Ligand Covalency from the Bonding in Carboxylate Ligands
Rosalie K. Hocking and Trevor W. Hambley
pp 2833 - 2835; DOI:
10.1021/ic034198a
PDF
Formation and Structure of fac-[Mo(CO)3(C2H2[N(CH2But)]2Ge)3]: The First Structurally Characterized Group 6 Transition Metal Complex of an Unsaturated Diaminogermylene
Olaf Kühl, Peter Lönnecke, and Joachim Heinicke
pp 2836 - 2838; DOI:
10.1021/ic0259991
PDF
Rational Design of Molecular Sheets Composed of Interconnecting Eight- and Twenty-Four-Membered Rings: Use of Lithiated Aggregates To Control Network Assembly
Kenneth W. Henderson, Alan R. Kennedy, Lynn Macdonald, and Dugald J. MacDougall
pp 2839 - 2841; DOI:
10.1021/ic034115q
PDF
Monolayer, Bilayer, Multilayers: Evolving Magnetic Behavior in Langmuir-Blodgett Films Containing a Two-Dimensional Iron-Nickel Cyanide Square Grid Network
Jeffrey T. Culp, Ju-Hyun Park, Mark W. Meisel, and Daniel R. Talham
pp 2842 - 2848; DOI:
10.1021/ic026158x
PDF
Transition from Hydrogen Atom to Hydride Abstraction by Mn4O4(O2PPh2)6 versus [Mn4O4(O2PPh2)6]+: O-H Bond Dissociation Energies and the Formation of Mn4O3(OH)(O2PPh2)6
Thomas G. Carrell, Emilie Bourles, Matthew Lin, and G. Charles Dismukes
pp 2849 - 2858; DOI:
10.1021/ic025977e
PDF
Ruthenium Dihydrogen Complexes with Wide Bite Angle Diphosphines
Karina Almeida Leñero, Mirko Kranenburg, Yannick Guari, Paul C. J. Kamer, Piet W. N. M. van Leeuwen, Sylviane Sabo-Etienne, and Bruno Chaudret
pp 2859 - 2866; DOI:
10.1021/ic020577c
PDF
Density Functional Calculations on Electronic Circular Dichroism Spectra of Chiral Transition Metal Complexes
Jochen Autschbach, Francisco E. Jorge, and Tom Ziegler
pp 2867 - 2877; DOI:
10.1021/ic020580w
PDF
Kinetics and Mechanism of Ligand Substitution in Bis(N-alkylsalicylaldiminato)oxovanadium(IV) Complexes
Horst Elias, Sibylle Schwartze-Eidam, and Klaus Jürgen Wannowius
pp 2878 - 2885; DOI:
10.1021/ic020682m
PDF
Estimation of Enthalpy Data for Reactions Involving Gas Phase Ions Utilizing Lattice Potential Energies: Fluoride Ion Affinities (FIA) and pF- Values of mSbF5(l) and mSbF5(g) (m = 1, 2, 3), AsF5(g), AsF5·SO2(c). Standard Enthalpies of Formation: fH(SbmF5m+1-,g) (m = 1, 2, 3), fH(AsF6-,g), and fH(NF4+,g)
H. Donald Brooke Jenkins, H. K. Roobottom, and Jack Passmore
pp 2886 - 2893; DOI:
10.1021/ic0206544
PDF
Tetramethylphosphonium Fluoride: "Naked" Fluoride and Phosphorane
Andreas Kornath, F. Neumann, and H. Oberhammer
pp 2894 - 2901; DOI:
10.1021/ic020663c
PDF
Synthesis and Structural Studies of Binuclear Platinum(II) Complexes with a Novel Phosphorus-Nitrogen-Phosphorus Ligand
Laurent Barloy, Grégory Malaisé, Shailesh Ramdeehul, Claire Newton, John A. Osborn, and Nathalie Kyritsakas
pp 2902 - 2907; DOI:
10.1021/ic020668+
PDF
Electron Donor-Acceptor Dyads Based on Ruthenium(II) Bipyridine and Terpyridine Complexes Bound to Naphthalenediimide
Olof Johansson, Magnus Borgström, Reiner Lomoth, Magnus Palmblad, Jonas Bergquist, Leif Hammarström, Licheng Sun, and Björn Åkermark
pp 2908 - 2918; DOI:
10.1021/ic020420k
PDF
Adjacent- versus Remote-Site Electron Injection in TiO2 Surfaces Modified with Binuclear Ruthenium Complexes
Bobak Gholamkhass, Kazuhide Koike, Nobuaki Negishi, Hisao Hori, Taizo Sano, and Koji Takeuchi
pp 2919 - 2932; DOI:
10.1021/ic0341237
PDF
Superconductivity of Metal Deficient Silicon Clathrate Compounds, Ba8-xSi46 (0 < x 1.4)
Hiroshi Fukuoka, Junichi Kiyoto, and Shoji Yamanaka
pp 2933 - 2937; DOI:
10.1021/ic020676q
PDF
Aminomethyl-bipyridine Bearing Two Flexible Nitronyl-nitroxide Arms: A New Podand for Complexation of Transition Metals in a Facial or Meridional Conformation
Christophe Stroh, Elie Belorizky, Philippe Turek, Hélène Bolvin, and Raymond Ziessel
pp 2938 - 2949; DOI:
10.1021/ic020484v
PDF
Self-Assembled Dinuclear, Trinuclear, Tetranuclear, Pentanuclear, and Octanuclear Ni(II) Complexes of a Series of Polytopic Diazine Based Ligands: Structural and Magnetic Properties
Zhiqiang Xu, Laurence K. Thompson, Victoria A. Milway, Liang Zhao, Timothy Kelly, and David O. Miller
pp 2950 - 2959; DOI:
10.1021/ic0206950
PDF
Synthesis and Characterization of Novel 99gTc(V) and Re(V) Complexes with Water-Soluble Tetraaza Diamido Dipyridino Ligands: Single-Crystal X-ray Structural Investigations of Mono- and Dinuclear Complexes
Laszlo Kurti, Dioni Papagiannopoulou, Minas Papadopoulos, Ioannis Pirmettis, Catherine P. Raptopoulou, Aris Terzis, Efstratios Chiotellis, Michael Harmata, Robert R. Kuntz, and Raghoottama S. Pandurangi
pp 2960 - 2967; DOI:
10.1021/ic020434q
PDF
Synthesis, Crystal Structures, and Thermal and Thermodynamic Properties of Dimorphic Copper(I) Coordination Polymers
Christian Näther and Inke Jess
pp 2968 - 2976; DOI:
10.1021/ic026181i
PDF
Self-Assembly between Silver(I) and Di- and Tri-2-pyridines with Flexible Spacer: Formation of Discrete Metallocycle versus Coordination Polymer
Dong Mok Shin, In Su Lee, Young-A Lee, and Young Keun Chung
pp 2977 - 2982; DOI:
10.1021/ic0260163
PDF
Cyano-Bridged Homometallic 1-D and Bimetallic 2-D Assemblies: Synthesis, Structures, and Magnetic Properties of [Ni(baepn)(CN)]n(ClO4)n and [Ni(baepn)]2n[Fe(CN)6]n(H2O)8n
Ja-eung Koo, Do-hyeon Kim, Yaung-Soo Kim, and Youngkyu Do
pp 2983 - 2987; DOI:
10.1021/ic020686r
PDF
Synthesis and Characterization of Mononuclear Iron Silanethiolato Complexes Containing an Unsupported Fe-S-Si Bond System: X-ray Crystal Structure of CpFe(CO)2SSiPh3 and Its Reaction with SO2
István Kovács, Francine Bélanger-Gariépy, and Alan Shaver
pp 2988 - 2991; DOI:
10.1021/ic030049g
PDF
Oxidative Cleavage of DNA by a New Ferromagnetic Linear Trinuclear Copper(II) Complex in the Presence of H2O2/Sodium Ascorbate
M. González-Álvarez, G. Alzuet, J. Borrás, B. Macías, and A. Castiñeiras
pp 2992 - 2998; DOI:
10.1021/ic020611n
PDF
Adamantane-like Cluster Complexes of Mixed-Valent Copper-Copper and Nickel-Copper Thiolates
Matthew L. Miller, Said A. Ibrahim, Melissa L. Golden, and Marcetta Y. Darensbourg
pp 2999 - 3007; DOI:
10.1021/ic0262684
PDF
Synthesis, Characterization, and Theoretical Studies of Group 4 Amido Hydrotris(pyrazolyl)borate Complexes
Hu Cai, Wai Han Lam, Xianghua Yu, Xiaozhan Liu, Zhong-Zhi Wu, Tianniu Chen, Zhenyang Lin, Xue-Tai Chen, Xiao-Zeng You, and Ziling Xue
pp 3008 - 3015; DOI:
10.1021/ic026063v
PDF
Synthesis and Characterization of Reduced Heme and Heme/Copper Carbonmonoxy Species
Ryan M. Kretzer, Reza A. Ghiladi, Estelle L. Lebeau, Hong-Chang Liang, and Kenneth D. Karlin
pp 3016 - 3025; DOI:
10.1021/ic020521i
PDF
One-Dimensional Collective Electronic Effects in the Helically Stacked Cs2[Ni(CN)4]·H2O and Cs2[Pt(CN)4]·H2O: X-ray Structure, Polarized Specular Reflectance, and ZINDO Calculations
Jeffrey B. Cornelius, Robert M. Trapp, Terry J. Delord, Frank R. Fronczek, Steven F. Watkins, Jill Jasin Orosz, and Ronald L. Musselman
pp 3026 - 3035; DOI:
10.1021/ic026101a
PDF
Na6TlSb4: Synthesis, Structure, and Bonding. An Electron-Rich Salt with a Chain Conformation and a Tl-Tl Bond Length Determined by the Cation
Bin Li, Lisheng Chi, and John D. Corbett
pp 3036 - 3042; DOI:
10.1021/ic020728b
PDF
Structure of 1-Thia-closo-dodecaborane(11), 1-SB11H11, as Determined by Microwave Spectroscopy Complemented by Quantum Chemical Calculations
Harald Mllendal, Svein Samdal, Josef Holub, and Drahomír Hnyk
pp 3043 - 3046; DOI:
10.1021/ic034019p
PDF
Minor Groove Site Coordination of Adenine by Platinum Group Metal Ions: Effects on Basicity, Base Pairing, and Electronic Structure
David Amantia, Clayton Price, Michelle A. Shipman, Mark R. J. Elsegood, William Clegg, and Andrew Houlton
pp 3047 - 3056; DOI:
10.1021/ic020657g
PDF
Synthesis and Structural, Electrochemical, and Optical Properties of Ru(II) Complexes with Azobis(2,2'-bipyridine)s
Joe Otsuki, Nobuyuki Omokawa, Kenji Yoshiba, Isao Yoshikawa, Tetsuo Akasaka, Tomoyoshi Suenobu, Toshio Takido, Koji Araki, and Shunichi Fukuzumi
pp 3057 - 3066; DOI:
10.1021/ic026040g
PDF
Tetrakis(imidazolyl)borate-Based Coordination Polymers: Group II Network Solids, M[B(Im)4]2(H2O)2 (M = Mg, Ca, Sr)
Barton H. Hamilton, Kathryn A. Kelly, Wilhelm Malasi, and Christopher J. Ziegler
pp 3067 - 3073; DOI:
10.1021/ic026244x
PDF
Predicted Group 4 Tetra-azides M(N3)4 (M = Ti-Hf, Th): The First Examples of Linear M-NNN Coordination
Laura Gagliardi and Pekka Pyykkö
pp 3074 - 3078; DOI:
10.1021/ic034122e
PDF
Perfluoromethyl Fluorocarbonyl Peroxide, CF3OOC(O)F: Structure, Conformations, and Vibrational Spectra Studied by Experimental and Theoretical Methods
Frank Trautner, Khodayar Gholivand, Plácido García, Helge Willner, Mauricio F. Erben, Carlos O. Della Védova, and Heinz Oberhammer
pp 3079 - 3085; DOI:
10.1021/ic0262583
PDF
Complexation of Diphenyl(phenylacetenyl)phosphine to Rhodium(III) Tetraphenyl Porphyrins: Synthesis and Structural, Spectroscopic, and Thermodynamic Studies
Eugen Stulz, Sonya M. Scott, Andrew D. Bond, Sijbren Otto, and Jeremy K. M. Sanders
pp 3086 - 3096; DOI:
10.1021/ic026257a
PDF
Large Scale Synthesis of Dysprosium and Neodymium Diiodides
William J. Evans, Nathan T. Allen, Penny S. Workman, and Jorg C. Meyer
pp 3097 - 3099; DOI:
10.1021/ic0300316
PDF
Kinetically Controlled Synthesis of Wurtzite ZnS Nanorods through Mild Thermolysis of a Covalent Organic-Inorganic Network
Xijian Chen, Huifang Xu, Ningsheng Xu, Fenghua Zhao, Wenjiao Lin, Gang Lin, Yunlong Fu, Zhenli Huang, Hezhou Wang, and Mingmei Wu
pp 3100 - 3106; DOI:
10.1021/ic025848y
PDF
New Vanadium Phosphate {[(phen)VIVO]2(VV2O5)(HPO4)}n with Chiral Layer Architecture
Chao Qin, Lin Xu, Yongge Wei, Xinlong Wang, and Fengyan Li
pp 3107 - 3110; DOI:
10.1021/ic026256i
PDF
Dynamical Intramolecular Metal-to-Metal Ligand Exchange of Phosphine and Thioether Ligands in Derivatives PtRu5(CO)16(6-C)
Richard D. Adams, Burjor Captain, Wei Fu, and Perry J. Pellechia
pp 3111 - 3118; DOI:
10.1021/ic0207000
PDF
New Two-Dimensional Metal-Organic Networks Constructed from 1,2,4,5-Benzenetetracarboxylate and Chelate Ligands
Yangguang Li, Na Hao, Ying Lu, Enbo Wang, Zhenhui Kang, and Changwen Hu
pp 3119 - 3124; DOI:
10.1021/ic026306j
PDF
A Novel Series of Materials Composed of Arrays of Vanadium Oxide Container Molecules, {V18O42(X)} (X = H2O, Cl-, Br-): Synthesis and Characterization of [M2(H2N(CH2)2NH2)5][{M(H2N(CH2)2NH2)2}2V18O42(X)]· 9H2O (M = Zn, Cd)
M. Ishaque Khan, Elizabeth Yohannes, and Robert J. Doedens
pp 3125 - 3129; DOI:
10.1021/ic025889u
PDF
Ce10Cl4Ga5 and Ln3ClGa4 (Ln = La, Ce): Reduced Halides or Oxidized Intermetallics?
Chong Zheng, Hansjürgen Mattausch, Oliver Oeckler, and Arndt Simon
pp 3130 - 3135; DOI:
10.1021/ic026086+
PDF
Synthesis and Structures of the First Bismuth-Ester Complexes Using Heterobifunctional Thiolate Anchored Ligands and Mass Spectrometric Identification of Ligand-Bridged Derivatives
Glen G. Briand, Neil Burford, Melanie D. Eelman, T. Stanley Cameron, and Katherine N. Robertson
pp 3136 - 3141; DOI:
10.1021/ic0261934
PDF
Interaction of Cd and Zn with Biologically Important Ligands Characterized Using Solid-State NMR and ab Initio Calculations
Srikanth S. Kidambi, Dong-Kuk Lee, and A. Ramamoorthy
pp 3142 - 3151; DOI:
10.1021/ic026287d
PDF
Synthesis and Crystal Structure of Sr2AlH7: A New Structural Type of Alkaline Earth Aluminum Hydride
Qing-An Zhang, Yumiko Nakamura, Ken-ich Oikawa, TakashiKamiyama, and Etsuo Akiba
pp 3152 - 3152; DOI:
10.1021/ic0300363
PDF

Issue 10


Structural and Catalytic Properties of Bis(guanidine)copper(I) Halides
Sarah H. Oakley, Martyn P. Coles, and Peter B. Hitchcock
pp 3154 - 3156; DOI:
10.1021/ic034213b
PDF
Structure of a Terbium(III)-Quinizarine Complex: The First Crystallographic Model for Metalloanthracyclines
Massimo Di Vaira, Pierluigi Orioli, Francesca Piccioli, Bruno Bruni, and Luigi Messori
pp 3157 - 3159; DOI:
10.1021/ic034020o
PDF
A New Ligand System Based on a Bipyridine-Functionalized Calix[4]arene Backbone Leading to Mono- and Bimetallic Complexes
Reto Dorta, Linda J. W. Shimon, Haim Rozenberg, Yehoshoa Ben-David, and David Milstein
pp 3160 - 3167; DOI:
10.1021/ic020643a
PDF
Novel Metal-Organic Frameworks with Specific Topology from New Tripodal Ligands: 1,3,5-Tris(1-imidazolyl)benzene and 1,3-Bis(1-imidazolyl)-5-(imidazol-1-ylmethyl)benzene
Jian Fan, Wei-Yin Sun, Taka-aki Okamura, Wen-Xia Tang, and Norikazu Ueyama
pp 3168 - 3175; DOI:
10.1021/ic0206847
PDF
Ansa versus Spiro Substitution of Cyclophosphazenes: Is Fluorination Essential for Ansa to Spiro Transformation of Cyclophosphazenes?
K. Muralidharan, P. Venugopalan, and Anil J. Elias
pp 3176 - 3182; DOI:
10.1021/ic034119v
PDF
NaCl/KCl Flux Single Crystal Growth and Crystal Structure of the New Quaternary Mixed-Metal Pnictide: BaCuZn3As3
Tadashi C. Ozawa and Susan M. Kauzlarich
pp 3183 - 3186; DOI:
10.1021/ic034061k
PDF
Synthesis and Properties of Rhodium(III) Porphyrin Cyclic Tetramer and Cofacial Dimer
Keiko Fukushima, Kenji Funatsu, Akio Ichimura, Yoichi Sasaki, Masamitsu Suzuki, Tetsuaki Fujihara, Kiyoshi Tsuge, and Taira Imamura
pp 3187 - 3193; DOI:
10.1021/ic020652j
PDF
Synthesis, Structure, Electrical Properties, and Band Structure Calculations of TiAsTe
Fu Qiang Huang, Christine Flaschenriem, Paul Brazis, Carl R. Kannewurf, and James A Ibers
pp 3194 - 3198; DOI:
10.1021/ic020688b
PDF
Synthesis of Mono- and Dihalogenated Derivatives of (Me2S)2B12H10 and Palladium-Catalyzed Boron-Carbon Cross-Coupling Reactions of the Iodides with Grignard Reagents
Roman G. Kultyshev, Shengming Liu, Hoitung T. Leung, Jianping Liu, and Sheldon G. Shore
pp 3199 - 3207; DOI:
10.1021/ic020600u
PDF
Molecular and Electronic Structures of Iron(II)/(III) Complexes Containing N,S-Coordinated, Closed-Shell o-Aminothiophenolato(1-) and o-Iminothiophenolato(2-) Ligands
Prasanta Ghosh, Ameerunisha Begum, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt
pp 3208 - 3215; DOI:
10.1021/ic020617c
PDF
Novel Chloride-Centered Discrete CuI8 Cubic Clusters Containing Diselenophosphate Ligands. Syntheses and Structures of {Cu8(8-Cl)[Se2P(OR)2]6}(PF6) (R = Et, Pr, iPr)1
C. W. Liu, Chiu-Mine Hung, Bidyut Kumar Santra, Hsiu-Chih Chen, Hsin-Hsueh Hsueh, and Ju-Chung Wang
pp 3216 - 3220; DOI:
10.1021/ic020732n
PDF
Preparation and Magnetic Properties of Mn(hfac)2-Complexes of 2-(5-Pyrimidinyl)- and 2-(3-Pyridyl)-Substituted Nitronyl Nitroxides
Keiji Okada, Osami Nagao, Hiroki Mori, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Yasutaka Kitagawa, and Kizashi Yamaguchi
pp 3221 - 3228; DOI:
10.1021/ic0207193
PDF
A Rational Approach to the Design and Synthesis of Chiral Organopalladium-Amine Complexes
Yongxin Li, S. Selvaratnam, Jagadese J. Vittal, and Pak-Hing Leung
pp 3229 - 3236; DOI:
10.1021/ic030018l
PDF
New Structural Motifs in the Aggregation of Neutral Gold(I) Complexes: Structures and Luminescence from (Alkyl isocyanide)AuCN
Rochelle L. White-Morris, Matthias Stender, Dino S. Tinti, Alan L. Balch, Daniel Rios, and Saeed Attar
pp 3237 - 3244; DOI:
10.1021/ic0206948
PDF
Rh(II) and Rh(I) Two-Legged Piano-Stool Complexes: Structure, Reactivity, and Electronic Properties
Felicia M. Dixon, Martin S. Masar, III, Peter E. Doan, Joshua R. Farrell, Frederick P. Arnold Jr., Chad A. Mirkin, Christopher D. Incarvito, Lev N. Zakharov, and Arnold L. Rheingold
pp 3245 - 3255; DOI:
10.1021/ic0204981
PDF
Synthesis and Characterization of Nb(OR)4[OC(O)OR] (R = Me, Et, Allyl) and Their Reaction with the Parent Alcohol To Afford Organic Carbonates
Michele Aresta, Angela Dibenedetto, and Carlo Pastore
pp 3256 - 3261; DOI:
10.1021/ic020536g
PDF
Competition between Transferrin and the Serum Ligands Citrate and Phosphate for the Binding of Aluminum
Wesley R. Harris, Zhepeng Wang, and Yahia Z. Hamada
pp 3262 - 3273; DOI:
10.1021/ic026027w
PDF
Silylene-Bridged Dinuclear Iron Complexes [Cp(OC)2Fe]2SiX2 (X = H, F, Cl, Br, I). Synthesis, Molecular Structure, Vibrational Spectroscopy, and Theoretical Studies
Matthias Vögler, Ioana Pavel, Marco Hofmann, Damien Moigno, Martin Nieger, Wolfgang Kiefer, and Wolfgang Malisch
pp 3274 - 3284; DOI:
10.1021/ic026138v
PDF
Influence of Hydrogen Bonding in Competition with Lattice Interactions on Carbonyl Coordination at Phosphorus. Implications for Phosphoryl Transfer Activated States1
A. Chandrasekaran, Natalya V. Timosheva, Roberta O. Day, and Robert R. Holmes
pp 3285 - 3292; DOI:
10.1021/ic020666p
PDF
Ruthenium(II) and Ruthenium(IV) Complexes Containing 1-P-, 2-P,O-, and 3-P,N,O-Iminophosphorane-Phosphine Ligands Ph2PCH2P{=NP(=O)(OR)2}Ph2 (R = Et, Ph): Synthesis, Reactivity, Theoretical Studies, and Catalytic Activity in Transfer Hydrogenation of Cyclohexanone
Victorio Cadierno, Pascale Crochet, Josefina Díez, Joaquín García-Álvarez, Sergio E. García-Garrido, José Gimeno, Santiago García-Granda, and Miguel A. Rodríguez
pp 3293 - 3307; DOI:
10.1021/ic020702k
PDF
Synthesis of Lateral Macrobicyclic Compartmental Ligands: Structural, Magnetic, Electrochemical, and Catalytic Studies of Mono- and Binuclear Copper(II) Complexes
M. Thirumavalavan, P. Akilan, M. Kandaswamy, Kandaswamy Chinnakali, G. Senthil Kumar, and H. K. Fun
pp 3308 - 3317; DOI:
10.1021/ic020633+
PDF
New Rhodium(III) and Ruthenium(II) Water-Soluble Complexes with 3,5-Diaza-1-methyl-1-azonia-7-phosphatricyclo[3.3.1.13,7]decane
Piotr Smoleski, Florian P. Pruchnik, Zbigniew Ciunik, and Tadeusz Lis
pp 3318 - 3322; DOI:
10.1021/ic034044v
PDF
Synthesis and Structural Characterization of Unprecedented Bis-Asymmetric Heteroscorpionate U(III) Complexes: [U{3-H2B(pztBu,Me)(pzMe,tBu)}2I] and [U{3-H2B(pztBu,Me)(pzMe2)}2I]
Leonor Maria, Ângela Domingos, and Isabel Santos
pp 3323 - 3330; DOI:
10.1021/ic026210p
PDF
Preparation and Characterization of New Ruthenium and Osmium Containing Polyoxometalates, [M(DMSO)3Mo7O24]4- (M = Ru(II), Os(II)), and Their Use as Catalysts for the Aerobic Oxidation of Alcohols
Alexander M. Khenkin, Linda J. W. Shimon, and Ronny Neumann
pp 3331 - 3339; DOI:
10.1021/ic026003p
PDF
Low-Valent Cobalt Complexes with Three Different Acceptor Ligands: Experimental and DFT Studies of the Reduced and the Low-Lying Excited States of (R-DAB)Co(NO)(CO), R-DAB = Substituted 1,4-Diaza-1,4-butadiene
Monika Sieger, Matthias Wanner, Wolfgang Kaim, Derk J. Stufkens, Theo L. Snoeck, and Stanislav Záli
pp 3340 - 3346; DOI:
10.1021/ic026078t
PDF
Substituent Control of Hydrogen Bonding in Palladium(II)-Pyrazole Complexes
Douglas B. Grotjahn, Sang Van, David Combs, Daniel A. Lev, Christian Schneider, Christopher D. Incarvito, Kim-Chung Lam, Gene Rossi, Arnold L. Rheingold, Marc Rideout, Christoph Meyer, Genaro Hernandez, and Lupe Mejorado
pp 3347 - 3355; DOI:
10.1021/ic026104n
PDF
New Disulfido Molybdenum-Manganese Complexes Exhibit Facile Addition of Small Molecules to the Sulfur Atoms
Richard D. Adams, Burjor Captain, O-Sung Kwon, and Shaobin Miao
pp 3356 - 3365; DOI:
10.1021/ic030034i
PDF
Oxamato-Bridged Trinuclear NiIICuIINiII Complexes: A New (NiIICuIINiII)2 Hexanuclear Complex and Supramolecular Structures. Characterization and Magnetic Properties
Javier Tercero, Carmen Diaz, Joan Ribas, Miguel Maestro, José Mahía, and Helen Stoeckli-Evans
pp 3366 - 3373; DOI:
10.1021/ic026264z
PDF
Iron-Promoted Nucleophilic Additions to Diimine-Type Ligands: A Synthetic and Structural Study
Ana Tesouro Vallina, Helen Stoeckli-Evans, Antonia Neels, Jürgen Ensling, and Silvio Decurtins
pp 3374 - 3382; DOI:
10.1021/ic026079l
PDF

Issue 11


Water-Soluble Polymer-Bound Biomimetic Analogues of Cytochrome c Oxidase Catalyze 4e- Reduction of O2 to Water
James P. Collman, Werner Fudickar, and Irina Shiryaeva
pp 3384 - 3386; DOI:
10.1021/ic034140w
PDF
Structural Properties of Cyclopentanone-Bridged Bis-Macrocyclic Ligand Dicopper(II) Complexes in the Solid and in Solution: A Successful Test of the MM-EPR Method
Peter Comba, Marion Kerscher, Yaroslaw D. Lampeka, Lutz Lötzbeyer, Hans Pritzkow, and Lyudmyla V. Tsymbal
pp 3387 - 3389; DOI:
10.1021/ic026265r
PDF
Influence of the Li+ on the Structure of the [Cu3(phis)3]3+ Cation
Jagadese J. Vittal, Xiaobai Wang, and John D. Ranford
pp 3390 - 3392; DOI:
10.1021/ic026311n
PDF
Dual Emission from 3MLCT and 3ILCT Excited States in a New Ru(II) Diimine Complex
Lin-qing Song, Juan Feng, Xue-song Wang, Jun-hua Yu, Yuan-jun Hou, Pu-hui Xie, Bao-wen Zhang, Jun-feng Xiang, Xi-cheng Ai, and Jian-ping Zhang
pp 3393 - 3395; DOI:
10.1021/ic026070j
PDF
IR Spectroelectrochemical Study on UVO2+ Complex: First Evidence for Weakening of U=O Bond Strength in Uranyl Moiety with Reduction from U(VI) to U(V)
Koichiro Mizuoka and Yasuhisa Ikeda
pp 3396 - 3398; DOI:
10.1021/ic0342402
PDF
31P Solid State NMR Studies of Metal Selenophosphates Containing [P2Se6]4-, [P4Se10]4-, [PSe4]3-, [P2Se7]4-, and [P2Se9]4- Ligands
Christian G. Canlas, Mercouri G. Kanatzidis, and David P. Weliky
pp 3399 - 3405; DOI:
10.1021/ic025946j
PDF
Chains of [RE6] Octahedra Coupled by (NCN) Links in the Network Structure of RE2Cl(CN2)N. Synthesis and Structure of Two Novel Rare Earth Chloride Carbodiimide Nitrides with Structures Related to the RE2Cl3 Type
Radhakrishnan Srinivasan, Markus Ströbele, and H.-Jürgen Meyer
pp 3406 - 3411; DOI:
10.1021/ic020685z
PDF
Defective Vertices in arachno Borane Networks
R. B. King
pp 3412 - 3415; DOI:
10.1021/ic0300215
PDF
Recognition of Topological Isomerism: Synthesis, Structure, and Magnetic Properties of Two Pentanuclear High-Spin Molecules of the Type [NiII(N-N)2]3[FeIII(CN)6]2
Curtis P. Berlinguette, José Ramón Galán-Mascarós, and Kim R. Dunbar
pp 3416 - 3422; DOI:
10.1021/ic0205031
PDF
Examination of Novel Zinc-Binding Groups for Use in Matrix Metalloproteinase Inhibitors
David T. Puerta and Seth M. Cohen
pp 3423 - 3430; DOI:
10.1021/ic026029g
PDF
Gallium and Indium Hydrazides. Molecular and Electronic Structure of In[N(SiMe3)NMe2]3 and Related Compounds
Bing Luo, Christopher J. Cramer, and Wayne L. Gladfelter
pp 3431 - 3437; DOI:
10.1021/ic020693f
PDF
Iminophosphorane Mediated Imine Metathesis
Matthew C. Burland and Tara Y. Meyer
pp 3438 - 3444; DOI:
10.1021/ic0263138
PDF
Highly Sensitive Luminescent Metal-Complex Receptors for Anions through Charge-Assisted Amide Hydrogen Bonding
Shih-Sheng Sun, Alistair J. Lees, and Peter Y. Zavalij
pp 3445 - 3453; DOI:
10.1021/ic0206589
PDF
Iron and Cobalt Ethylene Polymerization Catalysts: Variations on the Central Donor
George J. P. Britovsek, Vernon C. Gibson, Olivier D. Hoarau, Stefan K. Spitzmesser, Andrew J. P. White, and David J. Williams
pp 3454 - 3465; DOI:
10.1021/ic034040q
PDF
Coordination Properties of a Diarylaza Crown Ether Appended with a Luminescent [Ru(bipy)3]2+ Unit
Loïc J. Charbonnière, Raymond F. Ziessel, Craig A. Sams, and Anthony Harriman
pp 3466 - 3474; DOI:
10.1021/ic020671t
PDF
Acid-Base and Metal Ion Binding Properties of Guanylyl(3'5')guanosine (GpG-) and 2'-Deoxyguanylyl(3'5')-2'-deoxyguanosine [d(GpG)-] in Aqueous Solution
Carla P. Da Costa and Helmut Sigel
pp 3475 - 3482; DOI:
10.1021/ic020672l
PDF
Eilatin as a Bridging Ligand in Ruthenium(II) Complexes: Synthesis, Crystal Structures, Absorption Spectra, and Electrochemical Properties
Dalia Gut, Israel Goldberg, and Moshe Kol
pp 3483 - 3491; DOI:
10.1021/ic020703c
PDF
Antiferromagnetic Three-Dimensional Order Induced by Carboxylate Bridges in a Two-Dimensional Network of [Cu3(dcp)2(H2O)4] Trimers
Philippa King, Rodolphe Clérac, Christopher E. Anson, Claude Coulon, and Annie K. Powell
pp 3492 - 3500; DOI:
10.1021/ic0261777
PDF
Self-Assembly of a Series of Novel Metal-Organic Compounds Containing Ferrocenecarboxylate Components
Hongwei Hou, Linke Li, Gang Li, Yaoting Fan, and Yu Zhu
pp 3501 - 3508; DOI:
10.1021/ic034031h
PDF
Structure and Magnetic Properties of the Two-Dimensional Ferrimagnet (NEt4)[{Mn(salen)}2Fe(CN)6]: Investigation of Magnetic Anisotropy on a Single Crystal
Hitoshi Miyasaka, Hidenori Ieda, Naohide Matsumoto, Ken-ichi Sugiura, and Masahiro Yamashita
pp 3509 - 3515; DOI:
10.1021/ic026261m
PDF
Reactivity of the Organometallic fac-[(CO)3ReI(H2O)3]+ Aquaion. Kinetic and Thermodynamic Properties of H2O Substitution
Bernadette Salignac, Pascal V. Grundler, Sonia Cayemittes, Urban Frey, Rosario Scopelliti, André E. Merbach, Roman Hedinger, Kaspar Hegetschweiler, Roger Alberto, Ulrich Prinz, Gerhard Raabe, Ulrich Kölle, and Syd Hall
pp 3516 - 3526; DOI:
10.1021/ic0341744
PDF
Donor-Functionalized Lanthanide Terphenyl Complexes: Synthesis and Structural Characterization of 2,6-Di(o-anisol)phenyl Compounds of Ytterbium, Yttrium, and Samarium
Gerd W. Rabe, Mei Zhang-Presse, Florian A. Riederer, and Glenn P. A. Yap
pp 3527 - 3533; DOI:
10.1021/ic0300161
PDF
Additional Steps toward Molecular Scale Wires: Further Study of Ni510/11+ Chains Embraced by Polypyridylamide Ligands
John F. Berry, F. Albert Cotton, Peng Lei, Tongbu Lu, and Carlos A. Murillo
pp 3534 - 3539; DOI:
10.1021/ic034071l
PDF
Aggregate Manganese Schiff Base Moieties by Terephthalate or Acetate: Dinuclear Manganese and Trinuclear Mixed Metal Mn2/Na Complexes
Changneng Chen, Deguang Huang, Xiaofeng Zhang, Feng Chen, Hongping Zhu, Qiutian Liu, Cunxi Zhang, Daizheng Liao, Licun Li, and Licheng Sun
pp 3540 - 3548; DOI:
10.1021/ic025944z
PDF
Synthesis, Structural Investigation, and Solid-State Properties of Iodine-Doped Zirconium Diphthalocyanine, [ZrPc2]I3·I2
Jan Janczak
pp 3549 - 3558; DOI:
10.1021/ic020717i
PDF
Formation and Photoinduced Electron Ejection of Amminedicyanocuprate(I) and Cyano-Bridged Trinuclear Copper(I) Complexes in Aqueous Ammonia Solution
Kenneth L. Stevenson, Jessica H. Jarboe, Stacy A. Langmeyer, and Travis W. Acra
pp 3559 - 3564; DOI:
10.1021/ic020725z
PDF
A Resonance Raman, Surface-Enhanced Resonance Raman, IR, and ab Initio Vibrational Spectroscopic Study of Nickel(II) Tetraazaannulene Complexes
Stephen Bell, Joe A. Crayston, Trevor J. Dines, Saira B. Ellahi, and Caroline I. Smith
pp 3565 - 3575; DOI:
10.1021/ic026216e
PDF
Electronic Effects in 12-Metallacrown-3 Complexes. A Theoretical and Experimental Study
Marie-Line Lehaire, Axel Schulz, Rosario Scopelliti, and Kay Severin
pp 3576 - 3581; DOI:
10.1021/ic034042a
PDF
Investigations into the Interactions between DNA and Conformationally Constrained Pyridylamineplatinum(II) Analogues of AMD473
Vivienne P. Munk, Connie I. Diakos, Leanne T. Ellis, Ronald R. Fenton, Barbara A. Messerle, and Trevor W. Hambley
pp 3582 - 3590; DOI:
10.1021/ic0340231
PDF
Diphenyldichlorophosphonium Trichloride-Chlorine Solvate 1:1, [PPh2Cl2]+Cl3-·Cl2: An Ionic Form of Diphenyltrichlorophosphorane. Crystal Structures of [PPh2Cl2]+Cl3-·Cl2 and [(PPh2Cl2)+]2[InCl5]2-
Jan Taraba and Zdirad Zak
pp 3591 - 3594; DOI:
10.1021/ic034091n
PDF
Enhancing the Stability of Trinickel Molecular Wires and Switches: Ni36+/Ni37+
John F. Berry, F. Albert Cotton, Tongbu Lu, Carlos A. Murillo, and Xiaoping Wang
pp 3595 - 3601; DOI:
10.1021/ic0341486
PDF
Pop-the-Cork Strategy in Synthetic Utilization of Imines: Stabilization by Complexation and Activation via Liberation of the Ligated Species
Nadezhda A. Bokach, Vadim Yu. Kukushkin, Matti Haukka, João J. R. Fraústo da Silva, and Armando J. L. Pombeiro
pp 3602 - 3608; DOI:
10.1021/ic034086j
PDF
A Monovacant Heteropolytungstate Thioderivative: Synthesis and Characterization of [(PW11O39)2(H4Mo4S4O6)]10- and Related Isomers
Jérôme Marrot, Marie Anne Pilette, Francis Sécheresse, and Emmanuel Cadot
pp 3609 - 3615; DOI:
10.1021/ic026191j
PDF
Metal-Bis[poly(pyrazolyl)borate] Complexes. Electrochemical, Magnetic, and Spectroscopic Properties and Coupled Electron-Transfer and Spin-Exchange Reactions
D. Chanaka L. De Alwis and Franklin A. Schultz
pp 3616 - 3622; DOI:
10.1021/ic034077a
PDF
Bis(trifluoromethyl)phosphane and Bis(pentafluorophenyl)phosphane and Their Pentacarbonyl Tungsten Complexes: Improved Synthesis and an Experimental and Density Functional Study
Berthold Hoge, Tobias Herrmann, Christoph Thösen, and Ingo Pantenburg
pp 3623 - 3632; DOI:
10.1021/ic034166n
PDF
Stabilization of the P(CF3)2- and P(C6F5)2- Ions by Coordination to Pentacarbonyl Tungsten: Structures of [18-crown-6-K]P(CF3)2, [18-crown-6-K][W{P(CF3)2}(CO)5], and [18-crown-6-K][{W(CO)5}2{-P(C6F5)2}]·THF
Berthold Hoge, Christoph Thösen, Tobias Herrmann, and Ingo Pantenburg
pp 3633 - 3641; DOI:
10.1021/ic034165v
PDF
New One-Dimensional Azido-Bridged Manganese(II) Coordination Polymers Exhibiting Alternating Ferromagnetic-Antiferromagnetic Interactions: Structural and Magnetic Studies
En-Qing Gao, Shi-Qiang Bai, Yan-Feng Yue, Zhe-Ming Wang, and Chun-Hua Yan
pp 3642 - 3649; DOI:
10.1021/ic0262987
PDF
Insertion Reactions into Pd-O and Pd-N Bonds: Preparation of Alkoxycarbonyl, Carbonato, Carbamato, Thiocarbamate, and Thioureide Complexes of Palladium(II)
José Ruiz, M. Teresa Martínez, Félix Florenciano, Venancio Rodríguez, Gregorio López, José Pérez, Penny A. Chaloner, and Peter B. Hitchcock
pp 3650 - 3661; DOI:
10.1021/ic0300058
PDF
1H NMR Studies of Ligand and H/D Exchange Reactions of cis- and trans-([14]aneN4)(H2O)RhH2+ in Aqueous Solutions
Kelemu Lemma, Arkady Ellern, and Andreja Bakac
pp 3662 - 3669; DOI:
10.1021/ic034130v
PDF
Modified Polyoxometalates: Hydrothermal Syntheses and Crystal Structures of Three Novel Reduced and Capped Keggin Derivatives Decorated by Transition Metal Complexes
Mei Yuan, Yangguang Li, Enbo Wang, Chungui Tian, Li Wang, Changwen Hu, Ninghai Hu, and Hengqing Jia
pp 3670 - 3676; DOI:
10.1021/ic026296m
PDF
Organometallic-Polyoxometalate Hybrid Compounds: Metallosalen Compounds Modified by Keggin Type Polyoxometalates
Itsik Bar-Nahum, Hagai Cohen, and Ronny Neumann
pp 3677 - 3684; DOI:
10.1021/ic034095s
PDF
Complexation of Uranium(VI) and Samarium(III) with Oxydiacetic Acid: Temperature Effect and Coordination Modes
Linfeng Rao, Alexander Yu. Garnov, Jun Jiang, Plinio Di Bernardo, PierLuigi Zanonato, and Arturo Bismondo
pp 3685 - 3692; DOI:
10.1021/ic034227h
PDF
Uranyl Complexes with Diamide Ligands: A Quantum Mechanics Study of Chelating Properties in the Gas Phase
Bernard Coupez and Georges Wipff
pp 3693 - 3703; DOI:
10.1021/ic0341082
PDF
Mechanistic Studies of the Formation and Decay of Diiron(III) Peroxo Complexes in the Reaction of Diiron(II) Precursors with Dioxygen
Andrew L. Feig, Michael Becker, Siegfried Schindler, Rudivan Eldik, and Stephen J. Lippard:
pp 3704 - 3704; DOI:
10.1021/ic030133w
PDF
Zinc-Bound Thiolate-Disulfide Exchange: A Strategy for Inhibiting Metallo--lactamases
Heidi Boerzel, Margery Koeckert, Weiming Bu, BernhardSpingler, and Stephen J. Lippard:
pp 3704 - 3704; DOI:
10.1021/ic030134o
PDF

Issue 12


Crystal Structure and Magnetic Properties of an Ionic C60 Complex with Decamethylcobaltocene: (Cp*2Co)2C60(C6H4Cl2, C6H5CN)2. Singlet-Triplet Transitions in the C602- Anion
Dmitri V. Konarev, Salavat S. Khasanov, Gunzi Saito, Ivan I. Vorontsov, Akihiro Otsuka, Rimma N. Lyubovskaya, and Yury M. Antipin
pp 3706 - 3708; DOI:
10.1021/ic0340074
PDF
A Novel Organic-Inorganic Hybrid Based on a Dinuclear Copper Complex Supported on a Keggin Polyoxometalate
Santiago Reinoso, Pablo Vitoria, Luis Lezama, Antonio Luque, and Juan M. Gutiérrez-Zorrilla
pp 3709 - 3711; DOI:
10.1021/ic034203a
PDF
Aromatic Hydrocarbon-Catalyzed Direct Reaction of Sulfur and Sodium in a Heterogeneous System: Selective and Facile Synthesis of Sodium Monosulfide and Disulfide
Toshikazu Takata, Daisaku Saeki, Yoshimasa Makita, Nobuo Yamada, and Nobuhiro Kihara
pp 3712 - 3714; DOI:
10.1021/ic034084z
PDF
Speciation and Unusual Reactivity in PuO2+x
Steven D. Conradson, Bruce D. Begg, David L. Clark, Christophe Den Auwer, Francisco J. Espinosa-Faller, Pamela L. Gordon, Nancy J. Hess, Ryan Hess, D. Webster Keogh, Luis A. Morales, Mary P. Neu, Wolfgang Runde, C. Drew Tait, D. Kirk Veirs, and Phillip M. Villella
pp 3715 - 3717; DOI:
10.1021/ic026044l
PDF
Self-Exchange Reaction Kinetics of Metallocenes Revisited: Insights from the Decamethylferricenium-Decamethylferrocene Reaction at Variable Pressure
Achim Zahl, Rudi van Eldik, Mitsuru Matsumoto, and Thomas W. Swaddle
pp 3718 - 3722; DOI:
10.1021/ic030067y
PDF
APdCu(Se2)(Se3) (A = K and Rb): New Quaternary Copper Palladium Polyselenides with Unusual Metal-Selenium Coordination
Xuean Chen, Kieran J. Dilks, Xiaoying Huang, and Jing Li
pp 3723 - 3727; DOI:
10.1021/ic0340130
PDF
Vanadogermanate Cluster Anions
T. Whitfield, X. Wang, and A. J. Jacobson
pp 3728 - 3733; DOI:
10.1021/ic0206185
PDF
Formation of A Novel 1D Supramolecule [HgCl2(ptz)]2·HgCl2 (ptz = Phenothiazine): A New Precursor to Submicrometer Hg2Cl2 Rods
Xuanjun Zhang, Yi Xie, Wentao Yu, Qingrui Zhao, Minhua Jiang, and Yupeng Tian
pp 3734 - 3737; DOI:
10.1021/ic034055o
PDF
Multidimensional Frameworks Assembled from Silver(I) Coordination Polymers Containing Flexible Bis(thioquinolyl) Ligands: Role of the Intra- and Intermolecular Aromatic Stacking Interactions
Chun-Long Chen, Cheng-Yong Su, Yue-Peng Cai, Hua-Xin Zhang, An-Wu Xu, Bei-Sheng Kang, and Hans-Conrad zur Loye
pp 3738 - 3750; DOI:
10.1021/ic0341035
PDF
Influences of Changes in Multitopic Tris(pyrazolyl)methane Ligand Topology on Silver(I) Supramolecular Structures
Daniel L. Reger, Radu F. Semeniuc, Ioan Silaghi-Dumitrescu, and Mark D. Smith
pp 3751 - 3764; DOI:
10.1021/ic034039r
PDF
X-ray and Neutron Diffraction Studies on "Li4.4Sn"
Corina Lupu, Jiang-Gao Mao, J. Wayne Rabalais, Arnold M. Guloy, and James W. Richardson, Jr.
pp 3765 - 3771; DOI:
10.1021/ic026235o
PDF
Synthesis and Characterization of Platinum Diimine Bis(acetylide) Complexes Containing Easily Derivatizable Aryl Acetylide Ligands
Thaddeus J. Wadas, Rene J. Lachicotte, and Richard Eisenberg
pp 3772 - 3778; DOI:
10.1021/ic0263084
PDF
Induced Fit Process in the Selective Distal Binding of Imidazoles in Zinc(II) Porphyrin Receptors
Dharam Paul, Frédéric Melin, Caroline Hirtz, Jennifer Wytko, Philippe Ochsenbein, Michel Bonin, Kurt Schenk, Patrick Maltese, and Jean Weiss
pp 3779 - 3787; DOI:
10.1021/ic0341643
PDF
Cation-Cation Interactions in Neptunyl(V) Compounds: Hydrothermal Preparation and Structural Characterization of NpO2(IO3) and - and -AgNpO2(SeO3)
Thomas E. Albrecht-Schmitt, Philip M. Almond, and Richard E. Sykora
pp 3788 - 3795; DOI:
10.1021/ic034124z
PDF
Direct Determination of the Gibbs' Energy of Formation of Peroxynitrous Acid
Gábor Merényi, Johan Lind, Gideon Czapski, and Sara Goldstein
pp 3796 - 3800; DOI:
10.1021/ic025698r
PDF
Cationic Carbonyl Complexes of Rhodium(I) and Rhodium(III): Syntheses, Vibrational Spectra, NMR Studies, and Molecular Structures of Tetrakis(carbonyl)rhodium(I) Heptachlorodialuminate and -gallate, [Rh(CO)4][Al2Cl7] and [Rh(CO)4][Ga2Cl7]
Britta von Ahsen, Christian Bach, Michael Berkei, Martin Köckerling, Helge Willner, Gerhard Hägele, and Friedhelm Aubke
pp 3801 - 3814; DOI:
10.1021/ic0206903
PDF
Synthesis and Characterization of trans-[Os(en)2py(H)]2+ and Related Studies
J. Scott McQueen, Noriharu Nagao, Todd Eberspacher, Z. W. Li, and Henry Taube
pp 3815 - 3821; DOI:
10.1021/ic030091b
PDF
A Unique Mechanism for Base Catalyzed Hydrolysis of Pentaaminecobalt(III) Complexes Containing Picolyl Residues
Alistair J. Dickie, David C. R. Hockless, Anthony C. Willis, Josephine A. McKeon, and W. Gregory Jackson
pp 3822 - 3834; DOI:
10.1021/ic0206995
PDF
Self-Assembly of Dialkyltin(IV) Moieties and Aromatic Dicarboxylates to Complexes with a Polymeric or a Discrete Trinuclear Macrocyclic Structure in the Solid State and a Mixture of Fast Interchanging Cyclooligomeric Structures in Solution
Reyes García-Zarracino, Jesús Ramos-Quiñones, and Herbert Höpfl
pp 3835 - 3845; DOI:
10.1021/ic026270v
PDF
The Platinum Catalyst [bpyrPtCl2] in Superacidic Solution
Stefan Seidel and Konrad Seppelt
pp 3846 - 3848; DOI:
10.1021/ic026115g
PDF
Structural Diversity of Lithium Sulfenamides: 7Li NMR Studies in Solution and Crystal Structures of [Li2(2-(CH3)3C-NS-C6H4CH3-4)2(THF)2] and [Li2(1-4-CH3C6H4-NS-C6H4CH3-4)2(THF)4]
Amir H. Mahmoudkhani, Sarah Rauscher, Brian Grajales, and Ignacio Vargas-Baca
pp 3849 - 3855; DOI:
10.1021/ic026269w
PDF
Conformational Preferences Driven by the C-Methyl Substituent in Chelated o-Diphenylphosphino--methyl-N,N-dimethylbenzylamine Rhodium Complexes
M. Aránzazu Alonso, Juan A. Casares, Pablo Espinet, Katerina Soulantica, A. Guy Orpen, and Hirihattaya Phetmung
pp 3856 - 3864; DOI:
10.1021/ic034117a
PDF
Ligand Close Packing and the Geometry of the Fluorides of the Nonmetals of Periods 3, 4, and 5
E. A. Robinson and R. J. Gillespie
pp 3865 - 3872; DOI:
10.1021/ic030024h
PDF
Do Penta- and Decaphospha Analogues of Lithocene Anion and Beryllocene Exist? Analysis of Stability, Structure, and Bonding by Hybrid Density Functional Study
E. J. Padma Malar
pp 3873 - 3883; DOI:
10.1021/ic0340027
PDF
11B, 23Na, 27Al, and 19F NMR Study of Solid and Molten Na3AlF6-Na2B4O7
Catherine Bessada and Elena M. Anghel
pp 3884 - 3890; DOI:
10.1021/ic026074o
PDF
Electron Transfer through a Prenucleated Bimetalated Alanine-Based Peptide Helix
Kenneth J. Kise, Jr. and Bruce E. Bowler
pp 3891 - 3897; DOI:
10.1021/ic026166d
PDF
Interpretation of the Magnetic Structures of Cu2Te2O5X2 (X = Cl, Br) and Ca3.1Cu0.9RuO6 on the Basis of Electronic Structure Considerations: Cases for Strong Super-Superexchange Interactions Involving Cu2+ Ions
M.-H. Whangbo, H.-J. Koo, D. Dai, and D. Jung
pp 3898 - 3906; DOI:
10.1021/ic020551l
PDF
Pyrazolato-Bridged Polynuclear Palladium and Platinum Complexes. Synthesis, Structure, and Reactivity
Keisuke Umakoshi, Yoko Yamauchi, Keiko Nakamiya, Takashi Kojima, Mikio Yamasaki, Hiroyuki Kawano, and Masayoshi Onishi
pp 3907 - 3916; DOI:
10.1021/ic026196g
PDF
[Au(CN)4]- as a Supramolecular Building Block for Heterobimetallic Coordination Polymers
Carolyn J. Shorrock, Howard Jong, Raymond J. Batchelor, and Daniel B. Leznoff
pp 3917 - 3924; DOI:
10.1021/ic0341441
PDF
Nickel Complexes of o-Amidochalcogenophenolate(2-)/o-Iminochalcogenobenzosemiquinonate(1-) -Radical: Synthesis, Structures, Electron Spin Resonance, and X-ray Absorption Spectroscopic Evidence
Chung-Hung Hsieh, I-Jui Hsu, Chien-Ming Lee, Shyue-Chu Ke, Tze-Yuan Wang, Gene-Hsiang Lee, Yu Wang, Jin-Ming Chen, Jyh-Fu Lee, and Wen-Feng Liaw
pp 3925 - 3933; DOI:
10.1021/ic034211r
PDF
Copper-63 NMR Line width Study of the Copper(I)-Acetonitrile System
Japhet K. Irangu and R. B. Jordan
pp 3934 - 3942; DOI:
10.1021/ic030020c
PDF
The Ligand Effect on the Hydrolytic Reactivity of Zn(II) Complexes toward Phosphate Diesters
Lodovico Bonfá, Maddalena Gatos, Fabrizio Mancin, Paolo Tecilla, and Umberto Tonellato
pp 3943 - 3949; DOI:
10.1021/ic034139x
PDF
Structures and Magnetic Behavior of 1-, 2-, and 3D Coordination Polymers in the Cu(II)-Dicyanamide-Pyrimidine Family
Jamie L. Manson, Jiyeong Gu, John A. Schlueter, and H.-Hau Wang
pp 3950 - 3955; DOI:
10.1021/ic026164t
PDF
Stereoselective Oxidative Additions of Iodoalkanes and Activated Alkynes to a Sulfido-Bridged Heterotrinuclear Early-Late (TiIr2) Complex
Miguel A. Casado, Jesús J. Pérez-Torrente, Miguel A. Ciriano, Isabel T. Dobrinovitch, Fernando J. Lahoz, and Luis A. Oro
pp 3956 - 3964; DOI:
10.1021/ic034278e
PDF

Issue 13


Electrochromic Devices Based on Binuclear Mixed Valence Compounds Adsorbed on Nanocrystalline Semiconductors
Matteo Biancardo, Peter F. H. Schwab, Roberto Argazzi, and Carlo Alberto Bignozzi
pp 3966 - 3968; DOI:
10.1021/ic034145t
PDF
Isolation and Crystallographic Characterization of a Solid Precipitate/Intermediate in the Preparation of 5-Substituted 1H-Tetrazoles from Nitrile in Water
Li-Zhong Wang, Zhi-Rong Qu, Hong Zhao, Xi-Sen Wang, Ren-Gen Xiong, and Zi-Ling Xue
pp 3969 - 3971; DOI:
10.1021/ic034116i
PDF
The Gadolinium(III)-Water Hydrogen Distance in MRI Contrast Agents
Peter Caravan, Andrei V. Astashkin, and Arnold M. Raitsimring
pp 3972 - 3974; DOI:
10.1021/ic034414f
PDF
Structural and Magnetic Properties of a Novel Ferrocenyl-Diiodine Charge Transfer Complex
David W. Allen, Rory Berridge, Neil Bricklebank, Susan D. Forder, Fernando Palacio, Simon J. Coles, Michael B. Hursthouse, and Peter J. Skabara
pp 3975 - 3977; DOI:
10.1021/ic034092f
PDF
Salt-Inclusion Synthesis of Ba2MnSi2O7Cl. A Fresnoite-Type Polar Framework Containing the Acentric [Si2O7]6- Polyanion in the Anti-ReO3 Type [(Ba2Mn)Cl]6+ Cage
Xunhua Mo and Shiou-Jyh Hwu
pp 3978 - 3980; DOI:
10.1021/ic0342245
PDF
Electronic Structure of Oxovanadium(IV) Complexes of -Hydroxycarboxylic Acids
Eugenio Garribba, Giovanni Micera, Angelo Panzanelli, and Daniele Sanna
pp 3981 - 3987; DOI:
10.1021/ic0260567
PDF
Quasi-1D Cations 1[Ni8Bi8S]n+ of Variable Charge: Infinite Columns 1[Ni8Bi8S]2+ in the Novel Compound Ni8Bi8SI2
A. I. Baranov, L. Kloo, A. V. Olenev, B. A. Popovkin, and A. I. Romanenko
pp 3988 - 3993; DOI:
10.1021/ic0340332
PDF
Lithiation of Tris(alkyl- and arylamido)orthophosphates EP[N(H)R]3 (E = O, S, Se): Imido Substituent Effects and P=E Bond Cleavage
Tristram Chivers, Mark Krahn, Gabriele Schatte, and Masood Parvez
pp 3994 - 4005; DOI:
10.1021/ic034151p
PDF
Spectroscopic Characterization of the Leu513His Variant of Fungal Laccase: Effect of Increased Axial Ligand Interaction on the Geometric and Electronic Structure of the Type 1 Cu Site
Amy E. Palmer, Robert K. Szilagyi, Joel R. Cherry, Aubrey Jones, Feng Xu, and Edward I. Solomon
pp 4006 - 4017; DOI:
10.1021/ic026099n
PDF
Two-Electron-Transfer Redox Systems, Part 7:
Bernd Speiser, Tina Wizemann, and Marc Würde
pp 4018 - 4028; DOI:
10.1021/ic034101k
PDF
A Quasi-Tetrahedral Cu4 Cluster and a Helical-Chain Copper(II) Complex with Single Syn-Anti Carboxylate Bridges: Crystal Structure and Magnetic Properties
Subrata Kumar Dey, Bappaditya Bag, K. M. Abdul Malik, M. Salah El Fallah, Joan Ribas, and Samiran Mitra
pp 4029 - 4035; DOI:
10.1021/ic0206488
PDF
Combined Use of Platinum(II) Complexes and Palladium(II) Complexes for Selective Cleavage of Peptides and Proteins
Neboja M. Milovi, Laura-M. Dutc, and Nenad M. Kosti
pp 4036 - 4045; DOI:
10.1021/ic026280w
PDF
Comparative Theoretical Investigation of the Vertical Excitation Energies and the Electronic Structure of [MoVOCl4]-: Influence of Basis Set and Geometry
Victor N. Nemykin and Partha Basu
pp 4046 - 4056; DOI:
10.1021/ic0262942
PDF
Hydrothermal Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of a New Indium Silicate: K2In(OH)(Si4O10)
Ling-I Hung, Sue-Lein Wang, Hsien-Ming Kao, and Kwang-Hwa Lii
pp 4057 - 4061; DOI:
10.1021/ic020718a
PDF
Alkyl- and Aryl-Substituted Corroles. 4. Solvent Effects on the Electrochemical and Spectral Properties of Cobalt Corroles
Karl M. Kadish, Jianguo Shao, Zhongping Ou, Claude P. Gros, Frédéric Bolze, Jean-Michel Barbe, and Roger Guilard
pp 4062 - 4070; DOI:
10.1021/ic030010b
PDF
Structure and Conformations of N-(Fluoroformyl)imidosulfurous Dichloride, FC(O)N=SCl2
Christiane Leibold, Rosa M. S. Alvarez, Edgardo H. Cutin, Carlos O. Della Vedova, and Heinz Oberhammer
pp 4071 - 4075; DOI:
10.1021/ic030058p
PDF
Chemistry of the Si-Si and Fe-Fe Bonds in the Cyclic Structure (Me2SiSiMe2)[5-C5H4Fe(CO)2]2. Selective Cleavage of the Fe-Fe Bond by I2 and Unexpected Properties of the Iodide
Huailin Sun, Zhensheng Zhang, Yanbin Pan, Jian Yang, and Xiuzhong Zhou
pp 4076 - 4081; DOI:
10.1021/ic034156m
PDF
Do S,S'-Coordinated o-Dithiobenzosemiquinonate(1-) Radicals Exist in Coordination Compounds? The [AuIII(1,2-C6H4S2)2]1-/0 Couple
Kallol Ray, Thomas Weyhermüller, Anton Goossens, Menno W. J. Crajé, and Karl Wieghardt
pp 4082 - 4087; DOI:
10.1021/ic0207092
PDF
An Average-of-Configuration Method for Using Kohn-Sham Density Functional Theory in Modeling Ligand-Field Theory
Christian Anthon, Jesper Bendix, and Claus E. Schäffer
pp 4088 - 4097; DOI:
10.1021/ic0262233
PDF
Kinetics and Mechanism of Iron(III)-Nitrilotriacetate Complex Reactions with Phosphate and Acetohydroxamic Acid
Mario Gabrievi and Alvin L. Crumbliss
pp 4098 - 4101; DOI:
10.1021/ic026281o
PDF
Ruthenium(III) Triazacyclononane Dithiocarbamate, Pyridinecarboxylate, or Aminocarboxylate Complexes as Scavengers of Nitric Oxide
Beth R. Cameron, Marilyn C. Darkes, Ian R. Baird, Renato T. Skerlj, Zefferino L. Santucci, and Simon P. Fricker
pp 4102 - 4108; DOI:
10.1021/ic020283r
PDF
The CsLnMSe3 Semiconductors (Ln = Rare-Earth Element, Y; M = Zn, Cd, Hg)
Kwasi Mitchell, Fu Qiang Huang, Adam D. McFarland, Christy L. Haynes, Rebecca C. Somers, Richard P. Van Duyne, and James A. Ibers
pp 4109 - 4116; DOI:
10.1021/ic020733f
PDF
Solution Behavior and Structural Diversity of Bis(dialkylphosphino)methane Complexes of Palladium
Craig B. Pamplin, Steven J. Rettig, Brian O. Patrick, and Brian R. James
pp 4117 - 4126; DOI:
10.1021/ic030048o
PDF
Osmium Phosphiniminato Complexes: Synthesis, Protonation, Structure, and Redox-Coupled Hydrolytic Scission of N-P Bonds
Brian K. Bennett, Erik Saganic, Scott Lovell, Werner Kaminsky, Amanda Samuel, and James M. Mayer
pp 4127 - 4134; DOI:
10.1021/ic026260u
PDF
Novel Polyoxometalate-Templated, 3-D Supramolecular Networks Based on Lanthanide Dimers: Synthesis, Structure, and Fluorescent Properties of [Ln2(DNBA)4(DMF)8][Mo6O19] (DNBA = 3,5-Dinitrobenzoate)
Xiuli Wang, Yaqin Guo, Yangguang Li, Enbo Wang, Changwen Hu, and Ninghai Hu
pp 4135 - 4140; DOI:
10.1021/ic0342447
PDF
The Structure of Tri(cyclohexyl)tin Chloride between 108 and 298 K: A Compound in Which Molecular Dimensions Vary with Temperature
Ashrafomolouk Asadi, Colin Eaborn, Peter B. Hitchcock, Margaret M. Meehan, and J. David Smith
pp 4141 - 4146; DOI:
10.1021/ic026272f
PDF
Monte Carlo Simulation of a 1,4,7,10-Tetraazacyclododecane/Lithium Complex in Aqueous Solution
Supot Hannongbua
pp 4147 - 4152; DOI:
10.1021/ic025854u
PDF
New Ionic Crystals of Oppositely Charged Cluster Ions and Their Characterization
Jung Ho Son, Young-Uk Kwon, and Oc Hee Han
pp 4153 - 4159; DOI:
10.1021/ic0340377
PDF
A Hybrid Metalloarsenate 3D Framework-1D Interrupted Metal Oxide
Robert W. Hughes, Lee A. Gerrard, Daniel J. Price, and Mark T. Weller
pp 4160 - 4164; DOI:
10.1021/ic026151f
PDF
Synthesis and Structure of Ta4SI11: Disorder and Mixed Valency in the First Tantalum Sulfide Iodide
Mark D. Smith and Gordon J. Miller
pp 4165 - 4170; DOI:
10.1021/ic034075q
PDF
Synthesis and Photophysical Properties of New Chromium(III) Complexes of N-Derivatized 1,4,8,11-Tetraazacyclotetradecane Ligands cis-[Cr(1,8-R2cyclam)Cl2]Cl, Where R Is a Pendant Chromophore. Exclusive Formation of the cis Isomer
Frank DeRosa, Xianhui Bu, and Peter C. Ford
pp 4171 - 4178; DOI:
10.1021/ic0300870
PDF
Kinetics and Mechanism of the Interaction of Nitric Oxide with Pentacyanoferrate(II). Formation and Dissociation of [Fe(CN)5NO]3-
Federico Roncaroli, José A. Olabe, and Rudi van Eldik
pp 4179 - 4189; DOI:
10.1021/ic0342189
PDF
Stability and Three-Dimensional Aromaticity of closo-NBn-1Hn Azaboranes, n = 5-12
Katayoun Najafian, Paul von Rague Schleyer, and Thomas T. Tidwell
pp 4190 - 4203; DOI:
10.1021/ic0340783
PDF
Adduct Formation of Methyltrioxorhenium with Mono- and Bidentate Nitrogen Donors: Formation Constants
S. Masoud Nabavizadeh
pp 4204 - 4208; DOI:
10.1021/ic0343408
PDF
Hydrothermal Syntheses, Crystal Structures, and Properties of Two-Dimensional Homo- and Heterometallic Cyanide-Bridged Complexes: [Cu2(CN)2(bpym)] and [Fe(bipy)2(CN)4Cu2] (bpym = 2,2'-Bipyrimidine, bipy = 2,2'-Bipyridine)
Enrique Colacio, José M. Domínguez-Vera, Francesc Lloret, José M. Moreno Sánchez, Raikko Kivekäs, Antonio Rodríguez, and Reijo Sillanpää
pp 4209 - 4214; DOI:
10.1021/ic034155u
PDF
Zeolite-Mediated Photochemical Charge Separation Using a Surface-Entrapped Ruthenium-Polypyridyl Complex
Yanghee Kim, Hyunjung Lee, Prabir K. Dutta, and Amitava Das
pp 4215 - 4222; DOI:
10.1021/ic034216o
PDF
Triamidotriazacyclononane Complexes of Group 3 Metals. Synthesis and Crystal Structures
Bernardo Monteiro, Dmitrii Roitershtein, Humberto Ferreira, José R. Ascenso, Ana M. Martins, Ângela Domingos, and Noémia Marques
pp 4223 - 4231; DOI:
10.1021/ic034090v
PDF
Intercalation of [Cr(C2O4)3]3- Complex in Mg,Al Layered Double Hydroxides
M. del Arco, S. Gutiérrez, C. Martín, and V. Rives
pp 4232 - 4240; DOI:
10.1021/ic034034u
PDF

Issue 14


Unusual Hysteresis in the Magnetic Susceptibility of Cubic Hexaboride KB6
J. Etourneau, A. Ammar, A. Villesuzanne, G. Villeneuve, B. Chevalier, and M.-H. Whangbo
pp 4242 - 4244; DOI:
10.1021/ic034018x
PDF
Protonation State of Asp120 in the Binuclear Active Site of the Metallo--Lactamase from Bacteroides fragilis
Matteo Dal Peraro, Alejandro J. Vila, and Paolo Carloni
pp 4245 - 4247; DOI:
10.1021/ic026059j
PDF
A Solvothermal Synthesis and the Structure of K4Ag2Sn3S9·2KOH
Yonglin An, Min Ji, Menghe Baiyin, Xin Liu, Cuiying Jia, and Dehe Wang
pp 4248 - 4249; DOI:
10.1021/ic034186p
PDF
Synthesis and Properties of V6O16Cu(C4H4N2)2·(H2O)0.22(1): Charge Density Matching of a Metal-Segregated Layer Structure
Paul A. Maggard and Paul D. Boyle
pp 4250 - 4252; DOI:
10.1021/ic0342649
PDF
Luminescent Zn and Pd Tetranaphthaloporphyrins
Vladimir V. Rozhkov, Mazdak Khajehpour, and Sergei A. Vinogradov
pp 4253 - 4255; DOI:
10.1021/ic034257k
PDF
New Paramagnetic Re(II) Compounds with Nitrile and Cyanide Ligands Prepared by Homolytic Scission of Dirhenium Complexes
Eric J. Schelter, Jitendra K. Bera, John Bacsa, José Ramón Galán-Mascarós, and Kim R. Dunbar
pp 4256 - 4258; DOI:
10.1021/ic020661s
PDF
NO Orientation and Tilting in (Nitrosyl)iron(II) Deuteroporphyrin IX
Graeme R. A. Wyllie and W. Robert Scheidt
pp 4259 - 4261; DOI:
10.1021/ic034364e
PDF
Organic-Organometallic Crystal Engineering: Novel Formation of a Honeycomb Supramolecular Architecture of [Re2(-OMe)3(CO)6]- Anions Encapsulating a Linear H-Bonded Chain of [DABCO-H]+ Cations
Youngjo Kim and John G. Verkade
pp 4262 - 4264; DOI:
10.1021/ic034510g
PDF
The First 3-Oxalato-Bridged Copper Complex with Tridentate Schiff Base Ligand N-Ethyl-N'-Salicylidene-1,2-diaminoethane: Synthesis, Structure, and Magnetic Properties
He-Dong Bian, Wen Gu, Jing-Yuan Xu, Fang Bian, Shi-Ping Yan, Dai-Zheng Liao, Zong-Hui Jiang, and Peng Cheng
pp 4265 - 4267; DOI:
10.1021/ic034003z
PDF
1,1-Ethylenedithiolato Complexes of Palladium(II) and Platinum(II) with Isocyanide and Carbene Ligands
José Vicente, María Teresa Chicote, Sonia Huertas, and Peter G. Jones
pp 4268 - 4274; DOI:
10.1021/ic0343758
PDF
15N CIDNP Study of Formation and Decay of Peroxynitric Acid: Evidence for Formation of Hydroxyl Radicals
Manfred Lehnig, Michael Kirsch, and Hans-Gert Korth
pp 4275 - 4287; DOI:
10.1021/ic020650z
PDF
Dinuclear Iron Isonitrile Complexes: Models for the Iron Hydrogenase Active Site
Jennifer L. Nehring and D. Michael Heinekey
pp 4288 - 4292; DOI:
10.1021/ic034334b
PDF
Bond Dissociation Energy and Lewis Acidity of the Xenon Fluoride Cation
Ian H. Krouse and Paul G. Wenthold
pp 4293 - 4298; DOI:
10.1021/ic034301w
PDF
Templating Schiff-Base Lateral Macrobicycles: An Experimental and Theoretical Structural Study of the Intermediates
Carlos Platas-Iglesias, David Esteban, Vicente Ojea, Fernando Avecilla, Andrés de Blas, and Teresa Rodríguez-Blas
pp 4299 - 4307; DOI:
10.1021/ic034266t
PDF
Wavelength-Dependent Photofragmentation and Photoionization of Gaseous (4-Cycloocta-1,5-diene)(5-cyclopentadienyl)cobalt
Daniel Byun and Jeffrey I. Zink
pp 4308 - 4315; DOI:
10.1021/ic0300518
PDF
In Situ Fe K-Edge X-ray Absorption Fine Structure of a Nitrosyl Adduct of Iron Phthalocyanine Irreversibly Adsorbed on a High Area Carbon Electrode in an Acidic Electrolyte
Ionel C. Stefan, Yibo Mo, Sung Yong Ha, Sunghyun Kim, and Daniel A. Scherson
pp 4316 - 4321; DOI:
10.1021/ic026053u
PDF
Formation of Porphyrins in the Presence of Acid-Labile Metalloporphyrins: A New Route to Mixed-Metal Multiporphyrin Arrays
Markus Speckbacher, Lianhe Yu, and Jonathan S. Lindsey
pp 4322 - 4337; DOI:
10.1021/ic026206d
PDF
Unprecedented Chemical Transformation of Semicarbazones Mediated by Wilkinson's Catalyst
Indrani Pal, Swati Dutta, Falguni Basuli, Savitha Goverdhan, Shie-Ming Peng, Gene-Hsiang Lee, and Samaresh Bhattacharya
pp 4338 - 4345; DOI:
10.1021/ic034247j
PDF
Synthesis, Complexation, and Coordination Oligomerization of 1,8-Pyrazine-Capped 5,12-Dioxocyclams
Louis S. Hegedus, Michael J. Sundermann, and Peter K. Dorhout
pp 4346 - 4354; DOI:
10.1021/ic030090j
PDF
Dyads for Photoinduced Charge Separation Based on Platinum Diimine Bis(acetylide) Chromophores: Synthesis, Luminescence and Transient Absorption Studies
James E. McGarrah and Richard Eisenberg
pp 4355 - 4365; DOI:
10.1021/ic034026d
PDF
Electronic Structures of Mixed-Sandwich Complexes of Cyclopentadienyl and Hydrotris(pyrazolyl)borate Ligands with 3d Transition Metals
Tim J. Brunker, Jennifer C. Green, and Dermot O'Hare
pp 4366 - 4381; DOI:
10.1021/ic030073u
PDF
Synthesis and Characterization of N2S3X-Fe Models of Iron-Containing Nitrile Hydratase
Craig A. Grapperhaus, Ming Li, Apurba K. Patra, Selma Poturovic, Pawel M. Kozlowski, Marek Z. Zgierski, and Mark S. Mashuta
pp 4382 - 4388; DOI:
10.1021/ic026239t
PDF
Iron(II) and Copper(I) Coordination Polymers: Electrochromic Materials with and without Chiroptical Properties
Stefan Bernhard, Jonas I. Goldsmith, Kazutake Takada, and Héctor D. Abruña
pp 4389 - 4393; DOI:
10.1021/ic0207146
PDF
Synthesis, Characterization, and DNA Binding Properties of a Series of Ru, Pt Mixed-Metal Complexes
R. Lee Williams, H. Nathaniel Toft, Brenda Winkel, and Karen J. Brewer
pp 4394 - 4400; DOI:
10.1021/ic025810l
PDF
Synthesis and Luminescence Studies of Aryl Substituted Tetraamide Complexes of Europium(III): A New Approach to pH Responsive Luminescent Europium Probes
Mark Woods and A. Dean Sherry
pp 4401 - 4408; DOI:
10.1021/ic0300823
PDF
Structure and Magnetic Properties of Layered High-Spin Co(II)(L-threonine)2(H2O)2
Alberto C. Rizzi, Carlos D. Brondino, Rafael Calvo, Ricardo Baggio, María T. Garland, and Raul E. Rapp
pp 4409 - 4416; DOI:
10.1021/ic026111b
PDF
Cl3V(-S(CH3)2)3VCl32-: A First-Row, Face-Shared Bioctahedral Complex with Multiple Metal-Metal Bonding
Simon Petrie and Robert Stranger
pp 4417 - 4424; DOI:
10.1021/ic026276k
PDF
Increasing Solubility and Stability of Linear Tricobalt(II) Chains with depa (Diethyldipyridylamide) Ligands
John F. Berry, F. Albert Cotton, Tongbu Lu, and Carlos A. Murillo
pp 4425 - 4430; DOI:
10.1021/ic034149y
PDF
Bis(alkylamido)phenylborane Complexes of Zirconium, Hafnium, and Vanadium
David R. Manke and Daniel G. Nocera
pp 4431 - 4436; DOI:
10.1021/ic0340478
PDF
Electronegativities from Core-Ionization Energies: Electronegativities of SF5 and CF3
Jan E. True, T. Darrah Thomas, Rolf W. Winter, and Gary L. Gard
pp 4437 - 4441; DOI:
10.1021/ic0343298
PDF
Electronic Properties of 4,4',5,5'-Tetramethyl-2,2'-biphosphinine (tmbp) in the Redox Series fac-[Mn(Br)(CO)3(tmbp)], [Mn(CO)3(tmbp)]2, and [Mn(CO)3(tmbp)]-: Crystallographic, Spectroelectrochemical, and DFT Computational Study
Frantiek Hartl, Taasje Mahabiersing, Pascal Le Floch, Francois Mathey, Louis Ricard, Patrick Rosa, and Stanislav Záli
pp 4442 - 4455; DOI:
10.1021/ic0206894
PDF
Dinuclear Copper(I) Complexes with Hexaaza Macrocyclic Dinucleating Ligands: Structure and Dynamic Properties
Miquel Costas, Raul Xifra, Antoni Llobet, Miquel Solà, Juvencio Robles,, Teodor Parella, Helen Stoeckli-Evans, and Markus Neuburger
pp 4456 - 4468; DOI:
10.1021/ic0261833
PDF
Photoluminescence Properties of Four-Coordinate Gold(I)-Phosphine Complexes of the Types [Au(diphos)2]PF6 and [Au2(tetraphos)2](PF6)2
Christopher D. Delfs, Heather J. Kitto, Robert Stranger, Gerhard F. Swiegers, S. Bruce Wild, Anthony C. Willis, and Gerard J. Wilson
pp 4469 - 4478; DOI:
10.1021/ic0206701
PDF
A Layered Tungstic Acid H2W2O7·nH2O with a Double-Octahedral Sheet Structure: Conversion Process from an Aurivillius Phase Bi2W2O9 and Structural Characterization
Manabu Kudo, Hajime Ohkawa, Wataru Sugimoto, Nobuhiro Kumada, Zheng Liu, Osamu Terasaki, and Yoshiyuki Sugahara
pp 4479 - 4484; DOI:
10.1021/ic0206746
PDF

Issue 15


A Novel Bilayer Cobalt(II)-Organic Framework with Nanoscale Channels Accommodating Large Organic Molecules
Junhua Luo, Maochun Hong, Ruihu Wang, Rong Cao, Lei Han, Daqiang Yuan, Zhenzhong Lin, and Youfu Zhou
pp 4486 - 4488; DOI:
10.1021/ic034064x
PDF
Synthesis and Characterization of Ammonioundecafluoro-closo-dodecaborates(1-). New Superweak Anions
Sergei V. Ivanov, Jennifer A. Davis, Susie M. Miller, Oren P. Anderson, and Steven H. Strauss
pp 4489 - 4491; DOI:
10.1021/ic0344160
PDF
Novel Luminescent Tetranuclear and Pentanuclear Copper(I)-Dithiolates
Huan Xu and John H. K. Yip
pp 4492 - 4494; DOI:
10.1021/ic030070h
PDF
X-ray Structure and Variable Temperature NMR Spectra of [meso-Triarylcorrolato]copper(III)
Christian Brückner, Raymond P. Briñas, and Jeanette A. Krause Bauer
pp 4495 - 4497; DOI:
10.1021/ic034080u
PDF
The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl. Formation of a CO2 Soluble Polycarbonate
Donald J. Darensbourg, Jody L. Rodgers, and Cindy C. Fang
pp 4498 - 4500; DOI:
10.1021/ic034363m
PDF
Heterometallic Hexanuclear Cluster with an S = 8 Spin Ground State: MnII{MnII(hfac)2}3{NiII(pao)3}2 (hfac- = Hexafluoroacetylacetonate, pao- = Pyridine-2-aldoximate)
Hitoshi Miyasaka, Tomohiro Nezu, Fumiyasu Iwahori, Sachie Furukawa, Kunihisa Sugimoto, Rodolphe Clérac, Ken-ichi Sugiura, and Masahiro Yamashita
pp 4501 - 4503; DOI:
10.1021/ic034302o
PDF
New Structural Features of Unsupported Chains of Metal Ions in Luminescent [(NH3)4Pt][Au(CN)2]2·1.5(H2O) and Related Salts
Matthias Stender, Rochelle L. White-Morris, Marilyn M. Olmstead, and Alan L. Balch
pp 4504 - 4506; DOI:
10.1021/ic034383o
PDF
Reversible Electrochemical Generation of a Rhodium(II) Porphyrin: Thwarting Disproportionation with Weakly Coordinating Anions
Haoran Sun, Feng Xue, Andrew P. Nelson, Jody Redepenning, and Stephen G. DiMagno
pp 4507 - 4509; DOI:
10.1021/ic0345830
PDF
Isolation and Molecular Structure of Hexacyanoruthenate(III)
Jesper Bendix, Poul Steenberg, and Inger Stofte
pp 4510 - 4512; DOI:
10.1021/ic034287n
PDF
Fluxional Behavior of a Cadmium Zwitterion Complex: Proton Transport and Tautomerism in Methylene Chloride Solution
Oren P. Anderson, Agnete la Cour, Andrew Berg, Andrew D. Garrett, and Mark Wicholas
pp 4513 - 4515; DOI:
10.1021/ic034620n
PDF
Correlation between N 1s XPS Binding Energy and Bond Distance in Metal Amido, Imido, and Nitrido Complexes
Jin-Bao Wu, Yi-Feng Lin, Jelin Wang, Pei-Ju Chang, Chih-Pin Tasi, Chih-Chiang Lu, Hsin-Tien Chiu, and Yaw-Wen Yang
pp 4516 - 4518; DOI:
10.1021/ic034261w
PDF
Tungsten and Molybdenum Nitrosyl Cations in Fluorosulfonic Acid
Nobuko Tsumori and Qiang Xu
pp 4519 - 4521; DOI:
10.1021/ic034504k
PDF
Crystals from Concentrated Glyme Mixtures. The Single-Crystal Structure of LiClO4
Wesley A. Henderson and Neil R. Brooks
pp 4522 - 4524; DOI:
10.1021/ic034518q
PDF
Viewpoint: A New Showcase
Richard Eisenberg
pp 4525 - 4525; DOI:
10.1021/ic030159n
PDF
Pulsed EPR and NMR Spectroscopy of Paramagnetic Iron Porphyrinates and Related Iron Macrocycles: How To Understand Patterns of Spin Delocalization and Recognize Macrocycle Radicals
F. Ann Walker
pp 4526 - 4544; DOI:
10.1021/ic026245p
PDF
Trinuclear Heterobimetallic Complexes with Binucleating Dithioxamides: Stereoselective Synthesis and Solution Behavior Involving Pd-N Bond Rupture
Santo Lanza, Giuseppe Bruno, Francesco Nicolò, Giovanna Callipari, and Giuseppe Tresoldi
pp 4545 - 4552; DOI:
10.1021/ic034233d
PDF
Oxidative Addition of Ph2TeCl2 to a Dimethylplatinum(II) Complex: Effects of Secondary Bonding in the Platinum-Tellurium Products
Michael C. Janzen, Michael C. Jennings, and Richard J. Puddephatt
pp 4553 - 4558; DOI:
10.1021/ic030057x
PDF
Acrylate Intercalation and in Situ Polymerization in Iron-, Cobalt-, or Manganese-Substituted Nickel Hydroxides
C. Vaysse, L. Guerlou-Demourgues, E. Duguet, and C. Delmas
pp 4559 - 4567; DOI:
10.1021/ic026229s
PDF
X- and Q-Band EPR Studies of the Dinuclear Mn(II) Complex [(Bpmp)Mn2(-OAc)2]+. Determination of the Spin Parameters for the S = 1 and S = 2 Spin States
Sébastien Blanchard, Geneviève Blondin, Eric Rivière, Martine Nierlich, and Jean-Jacques Girerd
pp 4568 - 4578; DOI:
10.1021/ic0301066
PDF
Linear and Cyclic Polysilanes Containing the Bis(trimethylsilyl)amino Group: Synthesis, Reactions, and Spectroscopic Characterization
Waltraud Gollner, Karin Renger, and Harald Stueger
pp 4579 - 4584; DOI:
10.1021/ic034332r
PDF
Cubane-Type Heterometallic Sulfido Clusters: Incorporation of Two Metal Fragments into a Dinuclear ReS(-S)2ReS Core Affording Bimetallic M2Re2(3-S)4 Clusters (M = Ru, Pt, Cu) or Trimetallic MM'Re2(3-S)4 Clusters via Incomplete Cubane-Type MRe2(3-S)(2-S)3 Intermediates (M = Ru, Rh, Ir; M' = Mo, W, Pd, Ru, Rh)
Hidetake Seino, Tetsuhide Kaneko, Shunpei Fujii, Masanobu Hidai, and Yasushi Mizobe
pp 4585 - 4596; DOI:
10.1021/ic030129k
PDF
Investigation on the Chain-to-Chain and Chain-to-Open-Framework Transformations of Two One-Dimensional Aluminophosphate Chains
Kaixue Wang, Jihong Yu, Caijin Li, and Ruren Xu
pp 4597 - 4602; DOI:
10.1021/ic034015k
PDF
Metal Complexes of N-Benzamidoporphyrin: (N-Benzimido-meso-tetraphenylporphyrinato)(methanol)zinc(II) Methanol Solvate and (Acetato)(N-benzamido-meso-tetraphenylporphyrinato)cadmium(II) Benzene Solvate
Fuh-An Yang, Jyh-Horung Chen, Hsi-Ying Hsieh, Shanmugam Elango, and Lian-Pin Hwang
pp 4603 - 4609; DOI:
10.1021/ic0207202
PDF
High-Frequency and -Field EPR Spectroscopy of Tris(2,4-pentanedionato)manganese(III): Investigation of Solid-State versus Solution Jahn-Teller Effects
J. Krzystek, Gregory J. Yeagle, Ju-Hyun Park, R. David Britt, Mark W. Meisel, Louis-Claude Brunel, and Joshua Telser
pp 4610 - 4618; DOI:
10.1021/ic020712l
PDF
Trapping Tetramethoxyzincate and -cobaltate(II) between Mo24+ Units
F. Albert Cotton, Chun Y. Liu, Carlos A. Murillo, and Xiaoping Wang
pp 4619 - 4623; DOI:
10.1021/ic034167f
PDF
Vanadium-Iron-Sulfur Clusters Containing the Cubane-type [VFe3S4] Core Unit: Synthesis of a Cluster with the Topology of the PN Cluster of Nitrogenase
Jing-Lin Zuo, Hong-Cai Zhou, and R. H. Holm
pp 4624 - 4631; DOI:
10.1021/ic0301369
PDF
A New Dinuclear Ti(IV)-Peroxo-Citrate Complex from Aqueous Solutions. Synthetic, Structural, and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)-Peroxo-Citrate Speciation
M. Dakanali, E. T. Kefalas, C. P. Raptopoulou, A. Terzis, G. Voyiatzis, I. Kyrikou, T. Mavromoustakos, and A. Salifoglou
pp 4632 - 4639; DOI:
10.1021/ic0343051
PDF
NMR and Theoretical Investigations on the Structures and Dynamics of Octahedral Bis(chelate)dichloro VIII Compounds Isolated by an Unusual Reduction of Non-Oxo VIV Species
Maria Rikkou, Manolis Manos, Evangelos Tolis, Michael P. Sigalas, Themistoklis A. Kabanos, and Anastasios D. Keramidas
pp 4640 - 4649; DOI:
10.1021/ic034221s
PDF
Magic Electron Counts and Bonding in Tubular Boranes
Musiri M. Balakrishnarajan, Roald Hoffmann, Pattath D. Pancharatna, and Eluvathingal D. Jemmis
pp 4650 - 4659; DOI:
10.1021/ic0262435
PDF
Eu10Mn6Sb13: A New Ternary Rare-Earth Transition-Metal Zintl Phase
Aaron P. Holm, Seon-Mi Park, Cathie L. Condron, Marilyn M. Olmstead, Hyungrak Kim, Peter Klavins, Fernande Grandjean, Raphaël P. Hermann, Gary J. Long, Mercouri G. Kanatzidis, Susan M. Kauzlarich, and Sung-Jin Kim
pp 4660 - 4667; DOI:
10.1021/ic034054w
PDF
A Novel Tetranuclear Copper(II) Complex with Alternating 1,1-Azido and Phenoxo Bridges: Synthesis, Structure, and Magnetic Properties of [Cu4(-salen)2(1,1-N3)2(N3)2]
Subratanath Koner, Sandip Saha, Ken-Ichi Okamoto, and Jean-Pierre Tuchagues
pp 4668 - 4672; DOI:
10.1021/ic020526f
PDF
Complexes of Lanthanide Nitrates with Bis(diphenylphosphino)methane Dioxide
Anthony M. J. Lees and Andrew W. G. Platt
pp 4673 - 4679; DOI:
10.1021/ic0342954
PDF
Connecting Terminal Carboxylate Groups in Nine-Coordinate Lanthanide Podates: Consequences on the Thermodynamic, Structural, Electronic, and Photophysical Properties
Jean-Michel Senegas, Gérald Bernardinelli, Daniel Imbert, Jean-Claude G. Bünzli, Pierre-Yves Morgantini, Jacques Weber, and Claude Piguet
pp 4680 - 4695; DOI:
10.1021/ic034231t
PDF
Reactivity Studies, Structural Characterization, and Thermolysis of Cubic Titanosiloxanes: Precursors to Titanosilicate Materials Which Catalyze Olefin Epoxidation
Ramaswamy Murugavel, Paul Davis, and Vivekanand S. Shete
pp 4696 - 4706; DOI:
10.1021/ic034317m
PDF
An Unusual Dinuclear Ruthenium(III) Complex with a Conjugated Bridging Ligand Derived from Cleavage of a 1,4-Dihydro-1,2,4,5-Tetrazine Ring. Synthesis, Structure, and UV-Vis-NIR Spectroelectrochemical Characterization of a Five-Membered Redox Chain Incorporating Two Mixed-Valence States
Srikanta Patra, Thomas A. Miller, Biprajit Sarkar, Mark Niemeyer, Michael D. Ward, and Goutam Kumar Lahiri
pp 4707 - 4713; DOI:
10.1021/ic034131n
PDF
Structural, Magnetic, and Optoelectronic Properties of (Diimine)(dithiolato)platinum(II) and -palladium(II) Complexes and Their Charge-Transfer Adducts with Nitrile Acceptors
Bradley W. Smucker, Joshua M. Hudson, Mohammad A. Omary, and Kim R. Dunbar
pp 4714 - 4723; DOI:
10.1021/ic0259585
PDF
Structure of AuCN Determined from Total Neutron Diffraction
Simon J. Hibble, Alex C. Hannon, and Simon M. Cheyne
pp 4724 - 4730; DOI:
10.1021/ic0342043
PDF
Copper-Selenium Interactions: Influence of Alkane Spacer and Halide Anion in the Synthesis of Unusual Polynuclear Copper(I) Complexes with Bis(diphenylselenophosphinyl)alkanes
Tarlok S. Lobana, Rimple, Alfonso Castineiras, and Peter Turner
pp 4731 - 4737; DOI:
10.1021/ic034010n
PDF
Nanoscale Pt(0) Particles Prepared in Imidazolium Room Temperature Ionic Liquids: Synthesis from an Organometallic Precursor, Characterization, and Catalytic Properties in Hydrogenation Reactions
Carla W. Scheeren, Giovanna Machado, Jairton Dupont, Paulo F. P. Fichtner, and Sérgio Ribeiro Texeira
pp 4738 - 4742; DOI:
10.1021/ic034453r
PDF
Electron Deficient Bridges Involving Silylenes: A Theoretical Study
Prasad V. Bharatam, Rajnish Moudgil, and Damanjit Kaur
pp 4743 - 4749; DOI:
10.1021/ic026033s
PDF
Protonation Reactions of Dinuclear Pyrazolato Iridium(I) Complexes
Cristina Tejel, Miguel A. Ciriano, Marta Millaruelo, José A. López, Fernando J. Lahoz, and Luis A. Oro
pp 4750 - 4758; DOI:
10.1021/ic034225x
PDF
Octahedral Ru(II) Amido Complexes TpRu(L)(L')(NHR) (Tp = Hydridotris(pyrazolyl)borate; L = L' = P(OMe)3 or PMe3 or L = CO and L' = PPh3; R = H, Ph, or tBu): Synthesis, Characterization, and Reactions with Weakly Acidic C-H Bonds
David Conner, K. N. Jayaprakash, Michael B. Wells, Selena Manzer, T. Brent Gunnoe, and Paul D. Boyle
pp 4759 - 4772; DOI:
10.1021/ic034410a
PDF
Density Functional Theory Investigation of the Active Site of [Fe]-Hydrogenases: Effects of Redox State and Ligand Characteristics on Structural, Electronic, and Reactivity Properties of Complexes Related to the [2Fe]H Subcluster
Maurizio Bruschi, Piercarlo Fantucci, and Luca De Gioia
pp 4773 - 4781; DOI:
10.1021/ic0262132
PDF
Spin Crossover Behavior in the Iron(II)-2-pyridyl[1,2,3]triazolo[1,5-a]pyridine System: X-ray Structure, Calorimetric, Magnetic, and Photomagnetic Studies
Virginie Niel, Ana B. Gaspar, M. Carmen Muñoz, Belén Abarca, Rafael Ballesteros, and José Antonio Real
pp 4782 - 4788; DOI:
10.1021/ic034366z
PDF

Issue 16


Mononuclear N3S(thioether)-Ligated Copper(II) Methoxide Complexes: Synthesis, Characterization, and Hydrolytic Reactivity
Kyle J. Tubbs, Amy L. Fuller, Brian Bennett, Atta M. Arif, and Lisa M. Berreau
pp 4790 - 4791; DOI:
10.1021/ic034661j
PDF
Ferromagnetic Ordering and Metamagnetism in Malonate Bridged 3D Diamond-like and Honeycomb-like Networks: [Cu(mal)(DMF)]n and {[Cu(mal)(0.5pyz)]·H2O}n (mal = Malonate Dianion, DMF = N,N-dimethylformamide, pyz = Pyrazine)
Tian-Fu Liu, Hao-Ling Sun, Song Gao, Shi-Wei Zhang, and Tai-Chu Lau
pp 4792 - 4794; DOI:
10.1021/ic034346x
PDF
Self-Assembly of Octarhenium-Based Neutral Luminescent Rectangular Prisms
Bala. Manimaran, P. Thanasekaran, T. Rajendran, Rong-Tang Liao, Yen-Hsiang Liu, Gene-Hsiang Lee, Shie-Ming Peng, S. Rajagopal, and Kuang-Lieh Lu
pp 4795 - 4797; DOI:
10.1021/ic034172j
PDF
Utilization of CS2 as a Source of C1 Chemistry for the Generation of Methyldithioformate
Thirumanavelan Gandhi, Munirathinam Nethaji, and Balaji R. Jagirdar
pp 4798 - 4800; DOI:
10.1021/ic0346937
PDF
Structural Studies of Transition Metal Complexes with 4,5-Bis(2-pyridylmethylsulfanyl)-4',5'-ethylenedithiotetrathiafulvalene: Probing Their Potential for the Construction of Multifunctional Molecular Assemblies
Shi-Xia Liu, Stefan Dolder, Patrick Franz, Antonia Neels, Helen Stoeckli-Evans, and Silvio Decurtins
pp 4801 - 4803; DOI:
10.1021/ic034348h
PDF
The First Example of a Monomeric Alumatrane
Youngjo Kim and John G. Verkade
pp 4804 - 4806; DOI:
10.1021/ic034444i
PDF
Effect of Electron Availability on Selectivity of O2 Reduction by Synthetic Monometallic Fe Porphyrins
James P. Collman, Irina M. Shiryaeva, and Roman Boulatov
pp 4807 - 4809; DOI:
10.1021/ic034488r
PDF
"Chiral-at-Metal" Octahedral Ruthenium(II) Complexes with Achiral Ligands: A New Type of Enantioselective Catalyst
Murielle Chavarot, Stéphane Ménage, Olivier Hamelin, Florence Charnay, Jacques Pécaut, and Marc Fontecave
pp 4810 - 4816; DOI:
10.1021/ic0341338
PDF
Binuclear Manganese Compounds of Potential Biological Significance. Part 2. Mechanistic Study of Hydrogen Peroxide Disproportionation by Dimanganese Complexes: The Two Oxygen Atoms of the Peroxide End up in a Dioxo Intermediate
Lionel Dubois, Régis Caspar, Lilian Jacquamet, Pierre-Emmanuel Petit, Marie-France Charlot, Carole Baffert, Marie-Noëlle Collomb, Alain Deronzier, and Jean-Marc Latour
pp 4817 - 4827; DOI:
10.1021/ic020646n
PDF
Formation of Two Diverse Classes of Poly(amino-alkoxide) Chelates and Their Mononuclear and Polynuclear Lanthanide(III) Complexes
Marlon K. Thompson, Alan J. Lough, Andrew J. P. White, David J. Williams, and Ishenkumba A. Kahwa
pp 4828 - 4841; DOI:
10.1021/ic020154a
PDF
An Electron Paramagnetic Resonance Study of Copper(II)--Substituted -Amino Acid Systems by the Two-Dimensional Simulation Method: First Evidence of Primarily Steric Effects of Substituents on Equilibria of Metal Complexes
Zsuzsanna Árkosi, Terézia Szabó-Plánka, Antal Rockenbauer, Nóra Veronika Nagy, László Lázár, and Ferenc Fülöp
pp 4842 - 4848; DOI:
10.1021/ic030065d
PDF
A Compelling Experimental Test of the Hypothesis That Enzymes Have Evolved To Enhance Quantum Mechanical Tunneling in Hydrogen Transfer Reactions: The -Neopentylcobalamin System Combined with Prior Adocobalamin Data
Kenneth M. Doll and Richard G. Finke
pp 4849 - 4856; DOI:
10.1021/ic0300722
PDF
Preparation, Structures, and Redox and Emission Characteristics of the Isothiocyanate Complexes of Hexarhenium(III) Clusters [Re6(3-E)8(NCS)6]4- (E = S, Se)
Takashi Yoshimura, Zhong-Ning Chen, Ai Itasaka, Masaaki Abe, Yoichi Sasaki, Shoji Ishizaka, Noboru Kitamura, Spartak S. Yarovoi, Sergey F. Solodovnikov, and Vladimir E. Fedorov
pp 4857 - 4863; DOI:
10.1021/ic030030d
PDF
Synthesis, Characterization, and Evaluation of [Ir(ppy)2(vpy)Cl] as a Polymer-Bound Oxygen Sensor
Maria C. DeRosa, Peter J. Mosher, Glenn P. A. Yap, K.-S. Focsaneanu, Robert J. Crutchley, and Christopher E. B. Evans
pp 4864 - 4872; DOI:
10.1021/ic026230r
PDF
Theoretical Characterization of Stable 1-N2O-, 2-N2O-, 1-N2-, and 2-N2-Bound Species: Intermediates in the Addition Reactions of Nitrogen Hydrides with the Pentacyanonitrosylferrate(II) Ion
José A. Olabe and Guillermina L. Estiú
pp 4873 - 4880; DOI:
10.1021/ic0261880
PDF
Tailor-Made Strong Exchange Magnetic Coupling through Very Long Bridging Ligands: Theoretical Predictions
Eliseo Ruiz, Antonio Rodríguez-Fortea, and Santiago Alvarez
pp 4881 - 4884; DOI:
10.1021/ic026179r
PDF
Effects of Steric Constraint on Chromium(III) Complexes of Tetraazamacrocycles. Chemistry and Excited-State Behavior of 1,4-C2-Cyclam Complexes
Kimberley Wright-Garcia, Jillian Basinger, Sarah Williams, Chuanjiang Hu, Paul S. Wagenknecht, and Lawrence C. Nathan
pp 4885 - 4890; DOI:
10.1021/ic030037v
PDF
Enantioselective Recognition between Chiral -Hydroxy-Carboxylates and Macrocyclic Heptadentate Lanthanide(III) Chelates
Enzo Terreno, Mauro Botta, Franco Fedeli, Bruna Mondino, Luciano Milone, and Silvio Aime
pp 4891 - 4897; DOI:
10.1021/ic034321y
PDF
Synthesis, Structure, and Properties of the New Intermetallic Compounds SrPdTl2 and SrPtTl2
Shengfeng Liu and John D. Corbett
pp 4898 - 4901; DOI:
10.1021/ic030089k
PDF
Spectroscopic and Density Functional Studies of the Dinitrosyl Metalloporphyrin Complexes Fe(P)(NO)2 and Ru(P)(NO)2
James C. Patterson, Ivan M. Lorkovi, and Peter C. Ford
pp 4902 - 4908; DOI:
10.1021/ic034079v
PDF
Stoichiometric and Catalytic Activation of the - and -2,3,4-Tri-O-Acetyl-5-Thioxylopyranosyl Bromide Inside the Cavity of the Pd3(dppm)3(CO)2+ Cluster
David Brevet, Yves Mugnier, Frédéric Lemaître, Dominique Lucas, Soth Samreth, and Pierre D. Harvey
pp 4909 - 4917; DOI:
10.1021/ic026279x
PDF
X-ray Structures, Photophysical Characterization, and Computational Analysis of Geometrically Constrained Copper(I)-Phenanthroline Complexes
John Cody, Jeanette Dennisson, Joshua Gilmore, Donald G. VanDerveer, Maged M. Henary, Alan Gabrielli, C. David Sherrill, Yiyun Zhang, Chia-Pin Pan, Clemens Burda, and Christoph J. Fahrni
pp 4918 - 4929; DOI:
10.1021/ic034529j
PDF
Toward Optimized High-Relaxivity MRI Agents: The Effect of Ligand Basicity on the Thermodynamic Stability of Hexadentate Hydroxypyridonate/Catecholate Gadolinium(III) Complexes
Dan M. J. Doble, Marco Melchior, Brendon O'Sullivan, Carsten Siering, Jide Xu, Valérie C. Pierre, and Kenneth N. Raymond
pp 4930 - 4937; DOI:
10.1021/ic026240s
PDF
Crystal Structures and Vibrational and Solution and Solid-State (CPMAS) NMR Spectroscopic Studies in Triphenyl Phosphine, Arsine, and Stibine Silver(I) Bromate Systems, (R3E)xAgBrO3 (E = P, As, Sb; x = 1-4)
Augusto Cingolani, Effendy, John V. Hanna, Maura Pellei, Claudio Pettinari, Carlo Santini, Brian W. Skelton, and Allan H. White
pp 4938 - 4948; DOI:
10.1021/ic034243e
PDF
Chalcogeno-urea Ligands on a Phosphadiazonium Lewis Acceptor: A New Synthetic Approach to Ch-P Bonds (Ch = O, S, Se)
Neil Burford, Andrew D. Phillips, Heather A. Spinney, Katherine N. Robertson, T. Stanley Cameron, and Robert McDonald
pp 4949 - 4954; DOI:
10.1021/ic034182k
PDF
Metal Binding Characteristics of a Laterally Nonsymmetric Aza Cryptand upon Functionalization with a -Acceptor Group
Pritam Mukhopadhyay, Bijay Sarkar, Parimal K. Bharadwaj, Kalle Nättinen, and Kari Rissanen
pp 4955 - 4960; DOI:
10.1021/ic034183c
PDF
Group 6 Imido Complexes Supported by Diamido-Donor Ligands
Benjamin D. Ward, Stuart R. Dubberley, Lutz H. Gade, and Philip Mountford
pp 4961 - 4969; DOI:
10.1021/ic034377s
PDF
Neutral and Ionic Aluminum, Gallium, and Indium Compounds Carrying Two or Three Terminal Ethynyl Groups
Marcus Schiefer, N. Dastagiri Reddy, Hans-Jürgen Ahn, Andreas Stasch, Herbert W. Roesky, A. Christine Schlicker, Hans-Georg Schmidt, Mathias Noltemeyer, and Denis Vidovic
pp 4970 - 4976; DOI:
10.1021/ic0342806
PDF
Molecular Structures, Bond Energies, and Bonding Analysis of Group 11 Cyanides TM(CN) and Isocyanides TM(NC) (TM = Cu, Ag, Au)
Oliver Dietz, Víctor M. Rayón, and Gernot Frenking
pp 4977 - 4984; DOI:
10.1021/ic034120u
PDF
High-Dimensional Architectures from the Self-Assembly of Lanthanide Ions with Benzenedicarboxylates and 1,10-Phenanthroline
Yonghong Wan, Liping Zhang, Linpei Jin, Song Gao, and Shaozhe Lu
pp 4985 - 4994; DOI:
10.1021/ic034258c
PDF
Novel Pb(II), Zn(II), and Cd(II) Coordination Polymers Constructed from Ferrocenyl-Substituted Carboxylate and Bipyridine-Based Ligands
Gang Li, Hongwei Hou, Linke Li, Xiangru Meng, Yaoting Fan, and Yu Zhu
pp 4995 - 5004; DOI:
10.1021/ic034324a
PDF
Controlled Reactions on a Copper Surface: Synthesis and Characterization of Nanostructured Copper Compound Films
Weixin Zhang, Xiaogang Wen, and Shihe Yang
pp 5005 - 5014; DOI:
10.1021/ic0344214
PDF
Investigation of the Interaction between 1-Hydroxyethane-1,1'-diphosphonic Acid (HEDP) and Uranium(VI)
Christophe Jacopin, Marcin Sawicki, Gabriel Plancque, Denis Doizi, Frédéric Taran, Eric Ansoborlo, Badia Amekraz, and Christophe Moulin
pp 5015 - 5022; DOI:
10.1021/ic0343509
PDF
Facile Preparation and Photophysics of Near-Infrared Luminescent Lanthanide(III) Monoporphyrinate Complexes
Timothy J. Foley, Benjamin S. Harrison, Alison S. Knefely, Khalil A. Abboud, John R. Reynolds, Kirk S. Schanze, and James M. Boncella
pp 5023 - 5032; DOI:
10.1021/ic034217g
PDF

Issue 17


Syntheses of Aluminum and Zinc Alkyl Complexes of a Highly Fluorinated Tris(pyrazolyl)borate Using [HB(3,5-(CF3)2Pz)3]Ag(THF) as the Ligand Transfer Agent
H. V. Rasika Dias and Wiechang Jin
pp 5034 - 5036; DOI:
10.1021/ic0345875
PDF
Sodium Cobalt Aminomethylidenediphosphonate with a Novel Open Framework Structure
Song-Song Bao, Li-Min Zheng, Yong-Jiang Liu, Wei Xu, and Shouhua Feng
pp 5037 - 5039; DOI:
10.1021/ic0344158
PDF
The Metal-to-Ligand Charge-Transfer Luminescences of Ruthenium(II)-Polypyridine-Tetraam(m)ine Complexes. Support for the Interconvertibility of Optical and Thermal (Kinetic) Franck-Condon Parameters
Puhui Xie, Yuan-Jang Chen, John F. Endicott, Md. Jamal Uddin, Dhehinie Seneviratne, and Patrick G. McNamara
pp 5040 - 5042; DOI:
10.1021/ic034545g
PDF
Elite New Anion Ligands: Polythioamide Macrocycles
Md. Alamgir Hossain, Sung Ok Kang, José M. Llinares, Douglas Powell, and Kristin Bowman-James
pp 5043 - 5045; DOI:
10.1021/ic034735r
PDF
Protonation Studies of the New Iron Carbonyl Cyanide trans-[Fe(CO)3(CN)2]2-: Implications with Respect to Hydrogenases
Ajay Kayal and Thomas B. Rauchfuss
pp 5046 - 5048; DOI:
10.1021/ic034455b
PDF
A Novel Zirconium Polyoxometalate Complex That Contains Both a Coordinated Saturated Anion, [PMo12O40]3-, and a Coordinated Unsaturated Anion, [PMo11O39]7-
Andrew J. Gaunt, Iain May, David Collison, and O. Danny Fox
pp 5049 - 5051; DOI:
10.1021/ic034273h
PDF
K10M4Sn4S17 (M = Mn, Fe, Co, Zn): Soluble Quaternary Sulfides with the Discrete [M4Sn4S17]10- Supertetrahedral Clusters
Oleg Palchik, Ratnasabapathy G. Iyer, J. H. Liao, and Mercouri G. Kanatzidis
pp 5052 - 5054; DOI:
10.1021/ic034600l
PDF
Bis(phosphino)borates: A New Family of Monoanionic Chelating Phosphine Ligands
J. Christopher Thomas and Jonas C. Peters
pp 5055 - 5073; DOI:
10.1021/ic034150x
PDF
The Strong-Field Tripodal Phosphine Donor, [PhB(CH2PiPr2)3]-, Provides Access to Electronically and Coordinatively Unsaturated Transition Metal Complexes
Theodore A. Betley and Jonas C. Peters
pp 5074 - 5084; DOI:
10.1021/ic0343096
PDF
An 17O NMR and Quantum Chemical Study of Monoclinic and Orthorhombic Polymorphs of Triphenylphosphine Oxide
David L. Bryce, Klaus Eichele, and Roderick E. Wasylishen
pp 5085 - 5096; DOI:
10.1021/ic020706p
PDF
Sterically Congested Tripodal Phosphites: Conformational Analysis, Solid-State Polymorphism, Metal Complexation, and Application to the Asymmetric Hydrosilation of Ketones1
Sai P. Shum, Stephen D. Pastor, Anthony D. DeBellis, Paul A. Odorisio, Lilibeth Burke, Frank H. Clarke, Grety Rihs, Bogdan Piatek, and Ronald K. Rodebaugh
pp 5097 - 5106; DOI:
10.1021/ic030099l
PDF
Stability and Acidity Constants for Ternary Ligand-Zinc-Hydroxo Complexes of Tetradentate Tripodal Ligands
Yu-Hung Chiu and James W. Canary
pp 5107 - 5116; DOI:
10.1021/ic025855m
PDF
Diplatinum(III) Complexes with Four Bridging 1-Methylcytosinato Nucleobases Derived from a Mononuclear trans-(NH3)2PtII Complex and CuII
Jens Müller, Eva Freisinger, Pablo J. Sanz Miguel, and Bernhard Lippert
pp 5117 - 5125; DOI:
10.1021/ic0343152
PDF
Ligand Entrapment in Twofold Interpenetrating PtS Matrixes by Metallo-Organic Frameworks
Kalle I. Nättinen and Kari Rissanen
pp 5126 - 5134; DOI:
10.1021/ic034246r
PDF
Nature of the Reactants and Influence of Water on the Supramolecular Assembly
Xiaobai Wang and Jagadese J. Vittal
pp 5135 - 5142; DOI:
10.1021/ic0344970
PDF
Structure, Magnetism, and Electrochemistry of the Multinickel Polyoxoanions [Ni6As3W24O94(H2O)2]17-, [Ni3Na(H2O)2(AsW9O34)2]11-, and [Ni4Mn2P3W24O94(H2O)2]17-
Israel M. Mbomekalle, Bineta Keita, Martine Nierlich, Ulrich Kortz, Patrick Berthet, and Louis Nadjo
pp 5143 - 5152; DOI:
10.1021/ic0343915
PDF
Syntheses and Structures of Zwitterionic Indium(III) and Di-zinc Compounds of an Extended Nitrogenous Ligand. Examples of Unusually Long Wavelength Transitions in d10-Metal Complexes
Srijit Das, Chen-Hsiung Hung, and Sreebrata Goswami
pp 5153 - 5157; DOI:
10.1021/ic030009c
PDF
Synthesis and Structural Characterization of Porphyrinic Enediynes: Geometric and Electronic Effects on Thermal and Photochemical Reactivity
Tilak Chandra, Brian J. Kraft, John C. Huffman, and Jeffrey M. Zaleski
pp 5158 - 5172; DOI:
10.1021/ic030035a
PDF
Electron Donor-Acceptor Dyads and Triads Based on Tris(bipyridine)ruthenium(II) and Benzoquinone: Synthesis, Characterization, and Photoinduced Electron Transfer Reactions
Magnus Borgström, Olof Johansson, Reiner Lomoth, Helena Berglund Baudin, Staffan Wallin, Licheng Sun, Björn Åkermark, and Leif Hammarström
pp 5173 - 5184; DOI:
10.1021/ic020606j
PDF
Replacement of 2,2'-Bipyridine by 1,4-Diazabutadiene Acceptor Ligands: Why the Bathochromic Shift for [(NN)IrCl(C5Me5)]+ Complexes but the Hypsochromic Shift for (NN)Ir(C5Me5)?
Stanislav Záli, Monika Sieger, Stefan Greulich, Hermann Stoll, and Wolfgang Kaim
pp 5185 - 5191; DOI:
10.1021/ic034464k
PDF
Electrical Conducting and Magnetic Properties of (Ethylenedithiotetrathiafulvalenothioquinone-1,3-diselenolemethide)2·FeBr4 (GaBr4) Crystals with Two Different Interlayer Arrangements of Donor Molecules
Takuya Matsumoto, Yohsuke Kamada, Toyonari Sugimoto, Toshiji Tada, Satoru Noguchi, Hiroyuki Nakazumi, Motoo Shiro, Harukazu Yoshino, and Keizo Murata
pp 5192 - 5201; DOI:
10.1021/ic030083v
PDF
Effect of the Sixth Axial Ligand in CS-Ligated Iron(II)octaethylporphyrinates: Structural and Mössbauer Studies
Changsheng Cao, S. Dahal, Mayou Shang, Alicia M. Beatty, Wendy Hibbs, Charles E. Schulz, and W. Robert Scheidt
pp 5202 - 5210; DOI:
10.1021/ic030043r
PDF
Synthesis, Characterization, and Laser Flash Photolysis Reactivity of a Carbonmonoxy Heme Complex
David W. Thompson, Ryan M. Kretzer, Estelle L. Lebeau, Donald V. Scaltrito, Reza A. Ghiladi, Kin-Chung Lam, Arnold L. Rheingold, Kenneth D. Karlin, and Gerald J. Meyer
pp 5211 - 5218; DOI:
10.1021/ic026307b
PDF
Binuclear Homoleptic Manganese Carbonyls: Mn2(CO)x (x = 10, 9, 8, 7)
Yaoming Xie, Jee Hwan Jang, R. Bruce King, and Henry F. Schaefer, III
pp 5219 - 5230; DOI:
10.1021/ic030118r
PDF
Metal-Bridging Mechanism for O-O Bond Cleavage in Cytochrome c Oxidase
Margareta R. A. Blomberg, Per E. M. Siegbahn, and Mårten Wikström
pp 5231 - 5243; DOI:
10.1021/ic034060s
PDF
DFT Calculations of Isomer Shifts and Quadrupole Splitting Parameters in Synthetic Iron-Oxo Complexes: Applications to Methane Monooxygenase and Ribonucleotide Reductase
Tiqing Liu, Timothy Lovell, Wen-Ge Han, and Louis Noodleman
pp 5244 - 5251; DOI:
10.1021/ic020640y
PDF
Influence of the Ligand on the Coupling between the Metal-Based Electrons in Face-Shared [M2X9]3- (M = Mo, W; X = F, Cl, Br, I) Systems
Germán Cavigliasso and Robert Stranger
pp 5252 - 5258; DOI:
10.1021/ic026291p
PDF
Hydroxyl Radical Formation by O-O Bond Homolysis in Peroxynitrous Acid
Sergei V. Lymar, Rafail F. Khairutdinov, and James K. Hurst
pp 5259 - 5266; DOI:
10.1021/ic030104l
PDF
Electron-Transfer Kinetics of Copper(II/I) Tripodal Ligand Complexes
Edna A. Ambundo, Qiuyue Yu, L. A. Ochrymowycz, and D. B. Rorabacher
pp 5267 - 5273; DOI:
10.1021/ic030176c
PDF
Magnetism of Cyano-Bridged Hetero-One-Dimensional Ln3+-M3+ Complexes (Ln3+ = Sm, Gd, Yb; M3+ = FeLS, Co)
Albert Figuerola, Carmen Diaz, Joan Ribas, Vassilis Tangoulis, Claudio Sangregorio, Dante Gatteschi, Miguel Maestro, and José Mahía
pp 5274 - 5281; DOI:
10.1021/ic034051j
PDF
Synthesis, Characterization, and Computational Study of the trans-IO2F52- Anion
Jerry A. Boatz, Karl O. Christe, David A. Dixon, Barbara A. Fir, Michael Gerken, Robert Z. Gnann, Hélène P. A. Mercier, and Gary J. Schrobilgen
pp 5282 - 5292; DOI:
10.1021/ic034457w
PDF
Magnetic and Optical Studies on an S = 6 Ground-State Cluster [Cr12O9(OH)3(O2CCMe3)15]: Determination of, and the Relationship Between, Single-Ion and Cluster Spin Hamiltonian Parameters
David Collison, Mark Murrie, Vasily S. Oganesyan, Stergios Piligkos, Nigel R. J. Poolton, Gopalan Rajaraman, Graham M. Smith, Andrew J. Thomson, Grigore A. Timko, Wolfgang Wernsdorfer, Richard E. P. Winpenny, and Eric J. L. McInnes
pp 5293 - 5303; DOI:
10.1021/ic034541b
PDF
Silver(I) Coordination Chemistry of 2,6-Diarylpyrazines. -Stacking, Anion Coordination, and Steric Control
Nate Schultheiss, Douglas R. Powell, and Eric Bosch
pp 5304 - 5310; DOI:
10.1021/ic034277m
PDF
Syntheses and Structures of Dinuclear Gold(I) Dithiophosphonate Complexes and the Reaction of the Dithiophosphonate Complexes with Phosphines: Diverse Coordination Types
Angelo Maspero, Ibrahim Kani, Ahmed A. Mohamed, Mohammad A. Omary, Richard J. Staples, and John P. Fackler, Jr.
pp 5311 - 5319; DOI:
10.1021/ic034114y
PDF
Syntheses and Characterization of Titanium(IV) and Titanium(III) Complexes with (2-Dimethylphosphino)ethane-1-thiolate and (3-Dimethylphosphino)propane-1-thiolate as Ligands
Kazutaka Matsuzaki, Hiroyuki Kawaguchi, Peter Voth, Kyoko Noda, Sumitaka Itoh, Hideo D. Takagi, Kazuo Kashiwabara, and Kazuyuki Tatsumi
pp 5320 - 5329; DOI:
10.1021/ic034353l
PDF
Effect of Mono- versus Di-ammonium Cation of 2,2'-Bithiophene Derivatives on the Structure of Organic-Inorganic Hybrid Materials Based on Iodo Metallates
Xu-Hui Zhu, Nicolas Mercier, Pierre Frère, Philippe Blanchard, Jean Roncali, Magali Allain, Claude Pasquier, and Amédée Riou
pp 5330 - 5339; DOI:
10.1021/ic034235y
PDF
Coordination Chemistry of Silanedithiolato Ligands Derived from Cyclotrisilathiane: Synthesis and Structures of Complexes of Iron(II), Cobalt(II), Palladium(II), Copper(I), and Silver(I)
Takashi Komuro, Tsukasa Matsuo, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi
pp 5340 - 5347; DOI:
10.1021/ic0343253
PDF
Uranyl and Strontium Salt Solvation in Room-Temperature Ionic Liquids. A Molecular Dynamics Investigation
Alain Chaumont, Etienne Engler, and Georges Wipff
pp 5348 - 5356; DOI:
10.1021/ic034281y
PDF
Structural Variations of Potassium Aryloxides
Timothy J. Boyle, Nicholas L. Andrews, Mark A. Rodriguez, Charles Campana, and Timothy Yiu
pp 5357 - 5366; DOI:
10.1021/ic034222k
PDF
Design and Synthesis of a New Binucleating Ligand via Cobalt-Promoted C-N Bond Fusion Reaction. Ligand Isolation and Its Coordination to Nickel, Palladium, and Platinum
Kunal K. Kamar, Srijit Das, Chen-Hsiung Hung, Alfonso Castiñeiras, Michael D. Kuz'min, Conrado Rillo, Juan Bartolomé, and Sreebrata Goswami
pp 5367 - 5375; DOI:
10.1021/ic034313h
PDF
Mixed-Valence State of Optically Active 1',1' ''-Bis(2-phenylbutyl)-1,1' '-biferrocenium Pentaiodide: Effects of Cation Symmetry and Intermolecular Interaction on Trapped-/Detrapped-Valence States
Takashi Oda, Satoru Nakashima, and Tsutomu Okuda
pp 5376 - 5383; DOI:
10.1021/ic0343455
PDF
Synthesis and Solution Characterization of [Ru(bpy)2]2+ Modified Polyazines
Meng Cheng and William B. Euler
pp 5384 - 5391; DOI:
10.1021/ic0343049
PDF
X-ray Absorption Spectroscopic Studies of Chromium Nitroso Complexes. Crystal and Molecular Structure of (Ph4P)3[Cr(NO)(NCS)5]·2.4(CH3)2CO
Aviva Levina, Peter Turner, and Peter A. Lay
pp 5392 - 5398; DOI:
10.1021/ic0340480
PDF
Long-Range Ferromagnetic Ordering in Two-Dimensional Coordination Polymers Co[N(CN)2]2(L) [L = Pyrazine Dioxide (pzdo) and 2-Methyl Pyrazine Dioxide (mpdo)] with Dual - and 3-[N(CN)2] Bridges
Hao-Ling Sun, Song Gao, Bao-Qing Ma, and Gang Su
pp 5399 - 5404; DOI:
10.1021/ic034202i
PDF
Chemically Induced Cyclometalation of 2-(Arylazo)phenols. Synthesis, Characterization, and Redox Properties of a Family of Organoosmium Complexes
Parna Gupta, Ray J. Butcher, and Samaresh Bhattacharya
pp 5405 - 5411; DOI:
10.1021/ic0343713
PDF
Chelating Agents Related to Ethylenediamine Bis(2-hydroxyphenyl)acetic Acid (EDDHA): Synthesis, Characterization, and Equilibrium Studies of the Free Ligands and Their Mg2+, Ca2+, Cu2+, and Fe3+ Chelates
Felipe Yunta, Sonia García-Marco, Juan J. Lucena, Mar Gómez-Gallego, Roberto Alcázar, and Miguel A. Sierra
pp 5412 - 5421; DOI:
10.1021/ic034333j
PDF
Preparation and Characterization of [Hg{P(C6F5)2}2], [Hg{(-P(C6F5)2)W(CO)5}2], and [Hg{(-P(CF3)2)W(CO)5}2] and the X-ray Crystal Structure of [Hg{(-P(C6F5)2)W(CO)5}2]·2DMF
Berthold Hoge, Tobias Herrmann, Christoph Thösen, and Ingo Pantenburg
pp 5422 - 5428; DOI:
10.1021/ic034448n
PDF
Synthesis and Characterization of Vanadium(V)-Phosphinimide Complexes
Sarah B. Hawkeswood and Douglas W. Stephan
pp 5429 - 5433; DOI:
10.1021/ic030151d
PDF
NMR Studies of Phenylbenzohydroxamic Acid and Kinetics of Complex Formation with Nickel(II)
Begoña García, Saturnino Ibeas, A. Muñoz, José M. Leal, Chiara Ghinami, Fernando Secco, and Marcella Venturini
pp 5434 - 5441; DOI:
10.1021/ic034161q
PDF
The Thermostability and Reactivity of GaP Nanocrystals in Oxygen: From GaP Nanocrystals to Ga2O3 Nanocrystals
Shanmin Gao, Yi Xie, Liying Zhu, and Xiaobo Tian
pp 5442 - 5447; DOI:
10.1021/ic034327n
PDF
A Hybrid Metalloarsenate 3D Framework-1D Interrupted Metal Oxide
Robert W. Hughes, Lee A. Gerrard, Daniel J. Price, and Mark T. Weller:
pp 5448 - 5448; DOI:
10.1021/ic030198z
PDF

Issue 18


Biocatalytic Synthesis of the Conjugated Bridging Ligand Tetrapyrido[3,2-a:2',3'-c:3' ',2' '-h:2' '',3' ''-j]phenazine (tpphz) and a Dinuclear Ruthenium Complex
Ravi Mosurkal, Lynne A. Samuelson, and Jayant Kumar
pp 5450 - 5452; DOI:
10.1021/ic034197i
PDF
Generation of an Equilibrating Collection of Crystalline Solids from a Dynamic Combinational Library
Ke-liang Pang, Dong Guo, Chun-ying Duan, Hong Mo, and Qing-jin Meng
pp 5453 - 5455; DOI:
10.1021/ic034176o
PDF
Ferromagnetic Coupling in the Three-Dimensional Malonato-Bridged Gadolinium(III) Complex [Gd2(mal)3(H2O)6] (H2mal = Malonic Acid)
María Hernández-Molina, Catalina Ruiz-Pérez, Trinidad López, Francesc Lloret, and Miguel Julve
pp 5456 - 5458; DOI:
10.1021/ic034175w
PDF
Synthesis and Characterization of Novel Grid Coordination Polymer Networks Generated from Unsymmetrically Bridging Ligands
Dong Mok Shin, In Su Lee, Young Keun Chung, and Myoung Soo Lah
pp 5459 - 5461; DOI:
10.1021/ic034276u
PDF
TACN-Amino Acid Conjugates and Their Copper(II) Complexes
Arunendu Mondal, Eric L. Klein, Masood A. Khan, and Robert P. Houser
pp 5462 - 5464; DOI:
10.1021/ic034598y
PDF
PGSE and NOE NMR Evidence for Higher Order Aggregation in Some Cationic Ruthenium Complexes in Both Protic and Aprotic Solvents
Daniele Zuccaccia, Stefano Sabatini, Gianfranco Bellachioma, Giuseppe Cardaci, Eric Clot, and Alceo Macchioni
pp 5465 - 5467; DOI:
10.1021/ic034549l
PDF
A Fluorescent (E)-Poly(p-phenylenephosphaalkene) Prepared by a Phospha-Wittig Reaction
Rhett C. Smith, Xufang Chen, and John D. Protasiewicz
pp 5468 - 5470; DOI:
10.1021/ic0345471
PDF
Amido Phosphine Complexes of Zinc
Lan-Chang Liang, Wei-Ying Lee, and Chen-Hsiung Hung
pp 5471 - 5473; DOI:
10.1021/ic0346228
PDF
Na7Sn12: A Binary Zintl Phase with a Two-Dimensional Covalently Bonded Tin Framework
Thomas F. Fässler and Stefan Hoffmann
pp 5474 - 5476; DOI:
10.1021/ic030148u
PDF
The Unusual Paramagnetic Mixed-Metal Carbonyl Chalcogenide Clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se)
Minghuey Shieh, Ren-Ling Chung, Chun-Hsien Yu, Miao-Hsing Hsu, Chia-Hua Ho, Shie-Ming Peng, and Yi-Hung Liu
pp 5477 - 5479; DOI:
10.1021/ic034081m
PDF
Electrochemical Preparation of the Bis(ruthenocenium) Dication
Sabrina Trupia, Ayman Nafady, and William E. Geiger
pp 5480 - 5482; DOI:
10.1021/ic030146+
PDF
Short Metal-Metal Separations in a Highly Luminescent Trimetallic Ag(I) Complex Stabilized by Bridging NHC Ligands
Vincent J. Catalano and Mark A. Malwitz
pp 5483 - 5485; DOI:
10.1021/ic034483u
PDF
A Three-Dimensional Manganese(II) Complex Exhibiting Ferrimagnetic and Metamagnetic Behaviors
Ruihu Wang, Enqing Gao, Maochun Hong, Song Gao, Junhua Luo, Zhenzhong Lin, Lei Han, and Rong Cao
pp 5486 - 5488; DOI:
10.1021/ic034550k
PDF
Solvent Switching of Intramolecular Energy Transfer in Bichromophoric Systems: Photophysics of (2,2'-Bipyridine)tetracyanoruthenate(II)/Pyrenyl Complexes
M. T. Indelli, M. Ghirotti, A. Prodi, C. Chiorboli, F. Scandola, N. D. McClenaghan, F. Puntoriero, and S. Campagna
pp 5489 - 5497; DOI:
10.1021/ic034185x
PDF
Reaction of Polynuclear Platinum Antitumor Compounds with Reduced Glutathione Studied by Multinuclear (1H, 1H-15N Gradient Heteronuclear Single-Quantum Coherence, and 195Pt) NMR Spectroscopy
Michael E. Oehlsen, Yun Qu, and Nicholas Farrell
pp 5498 - 5506; DOI:
10.1021/ic030045b
PDF
Synthesis and Magnetic Properties of Heterometal Cyclic Tetranuclear Complexes [CuIILMII(hfac)]2 (MII = Zn, Cu, Ni, Co, Fe, Mn; H3L = 1-(2-Hydroxybenzamido)-2-((2-hydroxy-3-methoxybenzylidene)amino)ethane; Hhfac = Hexafluoroacetylacetone)
Shutaro Osa, Yukinari Sunatsuki, Yoko Yamamoto, Masaaki Nakamura, Tomoshige Shimamoto, Naohide Matsumoto, and Nazzareno Re
pp 5507 - 5512; DOI:
10.1021/ic0344012
PDF
Intermetallic Interactions in Face-to-Face Homo- and Heterodinuclear Bismacrocyclic Complexes of Copper(II) and Nickel(II)
Agnieszka Wickowska, Renata Bilewicz, Sawomir Domagaa, Krzysztof Woniak, Bohdan Korybut-Daszkiewicz, Alina Tomkiewicz, and Jerzy Mroziski
pp 5513 - 5522; DOI:
10.1021/ic034127b
PDF
Isolation and Structural Characterization of Anionic and Neutral Compounds Resulting from the Oxidative Addition of HI or CH3I to [IrI2(CO)2]-
Samuel Gautron, Roberto Giordano, Carole Le Berre, Joël Jaud, Jean-Claude Daran, Philippe Serp, and Philippe Kalck
pp 5523 - 5530; DOI:
10.1021/ic0340938
PDF
X-ray Absorption Spectroscopy of a Structural Analogue of the Oxidized Active Sites in the Sulfite Oxidase Enzyme Family and Related Molybdenum(V) Complexes
Farideh Jalilehvand, Booyong S. Lim, R. H. Holm, Britt Hedman, and Keith O. Hodgson
pp 5531 - 5536; DOI:
10.1021/ic030039f
PDF
Dimerization of A--[SiNb3W9O40]7- by pH-Controlled Formation of Individual Nb--O-Nb Linkages
Gyu-Shik Kim, Huadong Zeng, Wade A. Neiwert, Jennifer J. Cowan, Donald VanDerveer, Craig L. Hill, and Ira A. Weinstock
pp 5537 - 5544; DOI:
10.1021/ic0341845
PDF
Products of the Electrochemical Oxidation of cis-L2Ru(II)(NCS)2 in Dimethylformamide and Acetonitrile Determined by LC-UV/Vis-MS
Gregers Hansen, Bo Gervang, and Torben Lund
pp 5545 - 5550; DOI:
10.1021/ic0207294
PDF
Electrochemical and Spectroscopic Characterization of the Novel Charge-Transfer Ground State in Diimine Complexes of Ytterbocene
Ryan E. Da Re, Christopher J. Kuehl, Mac G. Brown, Reginaldo C. Rocha, Eric D. Bauer, Kevin D. John, David E. Morris, Andrew P. Shreve, and John L. Sarrao
pp 5551 - 5559; DOI:
10.1021/ic030069i
PDF
Difference in Spin Crossover Pathways among Saddle-Shaped Six-Coordinated Iron(III) Porphyrin Complexes
Takahisa Ikeue, Yoshiki Ohgo, Owendi Ongayi, M. Graça H. Vicente, and Mikio Nakamura
pp 5560 - 5571; DOI:
10.1021/ic0300969
PDF
Ca6[Cr2N6]H, the First Quaternary Nitride-Hydride
Mark S. Bailey, Mark N. Obrovac, Emilie Baillet, Thomas K. Reynolds, David B. Zax, and Francis J. DiSalvo
pp 5572 - 5578; DOI:
10.1021/ic0343206
PDF
Nickel(II) Complexes of 21-C-Alkylated Inverted Porphyrins: Synthesis, Protonation, and Redox Properties
Izabela Schmidt and Piotr J. Chmielewski
pp 5579 - 5593; DOI:
10.1021/ic034096k
PDF
Binuclear Copper(II) Complexes of Xylyl-Bridged Bis(1,4,7-triazacyclononane) Ligands
Fiona H. Fry, Leone Spiccia, Paul Jensen, Boujemaa Moubaraki, Keith S. Murray, and Edward R. T. Tiekink
pp 5594 - 5603; DOI:
10.1021/ic0342595
PDF
Pendant Macrocyclic Metallic Building Blocks for the Design of Cyano-Bridged Heterometallic Complexes with 1D Chain and 2D Layer Structures
Hui-Zhong Kou, Bei Chuan Zhou, Song Gao, Dai-Zheng Liao, and Ru-Ji Wang
pp 5604 - 5611; DOI:
10.1021/ic034028y
PDF
S = 3/2 S = 1/2 Spin Crossover Behavior in Five-Coordinate Halido- and Pseudohalido-bis(o-iminobenzosemiquinonato)iron(III) Complexes
Hyungphil Chun, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt
pp 5612 - 5620; DOI:
10.1021/ic0301526
PDF
New Layered Double Hydroxides Containing Intercalated Manganese Oxide Species: Synthesis and Characterization
Josanlet C. Villegas, Oscar H. Giraldo, Kate Laubernds, and Steven L. Suib
pp 5621 - 5631; DOI:
10.1021/ic030054k
PDF
Structural and Spectroscopic Trends in Actinyl Iodates of Uranium, Neptunium, and Plutonium
Amanda C. Bean, Brian L. Scott, Thomas E. Albrecht-Schmitt, and Wolfgang Runde
pp 5632 - 5636; DOI:
10.1021/ic0341688
PDF
Macrocyclic Copper(II) and Zinc(II) Complexes Incorporating Phosphate Esters
Fiona H. Fry, Paul Jensen, Christopher M. Kepert, and Leone Spiccia
pp 5637 - 5644; DOI:
10.1021/ic026091d
PDF
One- and Two-Step Spin-Crossover Behavior of [FeII(isoxazole)6]2+ and the Structure and Magnetic Properties of Triangular [FeIII3O(OAc)6(isoxazole)3][ClO4]
Wendy Hibbs, Petra J. van Koningsbruggen, Atta M. Arif, William W. Shum, and Joel S. Miller
pp 5645 - 5653; DOI:
10.1021/ic034226p
PDF
Crucial Role of the Counteranion on the Templation of Metallomacrocycles and a 3D Network: Synthesis, Characterization, and Structural Analysis
Laurence Raehm, Lamia Mimassi, Carine Guyard-Duhayon, Hani Amouri, and Marie Noelle Rager
pp 5654 - 5659; DOI:
10.1021/ic0340884
PDF
Covalent Linkage of the Type-2 and Type-3 Structural Mimics to Model the Active Site Structure of Multicopper Oxidases: Synthesis and Magneto- Structural Properties of Two Angular Trinuclear Copper(II) Complexes
Arindam Mukherjee, Indranil Rudra, Sunil G. Naik, Suryanarayanasastry Ramasesha, Munirathinam Nethaji, and Akhil R. Chakravarty
pp 5660 - 5668; DOI:
10.1021/ic034565i
PDF
Synthesis, Structure, and Mössbauer Study of [Fe(H2O)2(C9O6H4)]·H2O: A Two-Dimensional Iron(II) Trimellitate (MIL-67)
Myriam Riou-Cavellec, Cédric Lesaint, Marc Noguès, Jean-Marc Grenèche, and Gérard Férey
pp 5669 - 5674; DOI:
10.1021/ic020715y
PDF
Synthesis and Structure of Coordination Polymers of Ag(I) with Isomeric (Aminomethyl)pyridines. Formation of A Novel Circular Helicate and 2-D Networks via Ag···Ag Contacts and Coordination Shell Expansion under Anion Control
S. Sailaja and M. V. Rajasekharan
pp 5675 - 5684; DOI:
10.1021/ic0342292
PDF
Formation of Dinuclear, Macrocyclic, and Chain Structures from HgI2 and a Semirigid Benzimidazole-Based Bridging Ligand: An Example of Ring-Opening Supramolecular Isomerism
Cheng-Yong Su, Andrea M. Goforth, Mark D. Smith, and Hans-Conrad zur Loye
pp 5685 - 5692; DOI:
10.1021/ic034388l
PDF
Do Secondary and Tertiary Ammonium Cations Act as Structure-Directing Agents in the Formation of Layered Uranyl Selenites?
Philip M. Almond and Thomas E. Albrecht-Schmitt
pp 5693 - 5698; DOI:
10.1021/ic034308d
PDF
Self-Assembly of Coordination Polymers from AgX (X = SbF6-, PF6-, and CF3SO3-) and Oxadiazole-Containing Ligands
Yu-Bin Dong, Jun-Yan Cheng, Ru-Qi Huang, Mark D. Smith, and Hans-Conrad zur Loye
pp 5699 - 5706; DOI:
10.1021/ic034306t
PDF
Molecular QCA Cells. 1. Structure and Functionalization of an Unsymmetrical Dinuclear Mixed-Valence Complex for Surface Binding
Zhaohui Li, Alicia M. Beatty, and Thomas P. Fehlner
pp 5707 - 5714; DOI:
10.1021/ic026254y
PDF
Molecular QCA Cells. 2. Characterization of an Unsymmetrical Dinuclear Mixed-Valence Complex Bound to a Au Surface by an Organic Linker
Zhaohui Li and Thomas P. Fehlner
pp 5715 - 5721; DOI:
10.1021/ic026255q
PDF
Five- to Six-Coordination in (Nitrosyl)iron(II) Porphyrinates: Effects of Binding the Sixth Ligand
Graeme R. A. Wyllie, Charles E. Schulz, and W. Robert Scheidt
pp 5722 - 5734; DOI:
10.1021/ic034473t
PDF
Kinetics and Mechanism of Oxygen Atom Transfer from Methyl Phenyl Sulfoxide to Triarylphosphines Catalyzed by an Oxorhenium(V) Dimer
Nobuyoshi Koshino and James H. Espenson
pp 5735 - 5742; DOI:
10.1021/ic034322q
PDF
UV Photostability of Metal Phthalocyanines in Organic Solvents
Rudolf Sota and Gabriela Dyrda
pp 5743 - 5750; DOI:
10.1021/ic0260217
PDF
Modulation of the pKa of Metal-Bound Water via Oxidation of Thiolato Sulfur in Model Complexes of Co(III) Containing Nitrile Hydratase: Insight into Possible Effect of Cysteine Oxidation in Co-Nitrile Hydratase
Laurie A. Tyler, Juan C. Noveron, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 5751 - 5761; DOI:
10.1021/ic030088s
PDF
Carrier-Facilitated Bulk Liquid Membrane Transport of Iron(III)-Siderophore Complexes Utilizing First Coordination Sphere Recognition
Joseph I. Wirgau and Alvin L. Crumbliss
pp 5762 - 5770; DOI:
10.1021/ic034157e
PDF
Spectroscopic and Structural Characterization of the [Fe(imidazole)6]2+ Cation
Graham Carver, Philip L. W. Tregenna-Piggott, Anne-Laure Barra, Antonia Neels, and John A. Stride
pp 5771 - 5777; DOI:
10.1021/ic034110t
PDF
Synthesis and Characterization of Novel Oxotechnetium (99Tc and 99mTc) and Oxorhenium Complexes from the 2,2'-Bipyridine (NN)/Thiol (S) Mixed-Ligand System
Maria Papachristou, Ioannis C. Pirmettis, Charalambos Tsoukalas, Dionyssia Papagiannopoulou, Catherine Raptopoulou, Aris Terzis, Chariklia I. Stassinopoulou, Efstratios Chiotellis, Maria Pelecanou, and Minas Papadopoulos
pp 5778 - 5784; DOI:
10.1021/ic034368j
PDF

Issue 19


An Unprecedented 8-Fold Interpenetrating Diamondoid-like Coordination Polymer Containing a Cu+4(RCO2)4 Cluster as Connecting Node
Xi-Sen Wang, Hong Zhao, Zhi-Rong Qu, Qiong Ye, Jing Zhang, Ren-Gen Xiong, Xiao-Zeng You, and Hoong-Kun Fun
pp 5786 - 5788; DOI:
10.1021/ic0344620
PDF
[Ge9=Ge9=Ge9=Ge9]8-: A Linear Tetramer of Nine-Atom Germanium Clusters, a Nanorod
Angel Ugrinov and Slavi C. Sevov
pp 5789 - 5791; DOI:
10.1021/ic034677+
PDF
Room-Temperature Photochromism in cis- and trans-[Ru(bpy)2(dmso)2]2+
Jeffrey J. Rack and Nicholas V. Mockus
pp 5792 - 5794; DOI:
10.1021/ic0345323
PDF
Toward the Design of Novel Polynuclear Platinum Antitumor Complexes: A Polydentate Ligand System Based on Dipyridylamine and 1,3,5-Trimethylenebenzene
Chao Tu, Jun Lin, Ying Shao, and Zijian Guo
pp 5795 - 5797; DOI:
10.1021/ic034604q
PDF
Metathetical Conversion of Nd2O3 Nanoparticles into NdS2 Polysulfide Nanoparticles at Low Temperatures Using Boron Sulfides
Li-Ming Wu, Renu Sharma, and Dong-Kyun Seo
pp 5798 - 5800; DOI:
10.1021/ic034575j
PDF
Triangular, Ferromagnetically-Coupled CuII3-Pyrazolato Complexes as Possible Models of Particulate Methane Monooxygenase (pMMO)
Roman Boa, L'ubomír Dlhá, Gellert Mezei, Tamara Ortiz-Pérez, Raphael G. Raptis, and Joshua Telser
pp 5801 - 5803; DOI:
10.1021/ic0344416
PDF
The First Azide(1,1)-Bridged Binuclear Cobalt(II)-Imino Nitroxide Complex with Ferromagnetic Behavior
Li-Ya Wang, Bin Zhao, Chen-Xi Zhang, Dai-Zheng Liao, Zong-Hui Jiang, and Shi-Ping Yan
pp 5804 - 5806; DOI:
10.1021/ic034710s
PDF
Cu(II)Gly2HisGly Oxidation by H2O2/Ascorbic Acid to the Cu(III) Complex and Its Subsequent Decay to Alkene Peptides
Samantha K. Burke, Yinglin Xu, and Dale W. Margerum
pp 5807 - 5817; DOI:
10.1021/ic0345774
PDF
Kinetics and Mechanisms of the Reactions of Hypochlorous Acid, Chlorine, and Chlorine Monoxide with Bromite Ion
Jeffrey S. Nicoson, Thomas F. Perrone, Kara E. Huff Hartz, Lu Wang, and Dale W. Margerum
pp 5818 - 5824; DOI:
10.1021/ic0301223
PDF
Hydrolysis of 4-Nitrophenyl Acetate by a (N2S(thiolate))zinc Hydroxide Complex: A Model of the Catalytically Active Intermediate for the Zinc Form of Peptide Deformylase
Robert C. diTargiani, SeChin Chang, Michael H. Salter, Jr., Robert D. Hancock, and David P. Goldberg
pp 5825 - 5836; DOI:
10.1021/ic034337o
PDF
Structural Motifs in (t-butoxy)Zirconium Phosphinates, Arsinates, and Phosphates
K. C. Kumara Swamy, Michael Veith, Volker Huch, and Sanjay Mathur
pp 5837 - 5843; DOI:
10.1021/ic034458o
PDF
Interactions between Metal Ions and Carbohydrates. Coordination Behavior of Neutral Erythritol to Ca(II) and Lanthanide Ions
Limin Yang, Yunlan Su, Yizhuang Xu, Zheming Wang, Zonghui Guo, Shifu Weng, Chunhua Yan, Shiwei Zhang, and Jinguang Wu
pp 5844 - 5856; DOI:
10.1021/ic0300464
PDF
Cation-Directed Synthesis of Tungstosilicates. 1. Syntheses and Structures of K10A--[SiW9O34]·24H2O, of the Sandwich-Type Complex K10.75[Co(H2O)6]0.5[Co(H2O)4Cl]0.25A--[K2{Co(H2O)2}3(SiW9O34)2]·32H2O and of Cs15[K(SiW11O39)2]·39H2O
Nathalie Laronze, Jérôme Marrot, and Gilbert Hervé
pp 5857 - 5862; DOI:
10.1021/ic0342752
PDF
Ruthenium Complexes with Chiral Tetradentate Imino-Sulfoxide Ligands
Chui-Ying Lai, Wing-Leung Mak, Eddie Y. Y. Chan, Yiu-Keung Sau, Qian-Feng Zhang, Samuel M. F. Lo, Ian D. Williams, and Wa-Hung Leung
pp 5863 - 5870; DOI:
10.1021/ic030075e
PDF
Synthesis and Spectroscopic and Structural Characterization of Two Novel Photoactivatable Ca2+ Compounds
Alessia Bacchi, Mauro Carcelli, Corrado Pelizzi, Giancarlo Pelizzi, Paolo Pelagatti, Dominga Rogolino, Matteo Tegoni, and Cristiano Viappiani
pp 5871 - 5879; DOI:
10.1021/ic034059t
PDF
Kinetics of Metal Ion Exchange between Citric Acid and Serum Transferrin
Wesley R. Harris, Zhepeng Wang, Claire Brook, Binsheng Yang, and Ashraful Islam
pp 5880 - 5889; DOI:
10.1021/ic034009o
PDF
Equilibria between Metallosupramolecular Squares and Triangles with the New Rigid Linker 1,4-Bis(4-pyridyl)tetrafluorobenzene. Experimental and Theoretical Study of the Structural Dependence of NMR Data
Montserrat Ferrer, Mounia Mounir, Oriol Rossell, Eliseo Ruiz, and Miguel Angel Maestro
pp 5890 - 5899; DOI:
10.1021/ic034489j
PDF
Oxidation Chemistry of Uranium(III) Complexes of Tpa: Synthesis and Structural Studies of Oxo, Hydroxo, and Alkoxo Complexes of Uranium(IV)
Lydia Karmazin, Marinella Mazzanti, and Jacques Pécaut
pp 5900 - 5908; DOI:
10.1021/ic0343004
PDF
Redox Interplay of Oxo-Thio-Tungsten Centers with Sulfur-Donor Co-Ligands
Simon Thomas, Aston A. Eagle, Stephen A. Sproules, Jason P. Hill, Jonathan M. White, Edward R. T. Tiekink, Graham N. George, and Charles G. Young
pp 5909 - 5916; DOI:
10.1021/ic030095g
PDF
Mononuclear Cyano- and Hydroxo-Complexes of Iron(III)
W. Nimal Perera and Glenn Hefter
pp 5917 - 5923; DOI:
10.1021/ic034087b
PDF
Reactions of the Dirhenium(II) Complex Re2Cl4(-dppm)2 with Pyridinecarboxylic Acids. Examples of Bidentate O,O versus N,O Coordination and Tridentate O,N,O Coordination and Structural Isomers That Contain the Pyridine-2,6-dicarboxylate Ligand
Swarup Chattopadhyay, Phillip E. Fanwick, and Richard A. Walton
pp 5924 - 5931; DOI:
10.1021/ic030153y
PDF
Investigation of the Spin Exchange Interactions and Magnetic Structures of the CrVO4-Type Transition Metal Phosphates, Sulfates, and Vanadates by Spin Dimer Analysis
H.-J. Koo, M.-H. Whangbo, and K.-S. Lee
pp 5932 - 5937; DOI:
10.1021/ic030115e
PDF
Design of High-Dimensional Copper(II) Malonate Complexes with Exo-Polydentate N-Donor Ligands
Fernando S. Delgado, Joaquín Sanchiz, Catalina Ruiz-Pérez, Francesc Lloret, and Miguel Julve
pp 5938 - 5948; DOI:
10.1021/ic034422w
PDF
Controlled Structural Variations in Templated Uranium Sulfates
Alexander J. Norquist, Michael B. Doran, Paul M. Thomas, and Dermot O'Hare
pp 5949 - 5953; DOI:
10.1021/ic034343k
PDF
Synthesis and Characterization of Zirconogermanates
Jacques Plévert, Rebeca Sanchez-Smith, Travis M. Gentz, Hailian Li, Thomas L. Groy, Omar M. Yaghi, and Michael O'Keeffe
pp 5954 - 5959; DOI:
10.1021/ic034298g
PDF
Synthesis and Characterization of a Novel Organically Templated Open Framework Zirconogermanate with Three- and Seven-Membered Rings
Zhicheng Liu, Linhong Weng, Zhenxia Chen, and Dongyuan Zhao
pp 5960 - 5965; DOI:
10.1021/ic0343612
PDF
Syntheses, Structural Analyses, and Magneto-Structural Correlations of Three Polymeric Fe(II) Complexes with Azide Ligand
Sanjit Konar, Ennio Zangrando, Michael G. B. Drew, Talal Mallah, Joan Ribas, and Nirmalendu Ray Chaudhuri
pp 5966 - 5973; DOI:
10.1021/ic034423o
PDF
Density Functional Study of the Electric Hyperfine Interactions and the Redox-Structural Correlations in the Cofactor of Nitrogenase. Analysis of General Trends in 57Fe Isomer Shifts
Vladislav Vrajmasu, Eckard Münck, and Emile L. Bominaar
pp 5974 - 5988; DOI:
10.1021/ic0301371
PDF
A Phosphorus Supported Multisite Coordinating Tris Hydrazone P(S)[N(Me)N=CH-C6H4-o-OH]3 as an Efficient Ligand for the Assembly of Trinuclear Metal Complexes: Synthesis, Structure, and Magnetism
Vadapalli Chandrasekhar, Ramachandran Azhakar, Gurusamy Thanagavelu Senthil Andavan, Venkatasubbaiah Krishnan, Stefano Zacchini, Jamie F. Bickley, Alexander Steiner, Raymond J. Butcher, and Paul Kögerler
pp 5989 - 5998; DOI:
10.1021/ic034434h
PDF
Donor Atom Dependent Geometric Isomers in Mononuclear Oxo-Molybdenum(V) Complexes: Implications for Coordinated Endogenous Ligation in Molybdoenzymes
Carl J. Carrano, Balwant S. Chohan, Brian S. Hammes, Brian W. Kail, Victor N. Nemykin, and Partha Basu
pp 5999 - 6007; DOI:
10.1021/ic0262785
PDF
A Luminescent Supermolecule with Gold(I) Quinoline-8-thiolate: Crystal Structure, Spectroscopic and Photophysical Properties
Biing-Chiau Tzeng, Hsien-Te Yeh, Yung-Chi Huang, Hsiu-Yi Chao, Gene-Hsiang Lee, and Shie-Ming Peng
pp 6008 - 6014; DOI:
10.1021/ic034041i
PDF
Optical Charge-Transfer in Iron(III)hexacyanoferrate(II): Electro-intercalated Cations Induce Lattice-Energy-Dependent Ground-State Energies
David R. Rosseinsky, Hanyong Lim, Hongjin Jiang, and Jian Wei Chai
pp 6015 - 6023; DOI:
10.1021/ic020575s
PDF
Synthesis, X-ray Diffraction Structures, Spectroscopic Properties, and in vitro Antitumor Activity of Isomeric (1H-1,2,4-Triazole)Ru(III) Complexes
Vladimir B. Arion, Erwin Reisner, Madeleine Fremuth, Michael A. Jakupec, Bernhard K. Keppler, Vadim Yu. Kukushkin, and Armando J. L. Pombeiro
pp 6024 - 6031; DOI:
10.1021/ic034605i
PDF
Slow Electron Transfer Rates for Fluorinated Cobalt Porphyrins: Electronic and Conformational Factors Modulating Metalloporphyrin ET
Haoran Sun, Valeriy V. Smirnov, and Stephen G. DiMagno
pp 6032 - 6040; DOI:
10.1021/ic034705o
PDF
Fluorinated Aminoalkoxide and Ketoiminate Indium Complexes as MOCVD Precursors for In2O3 Thin Film Deposition
Tsung-Yi Chou, Yun Chi, Shu-Fen Huang, Chao-Shiuan Liu, Arthur J. Carty, Ludmila Scoles, and Konstantin A. Udachin
pp 6041 - 6049; DOI:
10.1021/ic034588x
PDF
Synthesis, Crystal Structure, and Magnetic Properties of -Hydroxo-bis[pentakis(acetonitrile)chromium(III)] Tetrafluoroborate: An Acetonitrile Analogue to "Acid Rhodo"
Niels H. Andersen, Anders Dssing, and Anne Mlgaard
pp 6050 - 6055; DOI:
10.1021/ic034428l
PDF
Bistable Copper Complexes of Bis-thia-bis-quinoline Ligands
Valeria Amendola, Carlo Mangano,, Piersandro Pallavicini, and Michele Zema
pp 6056 - 6062; DOI:
10.1021/ic025690h
PDF
New Chemistry of the Triply Bonded Divanadium (V24+) Unit and Reduction to an Unprecedented V23+ Core
F. Albert Cotton, Elizabeth A. Hillard, Carlos A. Murillo, and Xiaoping Wang
pp 6063 - 6070; DOI:
10.1021/ic034646e
PDF
Syntheses, Structures, and Properties of Imidazolate-Bridged Cu(II)-Cu(II) and Cu(II)-Zn(II) Dinuclear Complexes of a Single Macrocyclic Ligand with Two Hydroxyethyl Pendants
Dongfeng Li, Shuan Li, Dexi Yang, Jiuhong Yu, Jin Huang, Yizhi Li, and Wenxia Tang
pp 6071 - 6080; DOI:
10.1021/ic034338g
PDF
Absorption and Resonance Raman Investigations of Ligand Rotation and Nonplanar Heme Distortion in Bis-Base Low-Spin Iron(II)-Tetrakis(o-pivalamidophenyl)porphyrin Complexes
Carole Le Moigne, Thierry Picaud, Alain Boussac, Bernard Loock, Michel Momenteau, and Alain Desbois
pp 6081 - 6088; DOI:
10.1021/ic034449f
PDF
Synthesis of Group 1 Metal 2,6-Diphenylphenoxide Complexes [M(OC6H3Ph2-2,6)] (M = Li, Na, K, Rb, Cs) and Structures of the Solvent-Free Complexes [Rb(OC6H3Ph2-2,6)]x and [Cs(OC6H3Ph2-2,6)]x: One-Dimensional Extended Arrays of Metal Aryloxides
Charles S. Weinert, Phillip E. Fanwick, and Ian P. Rothwell
pp 6089 - 6094; DOI:
10.1021/ic0346580
PDF
Laser Photolysis Studies of the Photochemical Reactions of Chromium(III) Octaethylporphyrin and Tetramesitylporphyrin Complexes in Toluene Solution
Masahiko Inamo, Kosuke Eba, Kayoko Nakano, Norio Itoh, and Mikio Hoshino
pp 6095 - 6105; DOI:
10.1021/ic0342696
PDF
Ferro- and Ferrimagnetic Chains of hin-Bridged Copper(II) and Manganese(II) and hnn-Bridged Manganese(II) Complexes (hin = 4,4,5,5-Tetramethylimidazolin-1-oxyl; hnn = 4,4,5,5-Tetramethylimidazolin-1-oxyl 3-Oxide)
Tomoaki Ise, Takayuki Ishida, Daisuke Hashizume, Fujiko Iwasaki, and Takashi Nogami
pp 6106 - 6113; DOI:
10.1021/ic034392x
PDF
Structural, Electrical, and Magnetic Properties of a Series of Molecular Conductors Based on BDT-TTP and Lanthanoid Nitrate Complex Anions (BDT-TTP = 2,5-Bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene)
Hengbo Cui, Takeo Otsuka, Akiko Kobayashi, Naoya Takeda, Masayasu Ishikawa, Yohji Misaki, and Hayao Kobayashi
pp 6114 - 6122; DOI:
10.1021/ic034459g
PDF
Coexistence of Long-Range Ferromagnetic Ordering and Glassy Behavior in One-Dimensional Bimetallic Cyano-Bridged Polymers
Dongfeng Li, Limin Zheng, Yuanzhu Zhang, Jin Huang, Song Gao, and Wenxia Tang
pp 6123 - 6129; DOI:
10.1021/ic034539k
PDF
Synthesis and Structural Characterization of Novel Re(I) Tricarbonyl Complexes Anchored on a Phosphinoarylbenzylamine and a Phosphinoaryloxazoline Generated in Situ
Torsten Kniess, João D. G. Correia, Ângela Domingos, Elisa Palma, and Isabel Santos
pp 6130 - 6135; DOI:
10.1021/ic034372v
PDF
DFT Studies of Uranyl Acetate, Carbonate, and Malonate, Complexes in Solution
Jordi Vázquez, Carles Bo, Josep Maria Poblet, Joan de Pablo, and Jordi Bruno
pp 6136 - 6141; DOI:
10.1021/ic0342393
PDF
Quaternary Salts Containing the Pentafluorosulfanyl (SF5) Group
Rajendra P. Singh, Rolf W. Winter, Gary L. Gard, Ye Gao, and Jean'ne M. Shreeve
pp 6142 - 6146; DOI:
10.1021/ic034669t
PDF
Synthesis and Characterization of Two Polymorphic Crystalline Phases and an Amorphous Powder of Nickel(II) Bisimidazolate
Norberto Masciocchi, Fulvio Castelli, Paul M. Forster, Maya M. Tafoya, and Anthony K. Cheetham
pp 6147 - 6152; DOI:
10.1021/ic034619o
PDF

Issue 20


Novel Transition Metal Oxalatophosphates with a Two-Dimensional Honeycomb Structure: (H3TREN)[M2(HPO4)(C2O4)2.5]·3H2O (M = MnII and FeII, TREN = Tris(2-aminoethyl)amine)
Yau-Chen Jiang, Sue-Lein Wang, Shang-Fan Lee, and Kwang-Hwa Lii
pp 6154 - 6156; DOI:
10.1021/ic030019d
PDF
{Zn6[MeN(CH2CO2)(CH2PO3)]6(Zn)}4- Anion: The First Example of the Oxo-Bridged Zn6 Octahedron with a Centered Zn(II) Cation
Chong Lei, Jiang-Gao Mao, Yan-Qiong Sun, Hui-Yi Zeng, and Abraham Clearfield
pp 6157 - 6159; DOI:
10.1021/ic034137c
PDF
Synthesis and Structural Characterization of Cationic Rhenium(V) and Technetium(V) Dioxo Complexes Containing Four N-Heterocyclic Carbene Ligands
Henrik Braband, Theresa I. Zahn, and Ulrich Abram
pp 6160 - 6162; DOI:
10.1021/ic0348345
PDF
Kinetic Resolution of rac-Phenylalanine by Stereoselective Complexation to a Chiral Cobalt Complex through - Stacking Interaction
Koichiro Jitsukawa, Akira Katoh, Kentaro Funato, Nayumi Ohata, Yasuhiro Funahashi, Tomohiro Ozawa, and Hideki Masuda
pp 6163 - 6165; DOI:
10.1021/ic030135g
PDF
Structural Features of a New Dinuclear Platinum(II) Complex with Significant Antiproliferative Activity
Luigi Messori, Jiajiu Shaw, Mercedes Camalli, Pasquale Mura, and Giordana Marcon
pp 6166 - 6168; DOI:
10.1021/ic034025l
PDF
An Inorganic Route for Controlled Synthesis of W18O49 Nanorods and Nanofibers in Solution
Xiong Wen Lou and Hua Chun Zeng
pp 6169 - 6171; DOI:
10.1021/ic034771q
PDF
What a Difference Ancillary Thienyl Makes: Unexpected Additional Stabilization of the Diruthenium(III,II) but Not the Diosmium(III,II) Mixed-Valent State in Tetrazine Ligand-Bridged Complexes
Biprajit Sarkar, Wolfgang Kaim, Axel Klein, Brigitte Schwederski, Jan Fiedler, Carole Duboc-Toia, and Goutam K. Lahiri
pp 6172 - 6174; DOI:
10.1021/ic034105p
PDF
Syntheses and Reactivity of the Diselenido Molybdenum-Manganese Complex CpMoMn(CO)5(-Se2)
Richard D. Adams and O-Sung Kwon
pp 6175 - 6182; DOI:
10.1021/ic030077z
PDF
Core-Modified Porphyrin Incorporating a Phenolate Donor. Characterization of Pd(II), Ni(II), Zn(II), Cd(II), and Fe(III) Complexes
Marcin Stpie and Lechosaw Latos-Grayski
pp 6183 - 6193; DOI:
10.1021/ic0345121
PDF
Synthesis and EPR Characterization of New Models for the One-Electron Reduced Molybdenum Site of Sulfite Oxidase
Katrina Peariso, Balwant S. Chohan, Carl J. Carrano, and Martin L. Kirk
pp 6194 - 6203; DOI:
10.1021/ic034478q
PDF
Symmetry and Geometry Considerations of Atom Transfer: Deoxygenation of (silox)3WNO and R3PO (R = Me, Ph, tBu) by (silox)3M (M = V, NbL (L = PMe3, 4-Picoline), Ta; silox = tBu3SiO)
Adam S. Veige, LeGrande M. Slaughter, Emil B. Lobkovsky, Peter T. Wolczanski, Nikita Matsunaga, Stephen A. Decker, and Thomas R. Cundari
pp 6204 - 6224; DOI:
10.1021/ic0300114
PDF
Synthesis and Structural Investigation of N,N',N' '-Trialkylguanidinato-Supported Zirconium(IV) Complexes
Patrick Bazinet, Dayna Wood, Glenn P. A. Yap, and Darrin S. Richeson
pp 6225 - 6229; DOI:
10.1021/ic034445a
PDF
Cyanide Adducts on the Diruthenium Core of [Ru2(L)4]+ (L = ap, CH3ap, Fap, or F3ap). Electronic Properties and Binding Modes of the Bridging Ligand
John L. Bear, Wei-Zhong Chen, Boacheng Han, Shurong Huang, Li-Lun Wang, Antoine Thuriere, Eric Van Caemelbecke, Karl M. Kadish, and Tong Ren
pp 6230 - 6240; DOI:
10.1021/ic030195m
PDF
Sterically Encumbered Diphosphaalkenes and a Bis(diphosphene) as Potential Multiredox-Active Molecular Switches: EPR and DFT Investigations
Cosmina Dutan, Shashin Shah, Rhett C. Smith, Sylvie Choua, Théo Berclaz, Michel Geoffroy, and John D. Protasiewicz
pp 6241 - 6251; DOI:
10.1021/ic030079j
PDF
Binding Sites of Nitrogenase: Kinetic and Theoretical Studies of Cyanide Binding to Extracted FeMo-Cofactor Derivatives
Zhen Cui, Adrian J. Dunford, Marcus C. Durrant, Richard A. Henderson, and Barry E. Smith
pp 6252 - 6264; DOI:
10.1021/ic030108q
PDF
Synthesis of a Single Four-Ring (S4R) Molecular Zinc Phosphate and Its Assembly to an Extended Polymeric Structure: A Single-Crystal and in-Situ MAS NMR Investigation
Srinivasan Natarajan, Leo van Wüllen, Wilhelm Klein, and Martin Jansen
pp 6265 - 6273; DOI:
10.1021/ic0301831
PDF
Catalytic Oxidation of 3,5-Di-tert-butylcatechol by a Series of Mononuclear Manganese Complexes: Synthesis, Structure, and Kinetic Investigation
Michael U. Triller, Daniel Pursche, Wen-Yuan Hsieh, Vincent L. Pecoraro, Annette Rompel, and Bernt Krebs
pp 6274 - 6283; DOI:
10.1021/ic0347788
PDF
Adduct Formation between Alkali Metal Ions and Anionic LVVO2- (L2- = Tridentate ONS Ligands) Species: Syntheses, Structural Investigation, and Photochemical Studies
Satyabrata Samanta, Suman Mukhopadhyay, Debdas Mandal, Ray J. Butcher, and Muktimoy Chaudhury
pp 6284 - 6293; DOI:
10.1021/ic030080i
PDF
Synthesis and Characterization of HN(SPiPr2)(SePPh2) and [Te{N(SPiPr2)(SePPh2)}2]
Perumal Sekar and James A. Ibers
pp 6294 - 6299; DOI:
10.1021/ic030194u
PDF
Constrained Synthesis of Cobalt Oxide Nanomaterials in the 12-Subunit Protein Cage from Listeria innocua
Mark Allen, Debbie Willits, Mark Young, and Trevor Douglas
pp 6300 - 6305; DOI:
10.1021/ic0343657
PDF
Photochemical Behavior of Azobenzene-Conjugated CoII, CoIII, and FeII Bis(terpyridine) Complexes
Tomona Yutaka, Ichiro Mori, Masato Kurihara, Naoto Tamai, and Hiroshi Nishihara
pp 6306 - 6313; DOI:
10.1021/ic0260466
PDF
The (CO) Vibrational Spectra of Planar Transition Metal Carbonyl Clusters
S. F. A. Kettle, E. Boccaleri, E. Diana, R. Rossetti, P. L. Stanghellini, M. C. Iapalucci, and G. Longoni
pp 6314 - 6322; DOI:
10.1021/ic034477y
PDF
Lowest Singlet and Triplet Potential Energy Surfaces of S2N2
Robert C. Mawhinney and John D. Goddard
pp 6323 - 6337; DOI:
10.1021/ic0301270
PDF
The Dissociation of Fluoroaluminates in FLiNaK and CsF-KF Molten Mixtures: A Raman Spectroscopic and Solubility Study
F. Auguste, O. Tkatcheva, H. Mediaas, T. Østvold, and B. Gilbert
pp 6338 - 6344; DOI:
10.1021/ic026222a
PDF
Cr[(H3N-(CH2)2-PO3)(Cl)(H2O)]: X-Ray Single-Crystal Structure and Magnetism of a Polar Organic-Inorganic Hybrid Chromium(II) Organophosphonate
Elvira M. Bauer, Carlo Bellitto, Marcello Colapietro, Gustavo Portalone, and Guido Righini
pp 6345 - 6351; DOI:
10.1021/ic0343197
PDF
Structures and Conformational Dynamics of Gold(I) Halide Complexes of Resorcinarene Tetraphosphinite Ligands
Dana J. Eisler and Richard J. Puddephatt
pp 6352 - 6365; DOI:
10.1021/ic034430c
PDF
Structure-Dependent Photophysical Properties of Singlet and Triplet Metal-to-Ligand Charge Transfer States in Copper(I) Bis(diimine) Compounds
Zainul Abedin Siddique, Yuichi Yamamoto, Takeshi Ohno, and Koichi Nozaki
pp 6366 - 6378; DOI:
10.1021/ic034412v
PDF
Intramolecular Electrocatalysis of 8-Oxo-Guanine Oxidation: Secondary Structure Control of Electron Transfer in Osmium-Labeled Oligonucleotides
Rebecca C. Holmberg, Mark T. Tierney, Patricia A. Ropp, Eric E. Berg, Mark W. Grinstaff, and H. Holden Thorp
pp 6379 - 6387; DOI:
10.1021/ic030004f
PDF
Synthesis and Photophysical Properties of Neutral Luminescent Rhenium-Based Molecular Rectangles
T. Rajendran, Bala. Manimaran, Rong-Tang Liao, Ren-Jay Lin, P. Thanasekaran, Gene-Hsiang Lee, Shie-Ming Peng, Yen-Hsiang Liu, I-Jy Chang, S. Rajagopal, and Kuang-Lieh Lu
pp 6388 - 6394; DOI:
10.1021/ic034099x
PDF
Rhenium(I)-Induced Cyclization of Thiosemicarbazones Derived from -Keto Esters
Rosa Carballo, José S. Casas, Emilia García-Martínez, Gumersindo Pereiras-Gabián, Agustín Sánchez, José Sordo, and Ezequiel M. Vázquez-López
pp 6395 - 6403; DOI:
10.1021/ic030154q
PDF
Sonochemical Fabrication and Characterization of Stibnite Nanorods
Hui Wang, Yi-Nong Lu, Jun-Jie Zhu, and Hong-Yuan Chen
pp 6404 - 6411; DOI:
10.1021/ic0342604
PDF
REMGa3Ge and RE3Ni3Ga8Ge3 (M = Ni, Co; RE = Rare-Earth Element): New Intermetallics Synthesized in Liquid Gallium. X-ray, Electron, and Neutron Structure Determination and Magnetism
Marina A. Zhuravleva, Robert J. Pcionek, Xiaoping Wang, Arthur J. Schultz, and Mercouri G. Kanatzidis
pp 6412 - 6424; DOI:
10.1021/ic0341892
PDF
Novel Mo(V)-Dithiolene Compounds: Characterization of Nonsymmetric Dithiolene Complexes by Electrospray Ionization Mass Spectrometry
Rémi Dessapt, Corine Simonnet-Jégat, Alain Mallard, Hélène Lavanant, Jérôme Marrot, and Francis Sécheresse
pp 6425 - 6431; DOI:
10.1021/ic0342907
PDF
Temperature-Induced Solid-State Valence Tautomeric Interconversion in Two Cobalt-Schiff Base Diquinone Complexes
Olivier Cador, Françoise Chabre, Andrea Dei, Claudio Sangregorio, Joris Van Slageren, and Maria G. F. Vaz
pp 6432 - 6440; DOI:
10.1021/ic034210z
PDF
Electrochemical Behavior of Nickeladithiolene S,S'-Dialkyl Adducts: Evidence for the Formation of a Metalladithiolene Radical by Electrochemical Redox Reactions
Mitsushiro Nomura, Chikako Takayama, and Masatsugu Kajitani
pp 6441 - 6446; DOI:
10.1021/ic034402u
PDF
Modeling Features of the Non-Heme Diiron Cores in O2-Activating Enzymes through the Synthesis, Characterization, and Oxidation of 1,8-Naphthyridine-Based Complexes
Jane Kuzelka, Sumitra Mukhopadhyay, Bernhard Spingler, and Stephen J. Lippard
pp 6447 - 6457; DOI:
10.1021/ic0345976
PDF
Synthesis of a Pyridinium Bis[citrato(2-)]oxochromate(V) Complex and Its Ligand-Exchange Reactions
Carissa M. Cawich, Amritha Ibrahim, Karen L. Link, Allan Bumgartner, Mata D. Patro, Surendra N. Mahapatro, Peter A. Lay, Aviva Levina, Sandra S. Eaton, and Gareth R. Eaton
pp 6458 - 6468; DOI:
10.1021/ic034146l
PDF
Separating Innocence and Non-Innocence of Ligands and Metals in Complexes [(L)Ru(acac)2]n (n = -1, 0, +1; L = o-Iminoquinone or o-Iminothioquinone)
Srikanta Patra, Biprajit Sarkar, Shaikh M. Mobin, Wolfgang Kaim, and Goutam Kumar Lahiri
pp 6469 - 6473; DOI:
10.1021/ic034469h
PDF
Structural Insights into Aluminum Chlorofluoride (ACF)
Thoralf Krahl, Reinhard Stösser, Erhard Kemnitz, Gudrun Scholz, Michael Feist, Gilles Silly, and Jean-Yves Buzaré
pp 6474 - 6483; DOI:
10.1021/ic034106h
PDF
Coordination Polyhedron and Chemical Vapor Deposition of Cu(hfacac)2(t-BuNH2)
Kyoungja Woo, Hojeong Paek, and Wan In Lee
pp 6484 - 6488; DOI:
10.1021/ic034360+
PDF
EPR Spectroscopy of [Fe2O2(5-Et3-TPA)2]3+: Electronic Origin of the Unique Spin-Hamiltonian Parameters of the Fe2III,IVO2 Diamond Core
Andrew J. Skulan, Melissa A. Hanson, Hua-fen Hsu, Yanhong Dong, Lawrence Que, Jr., and Edward I. Solomon
pp 6489 - 6496; DOI:
10.1021/ic034170z
PDF
Synthesis and Characterization of Low-Spin and Cation Radical Complexes of Ruthenium(III) of a Tridentate Pyridine Bis-Amide Ligand
Akhilesh Kumar Singh, V. Balamurugan, and Rabindranath Mukherjee
pp 6497 - 6502; DOI:
10.1021/ic034356y
PDF
Pressure-Induced Enhancements of Luminescence Intensities and Lifetimes Correlated with Emitting-State Distortions for Thiocyanate and Selenocyanate Complexes of Platinum(II) and Palladium(II)
John K. Grey, Ian S. Butler, and Christian Reber
pp 6503 - 6518; DOI:
10.1021/ic0342503
PDF
Synthesis and Characterization of Novel Rhenium(V) Tetradentate N2O2 Schiff Base Monomer and Dimer Complexes
Paul D. Benny, Charles L. Barnes, Pamela M. Piekarski, John D. Lydon, and Silvia S. Jurisson
pp 6519 - 6527; DOI:
10.1021/ic030240q
PDF
Cyclometalated Analogues of Platinum Terpyridine Complexes: Kinetic Study of the Strong -Donor Cis and Trans Effects of Carbon in the Presence of a -Acceptor Ligand Backbone
Andreas Hofmann, Lutz Dahlenburg, and Rudi van Eldik
pp 6528 - 6538; DOI:
10.1021/ic034400+
PDF
Highly Asymmetric Coordination in Alkenes: Gas-Phase Structures of trans-1,2-Dichloro-1,2-disilylethene and 1-Bromo-1-silylethene
Lorna J. McLachlan, Sarah L. Hinchley, David W. H. Rankin, Carole A. Morrison, Heather E. Robertson, Norbert W. Mitzel, Christoph Rüdinger, and Hubert Schmidbaur
pp 6539 - 6544; DOI:
10.1021/ic034596d
PDF
Rhenium Chemistry of Diazabutadienes and Derived Iminoacetamides Spanning the Valence Domain II-VI. Synthesis, Characterization, and Metal-Promoted Regiospecific Imine Oxidation
Samir Das, Indranil Chakraborty, and Animesh Chakravorty
pp 6545 - 6555; DOI:
10.1021/ic034586c
PDF
Structure-Based Description of a Step-by-Step Synthesis of Homo- and Heterodinuclear (4f, 4f ') Lanthanide Complexes
Jean-Pierre Costes, Françoise Dahan, and Franck Nicodème
pp 6556 - 6563; DOI:
10.1021/ic034564q
PDF
Construction of Multiporphyrin Arrays Using Ruthenium and Rhodium Coordination to Phosphines
Eugen Stulz, Sonya M. Scott, Yiu-Fai Ng, Andrew D. Bond, Simon J. Teat, Scott L. Darling, Neil Feeder, and Jeremy K. M. Sanders
pp 6564 - 6574; DOI:
10.1021/ic034699w
PDF
Regulation of Geometry around the Ruthenium Center of Bis(2-pyridinecarboxylato) Complexes by the Nitrosyl Moiety: Syntheses, Structures, and Theoretical Studies
Toshiyuki Hirano, Takao Oi, Hirotaka Nagao, and Keiji Morokuma
pp 6575 - 6583; DOI:
10.1021/ic0344261
PDF
Pyrazolato-Bridged Polynuclear Palladium and Platinum Complexes. Synthesis, Structure, and Reactivity
Keisuke Umakoshi, Yoko Yamauchi, Keiko Nakamiya, Takashi Kojima, Mikio Yamasaki, Hiroyuki Kawano, and Masayoshi Onishi:
pp 6584 - 6584; DOI:
10.1021/ic030215k
PDF
Coordination Chemistry of the Water-Soluble Ligand TPPTP and Formation of a [Mo(CO)5(m-TPPTP)] Monolayer on an Alumina Surface
Brandy A. Harper, D. Andrew Knight, Clifford George, Susan L. Brandow, Walter J. Dressick, Charles S. Dulcey, and Terence L. Schull:
pp 6584 - 6584; DOI:
10.1021/ic030231h
PDF

Issue 21


Kinetic Stabilization of Primary Hydrides of Main Group Elements. The Synthesis of an Air-Stable, Crystalline Arsine and Silane
Marcin Brynda, Gérald Bernardinelli, Cosmina Dutan, and Michel Geoffroy
pp 6586 - 6588; DOI:
10.1021/ic034367r
PDF
[CH3(CH2)11NH3]SnI3: A Hybrid Semiconductor with MoO3-type Tin(II) Iodide Layers
Zhengtao Xu and David B. Mitzi
pp 6589 - 6591; DOI:
10.1021/ic0347081
PDF
Titanium and Zirconium Amido Complexes Ligated by 2,2'-Di(3-methylindolyl)methanes: Synthesis, Characterization, and Ethylene Polymerization Activity
Mark R. Mason, Bassam N. Fneich, and Kristin Kirschbaum
pp 6592 - 6594; DOI:
10.1021/ic0347236
PDF
[Ge7O13(OH)2F3]3-·Cl-·2[Ni(dien)2]2+: The First Chainlike Germanate Templated by a Transition Metal Complex
Hong-Xia Zhang, Jie Zhang, Shou-Tian Zheng, and Guo-Yu Yang
pp 6595 - 6597; DOI:
10.1021/ic034645m
PDF
Low-Potential Cyclometalated Osmium(II) Mediators of Glucose Oxidase
Alexander D. Ryabov, Valentin S. Soukharev, Larissa Alexandrova, Ronan Le Lagadec, and Michel Pfeffer
pp 6598 - 6600; DOI:
10.1021/ic0346578
PDF
A Novel Undecametallic Iron(III) Cluster with an S = 11/2 Spin Ground State
Leigh F. Jones, Euan K. Brechin, David Collison, Madeleine Helliwell, Talal Mallah, Stergios Piligkos, Gopalan Rajaraman, and Wolfgang Wernsdorfer
pp 6601 - 6603; DOI:
10.1021/ic034654v
PDF
Formation of a Spiral-Shaped Inorganic-Organic Hybrid Chain, [CuII(2,2'-bipy)(H2O)2Al(OH)6Mo6O18]nn-: Influence of Intra- and Interchain Supramolecular Interactions
Vaddypally Shivaiah, M. Nagaraju, and Samar K. Das
pp 6604 - 6606; DOI:
10.1021/ic034581f
PDF
Octadecanuclear Cluster or 1D Polymer with [{ML}2Nb(CN)8]n Motifs as a Function of {ML} (M = Ni(II), n = 6; M = Mn(II), n = ; L = Macrocycle)
Rabindranath Pradhan, Cédric Desplanches, Philippe Guionneau, and Jean-Pascal Sutter
pp 6607 - 6609; DOI:
10.1021/ic034628x
PDF
Cupric Decamolybdodivanadophosphate. A Coordination Polymer Heterogeneous Catalyst for Rapid, High Conversion, High Selectivity Sulfoxidation Using the Ambient Environment
Nelya M. Okun, Travis M. Anderson, Kenneth I. Hardcastle, and Craig L. Hill
pp 6610 - 6612; DOI:
10.1021/ic0348953
PDF
Novel Ru-Dioxolene Complexes as Potential Electrochromic Materials and NIR Dyes
Peter F. H. Schwab, Sara Diegoli, Matteo Biancardo, and Carlo Alberto Bignozzi
pp 6613 - 6615; DOI:
10.1021/ic0346782
PDF
Excited-State Energy-Transfer Dynamics of Self-Assembled Imine-Linked Porphyrin Dyads
Igor V. Sazanovich, Arumugham Balakumar, Kannan Muthukumaran, Eve Hindin, Christine Kirmaier, James R. Diers, Jonathan S. Lindsey, David F. Bocian, and Dewey Holten
pp 6616 - 6628; DOI:
10.1021/ic034558u
PDF
Excited-State Energy-Transfer Dynamics in Self-Assembled Triads Composed of Two Porphyrins and an Intervening Bis(dipyrrinato)metal Complex
Lianhe Yu, Kannan Muthukumaran, Igor V. Sazanovich, Christine Kirmaier, Eve Hindin, James R. Diers, Paul D. Boyle, David F. Bocian, Dewey Holten, and Jonathan S. Lindsey
pp 6629 - 6647; DOI:
10.1021/ic034559m
PDF
Cu(I) Complexes of 3,3'-Polymethylene Bridged Derivatives of 2,2'-Bi-1,10-Phenanthroline
Elvira C. Riesgo, Yi-Zhen Hu, and Randolph P. Thummel
pp 6648 - 6654; DOI:
10.1021/ic0300417
PDF
Synthesis and Comprehensive Characterizations of New cis-RuL2X2 (X = Cl, CN, and NCS) Sensitizers for Nanocrystalline TiO2 Solar Cell Using Bis-Phosphonated Bipyridine Ligands (L)
Hervé Zabri, Isabelle Gillaizeau, Carlo Alberto Bignozzi, Stefano Caramori, Marie-France Charlot, Joan Cano-Boquera, and Fabrice Odobel
pp 6655 - 6666; DOI:
10.1021/ic034403m
PDF
New Metal-Rich Sulfides Ni6SnS2 and Ni9Sn2S2 with a 2D Metal Framework: Synthesis, Crystal Structure, and Bonding
A. I. Baranov, A. A. Isaeva, L. Kloo, and B. A. Popovkin
pp 6667 - 6672; DOI:
10.1021/ic034349+
PDF
Nine Hexagonal Ca5Pb3Z Phases in Stuffed Mn5Si3-Type Structures with Transition Metal Interstitial Atoms Z. Problems with Classical Valence States in Possible Zintl Phases
Arnold M. Guloy, Anja-Verena Mudring, and John D. Corbett
pp 6673 - 6681; DOI:
10.1021/ic0301728
PDF
Tris(bis(trimethylsilyl)amido)samarium: X-ray Structure and DFT Study
Erik D. Brady, David L. Clark, John C. Gordon, P. Jeffrey Hay, D. Webster Keogh, Rinaldo Poli, Brian L. Scott, and John G. Watkin
pp 6682 - 6690; DOI:
10.1021/ic0341690
PDF
Pi Bonding and Negative Hyperconjugation in Mono-, Di-, and Triaminoborane, -alane, -gallane, and -indane
Bethany L. Kormos and Christopher J. Cramer
pp 6691 - 6700; DOI:
10.1021/ic034584s
PDF
Density Functional Theory Study of Nine-Atom Germanium Clusters: Effect of Electron Count on Cluster Geometry
R. B. King and I. Silaghi-Dumitrescu
pp 6701 - 6708; DOI:
10.1021/ic030107y
PDF
Reversible Guest Exchange and Ferrimagnetism (TC = 60.5 K) in a Porous Cobalt(II)-Hydroxide Layer Structure Pillared with trans-1,4-Cyclohexanedicarboxylate
Mohamedally Kurmoo, Hitoshi Kumagai, Suzanne M. Hughes, and Cameron J. Kepert
pp 6709 - 6722; DOI:
10.1021/ic034787g
PDF
Silicon-Silica Nanowires, Nanotubes, and Biaxial Nanowires: Inside, Outside, and Side-by-Side Growth of Silicon versus Silica on Zeolite
Boon K. Teo, C. P. Li, X. H. Sun, N. B. Wong, and S. T. Lee
pp 6723 - 6728; DOI:
10.1021/ic034397u
PDF
Solid State Coordination Chemistry: One-, Two-, and Three-Dimensional Materials Constructed from Molybdophosphonate Subunits Linked through Binuclear Copper Tetra-2-pyridylpyrazine Groups
Eric Burkholder, Vladimir Golub, Charles J. O'Connor, and Jon Zubieta
pp 6729 - 6740; DOI:
10.1021/ic030169o
PDF
Orange Luminescence and Structural Properties of Three Isostructural Halocyclohexylisonitrilegold(I) Complexes
Rochelle L. White-Morris, Marilyn M. Olmstead, Alan L. Balch, O. Elbjeirami, and Mohammad A. Omary
pp 6741 - 6748; DOI:
10.1021/ic0341946
PDF
Nickel(II) Cyclidenes with Appended Ethylpyridine Receptor Centers as Molecular Tweezers for Dicarboxylic Acids
Jeremy S. Disch, Richard J. Staples, Thomas E. Concolino, Terry E. Haas, and Elena V. Rybak-Akimova
pp 6749 - 6763; DOI:
10.1021/ic0345572
PDF
DFT Study on the Reed Diethylaluminum Cation-like System: Structure and Bonding in Et2Al(CB11H6X6) (X = Cl, Br)
Krishna K. Pandey
pp 6764 - 6767; DOI:
10.1021/ic034399e
PDF
Metal Complexes with a New N4O3 Amine Pendant-Armed Macrocyclic Ligand: Synthesis, Characterization, Crystal Structures, and Fluorescence Studies
Manuel Vicente, Rufina Bastida, Carlos Lodeiro, Alejandro Macías, A. Jorge Parola, Laura Valencia, and Sharon E. Spey
pp 6768 - 6779; DOI:
10.1021/ic034245z
PDF
Synthesis of a Copper [3]Rotaxane Able To Function as an Electrochemically Driven Oscillatory Machine in Solution, and To Form SAMs on a Metal Surface
Noémie Weber, Christine Hamann, Jean-Marc Kern, and Jean-Pierre Sauvage
pp 6780 - 6792; DOI:
10.1021/ic0347034
PDF
Speciation and Coordination Chemistry of Uranyl(VI)-Citrate Complexes in Aqueous Solution
Sofie P. Pasilis and Jeanne E. Pemberton
pp 6793 - 6800; DOI:
10.1021/ic0341800
PDF
Synthesis and Characterization of a New Asymmetric Bis-Porphyrinato Lanthanide Complex Presenting Mixed Hydrophilic-Hydrophobic Properties and Its Precursor Form
Georgios K. Tsikalas and Athanassios G. Coutsolelos
pp 6801 - 6804; DOI:
10.1021/ic026299z
PDF
New Cis Folded Organocobalt Derivatives with a Salen-Type Ligand
Renata Dreos, Giorgio Nardin, Lucio Randaccio, Patrizia Siega, Giovanni Tauzher, and Vinja Vrdoljak
pp 6805 - 6811; DOI:
10.1021/ic034085r
PDF
Iron Nitrosyls of a Pentadentate Ligand Containing a Single Carboxamide Group: Syntheses, Structures, Electronic Properties, and Photolability of NO
Apurba K. Patra, John M. Rowland, Dana S. Marlin, Eckhard Bill, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 6812 - 6823; DOI:
10.1021/ic0301627
PDF
Investigation of the Reduced High-Potential Iron-Sulfur Protein from Chromatium vinosum and Relevant Model Compounds: A Unified Picture of the Electronic Structure of [Fe4S4]2+ Systems through Magnetic and Optical Studies
Latévi M. Lawson Daku, Jacques Pécaut, Alix Lenormand-Foucaut, Béatrice Vieux-Melchior, Peter Iveson, and Jeanne Jordanov
pp 6824 - 6850; DOI:
10.1021/ic034494n
PDF
Fine-Tuning the Weak-Link Approach: Effect of Ligand Electron Density on the Formation of Rhodium(I) and Iridium(I) Metallomacrocycles
Martin S. Masar III, Maxim V. Ovchinnikov, Chad A. Mirkin, Lev N. Zakharov, and Arnold L. Rheingold
pp 6851 - 6858; DOI:
10.1021/ic034393p
PDF
Hydrothermal Synthesis in the System Ni(OH)2-NiSO4: Nuclear and Magnetic Structures and Magnetic Properties of Ni3(OH)2(SO4)2(H2O)2
Serge Vilminot, Mireille Richard-Plouet, Gilles André, Dariusz Swierczynski, Françoise Bourée-Vigneron, and Mohamedally Kurmoo
pp 6859 - 6867; DOI:
10.1021/ic0345469
PDF
Metal-Centered Ferrocene Clusters from 5-Ferrocenylpyrimidine and Ferrocenylpyrazine
Ryo Horikoshi, Chisato Nambu, and Tomoyuki Mochida
pp 6868 - 6875; DOI:
10.1021/ic034684y
PDF
Chromium(II) and Chromium(III) Complexes Supported by Tris(2-pyridylmethyl)amine: Synthesis, Structures, and Reactivity
Nicholas J. Robertson, Michael J. Carney, and Jason A. Halfen
pp 6876 - 6885; DOI:
10.1021/ic034530i
PDF
New Luminescent Cyclometalated Iridium(III) Diimine Complexes as Biological Labeling Reagents
Kenneth Kam-Wing Lo, Chi-Keung Chung, Terence Kwok-Ming Lee, Lok-Hei Lui, Keith Hing-Kit Tsang, and Nianyong Zhu
pp 6886 - 6897; DOI:
10.1021/ic0346984
PDF
4,4'-Dithiodipyridine as a Bridging Ligand in Osmium and Ruthenium Complexes: The Electron Conductor Ability of the -S-S- Bridge
Welter C. Silva, Joacy B. Lima, Icaro S. Moreira, Antônio M. Neto, Flávio C. G. Gandra, Antônio G. Ferreira, Bruce R. McGarvey, and Douglas W. Franco
pp 6898 - 6906; DOI:
10.1021/ic034630o
PDF
Kinetics and Mechanism of Formation of the Platinum-Thallium Bond: The [(CN)5Pt-Tl(CN)3]3- Complex
Péter Nagy, Imre Tóth, István Fábián, Mikhail Maliarik, and Julius Glaser
pp 6907 - 6914; DOI:
10.1021/ic034676h
PDF
Synthesis and Structures of Nickel and Palladium Salicylaldiminato 1,3,5-Triaza-7-phosphaadamantane (PTA) Complexes
Donald J. Darensbourg, Cesar G. Ortiz, and Jason C. Yarbrough
pp 6915 - 6922; DOI:
10.1021/ic0341284
PDF
The Kinetics and Mechanism of the Ferrate(VI) Oxidation of Hydroxylamines
Michael D. Johnson and Brooks J. Hornstein
pp 6923 - 6928; DOI:
10.1021/ic020705x
PDF
Coordination Properties of New Bis(1,4,7-triazacyclononane) Ligands: A Highly Active Dizinc Complex in Phosphate Diester Hydrolysis
Massimiliano Arca, Andrea Bencini, Emanuela Berni, Claudia Caltagirone, Francesco A. Devillanova, Francesco Isaia, Alessandra Garau, Claudia Giorgi, Vito Lippolis, Alessandro Perra, Lorenzo Tei, and Barbara Valtancoli
pp 6929 - 6939; DOI:
10.1021/ic034050r
PDF
Valence Compounds versus Metals. Synthesis, Characterization, and Electronic Structures of Cubic Ae4Pn3 Phases in the Systems Ae = Ca, Sr, Ba, Eu; Pn = As, Sb, Bi
Bin Li, Anja-Verena Mudring, and John D. Corbett
pp 6940 - 6945; DOI:
10.1021/ic0301472
PDF
A Schiff-Base Bibracchial Lariat Ether Forming a Cryptand-like Cavity for Lanthanide Ions
Marina González-Lorenzo, Carlos Platas-Iglesias, Fernando Avecilla, Carlos F. G. C. Geraldes, Daniel Imbert, Jean-Claude G. Bünzli, Andrés de Blas, and Teresa Rodríguez-Blas
pp 6946 - 6954; DOI:
10.1021/ic034024t
PDF

Issue 22


A Novel Three-Dimensional Network Constructed from Tetramolybdate Clusters Linked via Two Types of Copper Complex Fragments: Synthesis, Characterization, and Magnetic Behavior of [{CuII(2,2'-bpy)}{CuII(IN)2}{Mo4O12(OH)2}]
Jian Lü, Enhong Shen, Mei Yuan, Yangguang Li, Enbo Wang, Changwen Hu, Lin Xu, and Jun Peng
pp 6956 - 6958; DOI:
10.1021/ic034752g
PDF
Copper(I) Pseudorotaxane Monolayers Assembled on Gold Electrodes
Eugenio Coronado, Alicia Forment-Aliaga, Pablo Gaviña, and Francisco M. Romero
pp 6959 - 6961; DOI:
10.1021/ic034797h
PDF
A Novel One-Dimensional Cyano-Bridged Ni3Fe2 Ferromagnet Constructed from Bimetallic Molecular Squares
Enrique Colacio, José M. Domínguez-Vera, Francesc Lloret, Antonio Rodríguez, and Helen Stoeckli-Evans
pp 6962 - 6964; DOI:
10.1021/ic034307l
PDF
Ferromagnetism in a Dinuclear Nickel(II) Complex Containing Triethylenetetramine and Tricyanomethanide
Roman Boa, Milan Gembick, Radovan Herchel, Wolfgang Haase, Lothar Jäger, Christoph Wagner, Helmut Ehrenberg, and Hartmut Fuess
pp 6965 - 6967; DOI:
10.1021/ic034725q
PDF
Copper Hydroperoxo Species Activated by Hydrogen-Bonding Interaction with Its Distal Oxygen
Syuhei Yamaguchi, Shigenori Nagatomo, Teizo Kitagawa, Yasuhiro Funahashi, Tomohiro Ozawa, Koichiro Jitsukawa, and Hideki Masuda
pp 6968 - 6970; DOI:
10.1021/ic035080x
PDF
New Routes to High Nuclearity Clusters: Fluoride-Based Octametallic and Tridecametallic Clusters of Manganese
Leigh F. Jones, Euan K. Brechin, David Collison, James Raftery, and Simon J. Teat
pp 6971 - 6973; DOI:
10.1021/ic034979b
PDF
[Na(THF)2Cr(N3N)]: The First Trigonal Monopyramidal Chromium(II) Complex
Alexander C. Filippou, Sven Schneider, and Gregor Schnakenburg
pp 6974 - 6976; DOI:
10.1021/ic0349961
PDF
Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand
Masayuki Watanabe, Takuya Nankawa, Teppei Yamada, Takaumi Kimura, Kosuke Namiki, Masaki Murata, Hiroshi Nishihara, and Shoichi Tachimori
pp 6977 - 6979; DOI:
10.1021/ic034816n
PDF
(NaLa2)NaPtO6: The First 2H-Perovskite Related Oxide with a Rare Earth Cation on the A-Site
Matthew J. Davis, Mark D. Smith, and Hans-Conrad zur Loye
pp 6980 - 6982; DOI:
10.1021/ic034679u
PDF
Nanoparticles of Prussian Blue Ferritin: A New Route for Obtaining Nanomaterials
José M. Domínguez-Vera and Enrique Colacio
pp 6983 - 6985; DOI:
10.1021/ic034783b
PDF
Density Functional Calculations on the Binding of Dinitrogen to the FeFe Cofactor in Fe-Only Nitrogenase: FeFeco(6-N2) as Intermediate in Nitrogen Fixation
Zexing Cao, Zhaohui Zhou, Huilin Wan, Qianer Zhang, and Walter Thiel
pp 6986 - 6988; DOI:
10.1021/ic034714x
PDF
Exploration of Composition Space in Templated Uranium Sulfates
Michael B. Doran, Alexander J. Norquist, and Dermot O'Hare
pp 6989 - 6995; DOI:
10.1021/ic034540j
PDF
77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8
A. Goldbach, F. Fayon, T. Vosegaard, M. Wachhold, M. G. Kanatzidis, D. Massiot, and M.-L. Saboungi
pp 6996 - 7000; DOI:
10.1021/ic030074m
PDF
A New Family of Spin Crossover Complexes with a Tripod Ligand Containing Three Imidazoles: Synthesis, Characterization, and Magnetic Properties of [FeIIH3LMe](NO3)2·1.5H2O, [FeIIILMe]·3.5H2O, [FeIIH3LMe][FeIILMe]NO3, and [FeIIH3LMe][FeIIILMe](NO3)2 (H3LMe = Tris[2-(((2-methylimidazol-4-yl)methylidene)amino)ethyl]amine)
Yuichi Ikuta, Makoto Ooidemizu, Yuichi Yamahata, Masahiro Yamada, Shutaro Osa, Naohide Matsumoto, Seiichiro Iijima, Yukinari Sunatsuki, Masaaki Kojima, Françoise Dahan, and Jean-Pierre Tuchagues
pp 7001 - 7017; DOI:
10.1021/ic034495f
PDF
Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four [fac-Re(CO)3(bpy)]+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB)
Heiko Hartmann, Wolfgang Kaim, Matthias Wanner, Axel Klein, Stéphanie Frantz, Carole Duboc-Toia, Jan Fiedler, and Stanislav Záli
pp 7018 - 7025; DOI:
10.1021/ic034232l
PDF
A Solid-State Spectral Effect in Eclipsed Tetracyanonickelates: X-ray Crystal Structure, Polarized Specular Reflectance Spectroscopy, and ZINDO Modeling of Sr[Ni(CN)4]·5H2O, Rb2[Ni(CN)4]·H2O, and Na2[Ni(CN)4]·3H2O
Frank R. Fronczek, Terry J. Delord, Steven F. Watkins, Petia Gueorguieva, George G. Stanley, Annegret S. Zizza, Jeffrey B. Cornelius, Yves A. Mantz, and Ronald L. Musselman
pp 7026 - 7036; DOI:
10.1021/ic0345222
PDF
Novel Acetate Binding Modes in [Na2Cu(CH3COO)4(H2O)]·H2O
Andrew C. Warden, Milton T. W. Hearn, and Leone Spiccia
pp 7037 - 7040; DOI:
10.1021/ic034517y
PDF
Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)
Lauren A. Borkowski and Christopher L. Cahill
pp 7041 - 7045; DOI:
10.1021/ic030196e
PDF
Cobalt Phosphonates: An Unusual Polymeric Cobalt Phosphonate Containing a Clathrated Phosphonate Anion and a Layered Bisphosphonate
Ekaterina V. Bakhmutova, Xiang Ouyang, Dmitri G. Medvedev, and Abraham Clearfield
pp 7046 - 7051; DOI:
10.1021/ic0301425
PDF
Crystal Structures and Magnetic Properties of Two Octacyanotungstate(IV) and (V)-Cobalt(II) Three-Dimensional Bimetallic Frameworks
Juan Manuel Herrera, Anne Bleuzen, Yves Dromzée, Miguel Julve, Francesc Lloret, and Michel Verdaguer
pp 7052 - 7059; DOI:
10.1021/ic034188+
PDF
The Structure of Magnesium Alanate
Maximilian Fichtner, Jens Engel, Olaf Fuhr, Andreas Glöss, Oliver Rubner, and Reinhart Ahlrichs
pp 7060 - 7066; DOI:
10.1021/ic034160y
PDF
Heptanuclear and Decanuclear Manganese Complexes with the Anion of 2-Hydroxymethylpyridine
Nicholas C. Harden, Milissa A. Bolcar, Wolfgang Wernsdorfer, Khalil A. Abboud, William E. Streib, and George Christou
pp 7067 - 7076; DOI:
10.1021/ic0348906
PDF
PtII Diimine Chromophores with Perfluorinated Thiolate Ligands: Nature and Dynamics of the Charge-Transfer-to-Diimine Lowest Excited State
Julia A. Weinstein, Alexander J. Blake, E. Stephen Davies, Adrienne L. Davis, Michael W. George, David C. Grills, Igor V. Lileev, Alexander M. Maksimov, Pavel Matousek, Mikhail Ya. Mel'nikov, Anthony W. Parker, Vyacheslav E. Platonov, Michael Towrie, Claire Wilson, and Natalia N. Zheligovskaya
pp 7077 - 7085; DOI:
10.1021/ic026286l
PDF
Electroswitchable Photoluminescence Activity: Synthesis, Spectroscopy, Electrochemistry, Photophysics, and X-ray Crystal and Electronic Structures of [Re(bpy)(CO)3(CC-C6H4-CC)Fe(C5Me5)(dppe)][PF6]n (n = 0, 1)
Keith Man-Chung Wong, Sally Chan-Fung Lam, Chi-Chiu Ko, Nianyong Zhu, Vivian Wing-Wah Yam,, Séverine Roué, Claude Lapinte,, Sofiane Fathallah, Karine Costuas, Samia Kahlal, and Jean-François Halet
pp 7086 - 7097; DOI:
10.1021/ic030226d
PDF
The First Coordination Complexes of Selenones: A Structural Comparison with Complexes of Sulfones
Evgeny V. Dikarev, Renee Y. Becker, Eric Block, Zhixing Shan, R. Curtis Haltiwanger, and Marina A. Petrukhina
pp 7098 - 7105; DOI:
10.1021/ic0302130
PDF
Structural Studies on the Stepwise Chelating Processes of Bidentate 2-(Aminomethyl)pyridine and Tridentate Bis(2-pyridylmethyl)amine toward an Acetate-Bridged Dirhodium(II) Center
Takashi Yoshimura, Keisuke Umakoshi, and Yoichi Sasaki
pp 7106 - 7115; DOI:
10.1021/ic030093w
PDF
Fluorination of [Os3(CO)12] and [Ir4(CO)12]
In-Chul Hwang and Konrad Seppelt
pp 7116 - 7122; DOI:
10.1021/ic034611e
PDF
Crystal Structure and Spectroscopic Characterization of K8(VO)2O(SO4)6
Sren B. Rasmussen, Rikke Mattsson Rasmussen, Rasmus Fehrmann, and Kurt Nielsen
pp 7123 - 7128; DOI:
10.1021/ic0301674
PDF
Structural Changes, P-P Bond Energies, and Homolytic Dissociation Enthalpies of Substituted Diphosphines from Quantum Mechanical Calculations
Konstantin B. Borisenko and David W. H. Rankin
pp 7129 - 7136; DOI:
10.1021/ic034606a
PDF
Electrochemistry of Niobium(V) in Sulfuric and Methanesulfonic Acids: Formation of the Nb3O2(SO4)6(H2O)35- Cluster and Designed Electrochemical Generation of "Nb3O2" Core Clusters by Double Potential Pulse Electrolysis
Michael May, Melissa Gantt, Caroline Hoadley, Thomas Batten, William Sayers, and Vladimir Katovic
pp 7137 - 7147; DOI:
10.1021/ic030145h
PDF
Microwave-Assisted Polyol Synthesis of CuInTe2 and CuInSe2 Nanoparticles
Haviv Grisaru, Oleg Palchik, Aharon Gedanken, Valery Palchik, Michael A. Slifkin, and Arie M. Weiss
pp 7148 - 7155; DOI:
10.1021/ic0342853
PDF
Reduction of the Allylic Substituents in NiI(1,8-dipropenyl-1,4,8,11-tetraazacyclotetradecane)+ by the Central Ni(I) in Aqueous Solutions
Hava Raznoshik, Israel Zilberman, Eric Maimon, Arkady Ellern, Haim Cohen, and Dan Meyerstein
pp 7156 - 7161; DOI:
10.1021/ic034284a
PDF
How Strong Can the Bend Be on a DNA Helix from Cisplatin? DFT and MP2 Quantum Chemical Calculations of Cisplatin-Bridged DNA Purine Bases
Jaroslav V. Burda and Jerzy Leszczynski
pp 7162 - 7172; DOI:
10.1021/ic034296w
PDF
Novel ET-Coordinated Copper(I) Complexes: Syntheses, Structures, and Physical Properties (ET = BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene)
Ryo Kanehama, Masamichi Umemiya, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken-ichi Sugiura, Masahiro Yamashita, Yasukata Yokochi, Hiroshi Ito, Shin-ichi Kuroda, Hideo Kishida, and Hiroshi Okamoto
pp 7173 - 7181; DOI:
10.1021/ic0344362
PDF
Bis(pyrazol-1-yl)acetates as Tripodal Heteroscorpionate Ligands in Iron Chemistry: Syntheses and Structures of Iron(II) and Iron(III) Complexes with bpza, bdmpza, and bdtbpza Ligands
Alexander Beck, Alexander Barth, Eike Hübner, and Nicolai Burzlaff
pp 7182 - 7188; DOI:
10.1021/ic034097c
PDF
Mixed-Spin Binuclear Nickel(II) Complexes in Unsymmetrical Ligand Environments and Related Mononuclear Compounds: Electronic and Molecular Structures in Solution and in the Solid State
Dipesh Ghosh, Suman Mukhopadhyay, Satyabrata Samanta, Ki-Young Choi, Akira Endo, and Muktimoy Chaudhury
pp 7189 - 7199; DOI:
10.1021/ic034314+
PDF
Tropochemical Cell-Twinning in the New Quaternary Bismuth Selenides KxSn6-2xBi2+xSe9 and KSn5Bi5Se13
Antje Mrotzek and Mercouri G. Kanatzidis
pp 7200 - 7206; DOI:
10.1021/ic034252n
PDF
Comparison of M-S, M-O, and M-(2-SO) Structures and Bond Dissociation Energies in d6 (CO)5M(SO2)nq Complexes Using Density Functional Theory
Heather J. Retzer and Thomas M. Gilbert
pp 7207 - 7218; DOI:
10.1021/ic030179p
PDF
Reactions of Palladium Germylene Complexes: Formation of Sulfide Bridges
Zuzanna T. Cygan, Jeff W. Kampf, and Mark M. Banaszak Holl
pp 7219 - 7226; DOI:
10.1021/ic034613z
PDF
Diphosphines Possessing Electronically Different Donor Groups: Synthesis and Coordination Chemistry of the Unsymmetrical Di(N-pyrrolyl)phosphino-Functionalized dppm Analogue Ph2PCH2P(NC4H4)2
Andrew D. Burrows, Mary F. Mahon, Steven P. Nolan, and Maurizio Varrone
pp 7227 - 7238; DOI:
10.1021/ic034487z
PDF
Facile Ni(II)/Ketoxime-Mediated Conversion of Organonitriles into Imidoylamidine Ligands. Synthesis of Imidoylamidines and Acetyl Amides
Maximilian N. Kopylovich, Armando J. L. Pombeiro, Andreas Fischer, Lars Kloo, and Vadim Yu. Kukushkin
pp 7239 - 7248; DOI:
10.1021/ic0349813
PDF
Kinetic Stability of the Peroxidase Activity of Unfolded Cytochrome c: Heme Degradation and Catalyst Inactivation by Hydrogen Peroxide
Rutger E. M. Diederix, Maria Fittipaldi, Jonathan A. R. Worrall, Martina Huber, Marcellus Ubbink, and Gerard W. Canters
pp 7249 - 7257; DOI:
10.1021/ic0343861
PDF
CrIII(salen)Cl Catalyzed Asymmetric Epoxidations: Insight into the Catalytic Cycle
Konstantin P. Bryliakov and Evgenii P. Talsi
pp 7258 - 7265; DOI:
10.1021/ic034578w
PDF
Reactivity of Dioxoosmium(VI) Porphyrins toward Arylhydrazine. Isolation of Hydrazidoosmium and Amidoosmium Porphyrins
Sarana Ka-Yan Leung, Jie-Sheng Huang, Nianyong Zhu, and Chi-Ming Che
pp 7266 - 7272; DOI:
10.1021/ic034389d
PDF
Volatile -Ketoiminato- and -Diketiminato-Based Zirconium Complexes as Potential MOCVD Precursors
Pier Luigi Franceschini, Marcus Morstein, Heinz Berke, and Helmut W. Schmalle
pp 7273 - 7282; DOI:
10.1021/ic034328f
PDF
Crystal Structures of Rubidium and Cesium Anthranilates and Salicylates
Frank Wiesbrock and Hubert Schmidbaur
pp 7283 - 7289; DOI:
10.1021/ic034427t
PDF
Unusual Coordination Assemblies from Platinum(II) Thienyl and Bithienyl Complexes
Peili Teo, L. L. Koh, and T. S. Andy Hor
pp 7290 - 7296; DOI:
10.1021/ic034690u
PDF
Trifluoromethyl Chlorosulfonate, CF3OSO2Cl: Gas Phase and Crystal Structure, Conformation and Vibrational Analysis Studied by Experimental and Theoretical Methods
Mauricio F. Erben, Carlos O. Della Védova, Roland Boese, Helge Willner, Christiane Leibold, and Heinz Oberhammer
pp 7297 - 7303; DOI:
10.1021/ic034531a
PDF
Novel Mixed-Valence Heteropolyoxometalates: A Molybdenum Diphosphonate Anion [MoV7MoVIO16(O3PPhPO3H)4]3- and Its One- and Two-Dimensional Assemblies
Nathalie Calin and Slavi C. Sevov
pp 7304 - 7308; DOI:
10.1021/ic034505c
PDF
Structure and Properties of a Novel 3D Straight-Channel Polyoxovanadate and an Unexpected Trimeric Barbiturate Obtained by Hydrothermal Reactions
Wenbin Yang, Canzhong Lu, Quanzheng Zhang, Shumei Chen, Xiaoping Zhan, and Jiuhui Liu
pp 7309 - 7314; DOI:
10.1021/ic034554p
PDF
Synthesis, Structure, and Magnetoresistance of SmPd2Ga2
Willa M. Williams, Robin T. Macaluso, M. Moldovan, D. P. Young, and Julia Y. Chan
pp 7315 - 7318; DOI:
10.1021/ic034660r
PDF
MASb2- (M = Zr, Hf; A = Si, Ge): A New Series of Ternary Antimonides and Not "-ZrSb2"
Navid Soheilnia, Abdeljalil Assoud, and Holger Kleinke
pp 7319 - 7325; DOI:
10.1021/ic0347440
PDF
Organometallic Chemistry of Azuliporphyrins: Synthesis, Spectroscopy, Electrochemistry, and Structural Characterization of Nickel(II), Palladium(II), and Platinum(II) Complexes of Azuliporphyrins
Timothy D. Lash, Denise A. Colby, Shelley R. Graham, Gregory M. Ferrence, and Lisa F. Szczepura
pp 7326 - 7338; DOI:
10.1021/ic030166b
PDF

Issue 23


High-Pressure Combinatorial Screening of Homogeneous Catalysts: Hydrogenation of Carbon Dioxide
Chih-Cheng Tai, Tangel Chang, Brentin Roller, and Philip G. Jessop
pp 7340 - 7341; DOI:
10.1021/ic034881x
PDF
Hydrothermal Synthesis and Structure of a New Helical Chain Constructed from Only Molybdenum-Oxide Building Blocks
Lin Xu, Chao Qin, Xinlong Wang, Yongge Wei, and Enbo Wang
pp 7342 - 7344; DOI:
10.1021/ic034331z
PDF
Synthesis, Characterization, and Autoreduction of a Highly Electron-Deficient Porphycenatoiron(III) with Trifluoromethyl Substituents
Takashi Hayashi, Yuji Nakashima, Kazuyuki Ito, Takahiro Ikegami, Isao Aritome, Katsuhiro Aoyagi, Tsutomu Ando, and Yoshio Hisaeda
pp 7345 - 7347; DOI:
10.1021/ic034757d
PDF
Remarkable Paramagnetically Shifted 1H and 2H NMR Spectra of Iron(II) Complexes of 2-Aza-21-carbaporphyrin: An Evidence for Agostic Interaction
Krystyna Rachlewicz, Sian-Ling Wang, Chih-Hsiung Peng, Chen-Hsiung Hung, and Lechosaw Latos-Grayski
pp 7348 - 7350; DOI:
10.1021/ic034886u
PDF
Excited State Interfacial Electron Transfer from a Compound with a Single Pyridine Ligand
Feng Liu and Gerald J. Meyer
pp 7351 - 7353; DOI:
10.1021/ic034857j
PDF
Copper(I) Complexes of a Heavily Fluorinated -Diketiminate Ligand: Synthesis, Electronic Properties, and Intramolecular Aerobic Hydroxylation
David S. Laitar, Casey J. N. Mathison, William M. Davis, and Joseph P. Sadighi
pp 7354 - 7356; DOI:
10.1021/ic035056j
PDF
Turning Off Phototriggered Linkage Isomerizations in Ruthenium Dimethyl Sulfoxide Complexes
Jeffrey J. Rack, Aaron A. Rachford, and Amy M. Shelker
pp 7357 - 7359; DOI:
10.1021/ic034918d
PDF
Direct Observation of the Luminescence from the 3* Excited State of Re2Cl2(p-OCH3form)4
Patricia M. Bradley, Laura T. Smith, Judith L. Eglin, and Claudia Turro
pp 7360 - 7362; DOI:
10.1021/ic034513t
PDF
A Ruthenium Nitrosyl That Rapidly Delivers NO to Proteins in Aqueous Solution upon Short Exposure to UV Light
Apurba K. Patra and Pradip K. Mascharak
pp 7363 - 7365; DOI:
10.1021/ic030110h
PDF
The Crystal Structure of a Novel Copper(II) Complex with Asymmetric Ligand Derived from L-Histidine
Patrick Deschamps, Prasad P. Kulkarni, and Bibudhendra Sarkar
pp 7366 - 7368; DOI:
10.1021/ic034760x
PDF
The First Example of a Seven-Coordinate Vanadium(III) Thiolate Complex Containing the Hydrazine Molecule, an Intermediate of Nitrogen Fixation
Hua-Fen Hsu, Wei-Cheng Chu, Chen-Hsiung Hung, and Ju-Hsiou Liao
pp 7369 - 7371; DOI:
10.1021/ic034992w
PDF
Crystal Structure of Thiogermanic Acid H4Ge4S10
Steven A. Poling, Carly R. Nelson, Jacob T. Sutherland, and Steve W. Martin
pp 7372 - 7374; DOI:
10.1021/ic034659s
PDF
Photoluminescence and Raman Studies of Curium and Americium Complexes of 6-Methyl 2-(2-Pyridyl)-benzimidazole: Evidence for an Efficient Intramolecular Energy Transfer
Zerihun Assefa, T. Yaita, R. G. Haire, and S. Tachimori
pp 7375 - 7377; DOI:
10.1021/ic034759y
PDF
An Unprecedented Oxidative Migration of a Methyl Group from 2-(2',6'-Dimethylphenylazo)-4-methylphenol Mediated by Ruthenium and Osmium
Rama Acharyya, Shie-Ming Peng, Gene-Hsiang Lee, and Samaresh Bhattacharya
pp 7378 - 7380; DOI:
10.1021/ic034968i
PDF
Speciation of Ternary Cobalt(II) Phenanthroline-Silica Surface Complexes as a Function of pH and Ligand Steric Bulk
Colleen M. Taylor, Stephen P. Watton, Alexander Flurie, and Jennifer I. Ricketts
pp 7381 - 7386; DOI:
10.1021/ic034082e
PDF
A Series of Dinuclear Homo- and Heterometallic Complexes with Two or Three Bridging Sulfido Ligands Derived from the Tungsten Tris(sulfido) Complex [Et4N][(Me2Tp)WS3] (Me2Tp = Hydridotris(3,5-dimethylpyrazol-1-yl)borate)
Hidetake Seino, Naohisa Iwata, Noriko Kawarai, Masanobu Hidai, and Yasushi Mizobe
pp 7387 - 7395; DOI:
10.1021/ic030164r
PDF
Hydrothermal Syntheses, Crystal Structures, and Magnetic Properties of Inorganic-Organic Hybrid Vanadium Selenites with Zero- to Three-Dimensional Structures: (1,10-Phenanthroline)2V2SeO7, (2,2'-Bipyridine)VSeO4, (4,4'-Bipyridine)V2Se2O8, and (4,4'-Bipyridine)2V4Se3O15·H2O
Zhimin Dai, Zhan Shi, Guanghua Li, Dong Zhang, Wensheng Fu, Haiying Jin, Wei Xu, and Shouhua Feng
pp 7396 - 7402; DOI:
10.1021/ic030165j
PDF
Reactivity of 2-Pyridinecarboxylic Esters with Cadmium(II) Halides: Study of 113Cd NMR Solid State Spectra and Crystal Structures of Hexacoordinated Complexes [CdI2(C5H4NCOOMe)2] and [CdI2(C5H4NCOOPrn)2]
Ricard March, Josefina Pons, Josep Ros, William Clegg, Angel Álvarez-Larena, Joan Francesc Piniella, and Jesus Sanz
pp 7403 - 7409; DOI:
10.1021/ic0206387
PDF
Vanadium(IV) and Vanadium(V) Complexes of Salicyladimine Ligands
Kathryn I. Smith, Londa L. Borer, and Marilyn M. Olmstead
pp 7410 - 7415; DOI:
10.1021/ic034640p
PDF
Bridged Tetraquaternary Salts from N,N'-Polyfluoroalkyl-4,4'-bipyridine
Rajendra P. Singh and Jean'ne M. Shreeve
pp 7416 - 7421; DOI:
10.1021/ic034812i
PDF
Adjusting the Frameworks of Silver(I) Complexes with New Pyridyl Thioethers by Varying the Chain Lengths of Ligand Spacers, Solvents, and Counteranions
Xian-He Bu, Ya-Bo Xie, Jian-Rong Li, and Ruo-Hua Zhang
pp 7422 - 7430; DOI:
10.1021/ic034454j
PDF
Synthesis and Characterization of Bis(S-acetylthio)-Derivatized Europium Triple-Decker Monomers and Oligomers
Karl-Heinz Schweikart, Vladimir L. Malinovskii, Amir A. Yasseri, Junzhong Li, Andrey B. Lysenko, David F. Bocian, and Jonathan S. Lindsey
pp 7431 - 7446; DOI:
10.1021/ic034730u
PDF
Coordination Complexes of 1-(4-[N-tert-Butyl-N-aminoxyl]phenyl)-1H-1,2,4-triazole with Paramagnetic Transition Metal Dications
Lora M. Field and Paul M. Lahti
pp 7447 - 7454; DOI:
10.1021/ic0349050
PDF
Metal Complexes of the trans-Influencing Ligand Thiomaltol
Jana A. Lewis, David T. Puerta, and Seth M. Cohen
pp 7455 - 7459; DOI:
10.1021/ic0347135
PDF
Solid State Coordination Chemistry of Oxomolybdenum Organoarsonate Materials
Eric Burkholder, Suzanne Wright, Vladimir Golub, Charles J. O'Connor, and Jon Zubieta
pp 7460 - 7471; DOI:
10.1021/ic030171f
PDF
First Row Divalent Transition Metal Complexes of Aryl-Appended Tris((pyridyl)methyl)amine Ligands: Syntheses, Structures, Electrochemistry, and Hydroxamate Binding Properties
Magdalena M. Makowska-Grzyska, Ewa Szajna, Crystal Shipley, Atta M. Arif, Michael H. Mitchell, Jason A. Halfen, and Lisa M. Berreau
pp 7472 - 7488; DOI:
10.1021/ic034810y
PDF
Syntheses, Spectroscopy, and Redox Chemistry of Encapsulated Oxo-Mo(V) Centers: Implications for Pyranopterin-Containing Molybdoenzymes
Partha Basu, Victor N. Nemykin, and Raghvendra S. Sengar
pp 7489 - 7501; DOI:
10.1021/ic034821r
PDF
Synthesis and Photophysics of One Mononuclear Mn(III) and One Dinuclear Mn(III,III) Complex Covalently Linked to a Ruthenium(II) Tris(bipyridyl) Complex
Anh Johansson, Malin Abrahamsson, Ann Magnuson, Ping Huang, Jerker Mårtensson, Stenbjörn Styring, Leif Hammarström, Licheng Sun, and Björn Åkermark
pp 7502 - 7511; DOI:
10.1021/ic0344822
PDF
Novel Silver-Containing Supramolecular Frameworks Constructed by Combination of Coordination Bonds and Supramolecular Interactions
Daofeng Sun, Rong Cao, Yanqiong Sun, Wenhua Bi, Xiaoju Li, Yanqin Wang, Qian Shi, and Xing Li
pp 7512 - 7518; DOI:
10.1021/ic034568v
PDF
Role of Carboxylate Bridges in Modulating Nonheme Diiron(II)/O2 Reactivity
Miquel Costas, Clyde W. Cady, Sergey V. Kryatov, Manabendra Ray, Meghan J. Ryan, Elena V. Rybak-Akimova, and Lawrence Que, Jr.
pp 7519 - 7530; DOI:
10.1021/ic034359a
PDF
A Porous Supramolecular Architecture from a Copper(II) Coordination Polymer with a 3D Four-Connected 86 Net
Jian-Fang Ma, Jin Yang, Guo-Li Zheng, Li Li, and Jing-Fu Liu
pp 7531 - 7534; DOI:
10.1021/ic034846q
PDF
Preparation of the First Examples of Ansa-Spiro Substituted Fluorophosphazenes and Their Structural Studies: Analysis of C-H···F-P Weak Interactions in Substituted Fluorophosphazenes
K. Muralidharan and Anil J. Elias
pp 7535 - 7543; DOI:
10.1021/ic034712c
PDF
Bulk Spontaneous Magnetization in the New Radical Cation Salt TM-TTF[Cr(NCS)4(isoquinoline)2] (TM-TTF = Tetramethyltetrathiafulvalene)
M. Mas-Torrent, S. S. Turner, K. Wurst, J. Vidal-Gancedo, X. Ribas, J. Veciana, P. Day, and C. Rovira
pp 7544 - 7549; DOI:
10.1021/ic034379c
PDF
Comparison of Thioethers and Sulfoxides as Axial Ligands for N-Acetylmicroperoxidase-8: Implications for Oxidation of Methionine-80 in Cytochrome c
Gerald H. Lushington, Aaron B. Cowley, Svetlana Silchenko, Gudrun S. Lukat-Rodgers, Kenton R. Rodgers, and David R. Benson
pp 7550 - 7559; DOI:
10.1021/ic034689v
PDF
Hydrolytic Metal-Mediated Coupling of Dialkylcyanamides at a Pt(IV) Center Giving a New Family of Diimino Ligands
Nadezhda A. Bokach, Tatyana B. Pakhomova, Vadim Yu. Kukushkin, Matti Haukka, and Armando J. L. Pombeiro
pp 7560 - 7568; DOI:
10.1021/ic034800x
PDF
Organometallic Aluminum Compounds Derived from 2-(1,3,5-Dithiazinan-5-yl)ethanol Ligands1
Juan Carlos Gálvez-Ruiz, Henrich Nöth, and Angelina Flores-Parra
pp 7569 - 7578; DOI:
10.1021/ic034642+
PDF
Ruthenium(II) Sulfoxide-Maltolato and -Nitroimidazole Complexes: Synthesis and MTT Assay
Adam Wu, David C. Kennedy, Brian O. Patrick, and Brian R. James
pp 7579 - 7586; DOI:
10.1021/ic030119j
PDF
Terphenyl Cyclooctatetraenyl Compounds of Samarium
Gerd W. Rabe, Mei Zhang-Presse, Florian A. Riederer, James A. Golen, Christopher D. Incarvito, and Arnold L. Rheingold
pp 7587 - 7592; DOI:
10.1021/ic0301775
PDF
Experimental and Theoretical Electron Density Distribution and Magnetic Properties of the Butterfly-like Complex [Fe4O2(O2CCMe3)8(NC5H4Me)2]·2CH3CN
Jacob Overgaard, David E. Hibbs, Eva Rentschler, Grigore A. Timco, and Finn K. Larsen
pp 7593 - 7601; DOI:
10.1021/ic034062c
PDF
Chemistry of Constrained Dioxocyclam Ligands with Co(III): Unusual Examples of C-H and C-N Bond Cleavage
Chuanjiang Hu, Robert M. Chin, Thoi D. Nguyen, Khoi T. Nguyen, Paul S. Wagenknecht, and Lawrence C. Nathan
pp 7602 - 7607; DOI:
10.1021/ic0302027
PDF
Atom Transfer as a Preparative Tool in Coordination Chemistry. Synthesis and Characterization of Cr(V) Nitrido Complexes of Bidentate Ligands
Torben Birk and Jesper Bendix
pp 7608 - 7615; DOI:
10.1021/ic034777f
PDF
Molecular Metamagnet [Ni(4ImNNH)2(NO3)2] (4ImNNH = 4-Imidazolyl Nitronyl Nitroxide) and the Related Compounds Showing Supramolecular H-Bonding Interactions
Chigusa Aoki, Takayuki Ishida, and Takashi Nogami
pp 7616 - 7625; DOI:
10.1021/ic0349048
PDF
Tetraphosphinitoresorcinarene Complexes: Dynamic Clusters with Silver(I) and Copper(I) Halides
Dana J. Eisler, Christopher W. Kirby, and Richard J. Puddephatt
pp 7626 - 7634; DOI:
10.1021/ic034717+
PDF
Synthesis and Properties of Rhenium Carbonyl Complexes of ,'-Bis[(1-pyrenyl)pyrazol-1-yl]alkane Ligands
Daniel L. Reger, James R. Gardinier, Perry J. Pellechia, Mark D. Smith, and Kenneth J. Brown
pp 7635 - 7643; DOI:
10.1021/ic034631g
PDF
Synthesis of [Ag(NH=CMe2)2]ClO4 and Its Use as a Source of Acetimine. 1. Synthesis of the First Acetimine Rhodium Complexes and the First Crystal Structure of a Diacetonamine Complex
José Vicente, María-Teresa Chicote, Rita Guerrero, Inmaculada Vicente-Hernández, and Peter G. Jones
pp 7644 - 7651; DOI:
10.1021/ic035002+
PDF
Two Novel Vanadium Tellurites Covalently Bonded with Metal-Organic Complex Moieties: M(phen)V2TeO8 (M = Cu, Ni)
Dongrong Xiao, Yangguang Li, Enbo Wang, Shutao Wang, Yu Hou, Gejihu De, and Changwen Hu
pp 7652 - 7657; DOI:
10.1021/ic034272p
PDF
Heterotrimetallic 4f-3d Coordination Polymers: Synthesis, Crystal Structure, and Magnetic Properties
Hui-Zhong Kou, Bei Chuan Zhou, and Ru-Ji Wang
pp 7658 - 7665; DOI:
10.1021/ic0348502
PDF
Coordination of 2,2'-Bipyridyl and 1,10-Phenanthroline to Yttrium and Lanthanum Complexes Based on a Scorpionate Ligand
Dmitrii Roitershtein, Ângela Domingos, Laura C. J. Pereira, José R. Ascenso, and Noémia Marques
pp 7666 - 7673; DOI:
10.1021/ic034838+
PDF
Optical Resolution and the Study of Ligand Effects on the Ortho-Metalation Reaction of Resolved (±)-Diphenyl[1-(1-naphthyl)ethyl]phosphine and Its Arsenic Analogue
Joseph Kok-Peng Ng, Geok-Kheng Tan, Jagadese J. Vittal, and Pak-Hing Leung
pp 7674 - 7682; DOI:
10.1021/ic0302276
PDF
A Family of Diruthenium Compounds with Dianionic Tridentate Ligands of N-(2-Pyridyl)-2-oxy-5-R-benzylaminate (R = H, Me, Cl, Br, NO2): Isolation, Structure Determination, and Electrochemistry
Hitoshi Miyasaka, Toru Izawa, Ken-ichi Sugiura, and Masahiro Yamashita
pp 7683 - 7690; DOI:
10.1021/ic034625k
PDF

Issue 24


Carrier Doping Effect into Quasi-One-Dimensional Bromo-Bridged Ni(III) Complexes with Strong Electron-Correlation by Cu(II) Ions, [Ni1-xCux(chxn)2Br]Br2-x
Masahiro Yamashita, Takashi Ono, Satoshi Matsunaga, Mari Sasaki, Shinya Takaishi, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken-ichi Sugiura, Hideo Kishida, Hiroshi Okamoto, Hisaaki Tanaka, Yasuhisa Hasegawa, Kazuhiro Marumoto, Hiroshi Ito, Sin-ichi Kuroda, and Noriyoshi Kimura
pp 7692 - 7694; DOI:
10.1021/ic0349555
PDF
Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex
Sarah L. Chatwin, Richard A. Diggle, Rodolphe F. R. Jazzar, Stuart A. Macgregor, Mary F. Mahon, and Michael K. Whittlesey
pp 7695 - 7697; DOI:
10.1021/ic030241i
PDF
An Accurately-Constructed Structural Model for an Active Site of Fe-Containing Superoxide Dismutases (Fe-SODs)
Syuhei Yamaguchi, Akinori Kumagai, Yasuhiro Funahashi, Koichiro Jitsukawa, and Hideki Masuda
pp 7698 - 7700; DOI:
10.1021/ic034962t
PDF
The First Solvent-Free Cyclotrimerization Reaction of Arylethynes Catalyzed by Rhodium Porphyrins
Pietro Tagliatesta, Barbara Floris, Pierluca Galloni, Alessandro Leoni, and Giuseppe D'Arcangelo
pp 7701 - 7703; DOI:
10.1021/ic0351390
PDF
Observation of 3MC Emission in a Mixed 1,10-Phenanthroline Complex of Ruthenium(II) Having a RuIIN6 Core at Room Temperature in Solution
Derek A. Tocher, Pankaj K. Pal, and Dipankar Datta
pp 7704 - 7706; DOI:
10.1021/ic034603y
PDF
A Novel Coordination Mode for Pentalene in Trinuclear Chromium Complexes
Simon C. Jones, Tony Hascall, Alexander J. Norquist, and Dermot O'Hare
pp 7707 - 7709; DOI:
10.1021/ic0350887
PDF
Homochiral Zn and Cd Coordination Polymers Containing Amino Acid-Tetrazole Ligands
Zhi-Rong Qu, Hong Zhao, Xi-Sen Wang, Yong-Hua Li, Yu-Mei Song, Yu-juan Liu, Qiong Ye, Ren-Gen Xiong, Brendan F. Abrahams, Zi-Ling Xue, and Xiao-Zeng You
pp 7710 - 7712; DOI:
10.1021/ic034685q
PDF
A New Facile Route for the Preparation of Single-Source Precursors for Bulk, Thin-Film, and Nanocrystallite I-III-VI Semiconductors
Kulbinder K. Banger, Michael H.-C. Jin, Jerry D. Harris, Philip E. Fanwick, and Aloysius F. Hepp
pp 7713 - 7715; DOI:
10.1021/ic034802h
PDF
The Diammoniates of Dipotassiumtetraethinylozincate and -cadmate: K2M(C2H)4·2NH3 (M = Zn, Cd)
Ulrich Cremer, Ingo Pantenburg, and Uwe Ruschewitz
pp 7716 - 7718; DOI:
10.1021/ic034629p
PDF
A Robust Microporous Zinc Porphyrin Framework Solid
Dennis W. Smithenry, Scott R. Wilson, and Kenneth S. Suslick
pp 7719 - 7721; DOI:
10.1021/ic034873g
PDF
Three Topological Isomeric Coordination Polymer Networks from the Assembly of a Rigid Linear Spacer and a Square Planar Metal Node: Structures, Isomerism Control, and Solid-to-Solid Transformation
Dong Mok Shin, In Su Lee, Dahye Cho, and Young Keun Chung
pp 7722 - 7724; DOI:
10.1021/ic035111o
PDF
The Rearrangement of Dicarboranyl Methyl Cation: A Possible Synthetic Strategy Toward Cationic closo-Tricarbaboranes
Eluvathingal D. Jemmis and Elambalassery G. Jayasree
pp 7725 - 7727; DOI:
10.1021/ic035178b
PDF
Construction of a Novel Copper(I) Chain Polymer of Hexanuclear Cu6(2-SC5H4NH)6I6 Cores with A New (3-S) Mode of Bonding of Pyridine-2-thione and of an Unusual Triangular Cu3I3(dppe)3(2-SC5H4NH) Cluster
Tarlok S. Lobana, Ritu Sharma, Elena Bermejo, and Alfonso Castineiras
pp 7728 - 7730; DOI:
10.1021/ic034770y
PDF
Preparation and Precise Structural Determination of a Second Ga84 Cluster Compound. A First Hint for Cluster Doping and Its Fundamental Consequences in the Field of Chemistry and Physics of Nanoscaled Metalloid Cluster Material
Andreas Schnepf, Bettina Jee, Hansgeorg Schnöckel, Edgar Weckert, Alke Meents, Daniel Lübbert, Erik Herrling, and Bernd Pilawa
pp 7731 - 7733; DOI:
10.1021/ic035031k
PDF
On the Nature of the Bonding in 1:1 Adducts of O2
Dimitrios A. Pantazis and John E. McGrady
pp 7734 - 7736; DOI:
10.1021/ic034867k
PDF
Cooperativity between Metal Ions in the Cleavage of Phosphate Diesters and RNA by Dinuclear Zn(II) Catalysts
Olga Iranzo, Terry Elmer, John P. Richard, and Janet R. Morrow
pp 7737 - 7746; DOI:
10.1021/ic030131b
PDF
AVNb3Cl11 (A = K, Rb, Cs, Tl): A Series of Layered Vanadium Niobium Halides Based on Triangular Nb3 Clusters
Thirumalai Duraisamy and Abdessadek Lachgar
pp 7747 - 7751; DOI:
10.1021/ic0341439
PDF
Enolphosphato-Phosphines: A New Class of P,O Ligands
Xavier Morise, Pierre Braunstein, and Richard Welter
pp 7752 - 7765; DOI:
10.1021/ic030032y
PDF
Small Cluster Models of the Surface Electronic Structure and Bonding Properties of Titanium Carbide, Vanadium Carbide, and Titanium Nitride
Stephen V. Didziulis, Kristine D. Butcher, and Scott S. Perry
pp 7766 - 7781; DOI:
10.1021/ic030140k
PDF
Structure and Bonding of Sr3In11: How Size and Electronic Effects Determine Structural Stability of Polar Intermetallic Compounds
Shahrad Amerioun and Ulrich Häussermann
pp 7782 - 7788; DOI:
10.1021/ic0301829
PDF
Multimetallic Ruthenium(II) Complexes as Electrochemiluminescent Labels
Mara Staffilani, Eva Höss, Ulla Giesen, Erich Schneider, Frantiek Hartl, Hans-Peter Josel, and Luisa De Cola
pp 7789 - 7798; DOI:
10.1021/ic034435+
PDF
Synthesis, Structure, and Catalytic Activity of Mononuclear Iron and (-Oxo)diiron Complexes with the Ligand 2,6-Bis(N-methylbenzimidazol-2-yl)pyridine
Ximeng Wang, Shuangxi Wang, Lijuan Li, Eric B. Sundberg, and Gian Paola Gacho
pp 7799 - 7808; DOI:
10.1021/ic0259437
PDF
Synthesis and Structural Characterization of Double Metal Cyanides of Iron and Zinc: Catalyst Precursors for the Copolymerization of Carbon Dioxide and Epoxides
Donald J. Darensbourg, M. Jason Adams, Jason C. Yarbrough, and Andrea L. Phelps
pp 7809 - 7818; DOI:
10.1021/ic0347900
PDF
Methanolysis and Phenolysis Routes to Fe6, Fe8, and Fe10 Complexes and Their Magnetic Properties: A New Type of Fe8 Ferric Wheel
Cristina Cañada-Vilalta, Ted A. O'Brien, Maren Pink, Ernest R. Davidson, and George Christou
pp 7819 - 7829; DOI:
10.1021/ic034706g
PDF
Structure and Physical Properties of 1D Magnetic Chalcogenide, Jamesonite (FePb4Sb6S14)
Yoshitaka Matsushita and Yutaka Ueda
pp 7830 - 7838; DOI:
10.1021/ic034634t
PDF
Vanadium(V) Complexes of a Chelating Dianionic [ONNO]-Type Amine Bis(Phenolate) Ligand: Synthesis and Solid State and Solution Structures
Fabien Wolff, Christian Lorber, Robert Choukroun, and Bruno Donnadieu
pp 7839 - 7845; DOI:
10.1021/ic034742f
PDF
Templated Synthesis of the Novel Layered Silver-Antimony Sulfides [H3NCH2CH2NH2][Ag2SbS3] and [H3NCH2CH2NH2]2[Ag5Sb3S8]
Paz Vaqueiro, Ann M Chippindale, Andrew R Cowley, and Anthony V Powell
pp 7846 - 7851; DOI:
10.1021/ic034926u
PDF
Time-Dependent Density Functional Theory Study of the Spectroscopic Properties Related to Aggregation in the Platinum(II) Biphenyl Dicarbonyl Complex
Stanislav R. Stoyanov, John M. Villegas, and D. Paul Rillema
pp 7852 - 7860; DOI:
10.1021/ic030084n
PDF
Complexes of Platinum(II) Containing Neutral and Deprotonated 9-Methyladenine. Synthesis, X-ray Structures, and NMR Studies on the Cyclic Trimer cis-[L2Pt{9-MeAd(-H)}]3(NO3)3 and the Dinuclear cis-[L2Pt(ONO2){9-MeAd(-H)}PtL2](NO3)2 (L = PMePh2)
Bruno Longato, Lucia Pasquato, Adele Mucci, Luisa Schenetti, and Ennio Zangrando
pp 7861 - 7871; DOI:
10.1021/ic034406z
PDF
Self-Assembled Silver Polyhedra with Embedded Acetylide Dianion Stabilized by Perfluorocarboxylate and 4-Hydroxyquinoline Ligands
Xiao-Li Zhao, Quan-Ming Wang, and Thomas C. W. Mak
pp 7872 - 7876; DOI:
10.1021/ic034595l
PDF
Nucleophilic Reactivity and Oxo/Sulfido Substitution Reactions of MVIO3 Groups (M = Mo, W)
David V. Partyka, Richard J. Staples, and R. H. Holm
pp 7877 - 7886; DOI:
10.1021/ic030185l
PDF
Mono- and Dinuclear Ruthenium Carbonyl Complexes with Redox-Active Dioxolene Ligands: Electrochemical and Spectroscopic Studies and the Properties of the Mixed-Valence Complexes
Andrew P. Meacham, Kathryn L. Druce, Zöe R. Bell, Michael D. Ward, Jerome B. Keister, and A. B. P. Lever
pp 7887 - 7896; DOI:
10.1021/ic034579o
PDF
Photophysical and Novel Charge-Transfer Properties of Adducts between [RuII(bpy)3]2+ and [S2Mo18O62]4-
Tia E. Keyes, Etienne Gicquel, Liz Guerin, Robert J. Forster, Victoria Hultgren, Alan M. Bond, and Anthony G. Wedd
pp 7897 - 7905; DOI:
10.1021/ic0206802
PDF
The Cation-Deficient Ruddlesden-Popper Oxysulfide Y2Ti2O5S2 as a Layered Sulfide: Topotactic Potassium Intercalation To Form KY2Ti2O5S2
Oliver J. Rutt, Timothy L. Hill, Zoltán A. Gál, Michael A. Hayward, and Simon J. Clarke
pp 7906 - 7911; DOI:
10.1021/ic0301730
PDF
Geometry-Dependent Phosphodiester Hydrolysis Catalyzed by Binuclear Copper Complexes
Lei Zhu, Osvaldo dos Santos, Chi Wan Koo, Marc Rybstein, Louise Pape, and James W. Canary
pp 7912 - 7920; DOI:
10.1021/ic0340985
PDF
Panchromatic Sensitization of Nanocrystalline TiO2 with cis-Bis(4-carboxy-2-[2'-(4'-carboxypyridyl)]quinoline)bis(thiocyanato-N)ruthenium(II)
Masatoshi Yanagida, Takeshi Yamaguchi, Mitsuhiko Kurashige, Kohjiro Hara, Ryuzi Katoh, Hideki Sugihara, and Hironori Arakawa
pp 7921 - 7931; DOI:
10.1021/ic034674x
PDF
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)amine Ligands: Chirality Effects on Lanthanide Complexation and Luminescence Properties
Takashi Yamada, Satoshi Shinoda, Hideki Sugimoto, Jun-ichi Uenishi, and Hiroshi Tsukube
pp 7932 - 7937; DOI:
10.1021/ic020726r
PDF
Nucleophile Assistance of Electron-Transfer Reactions between Nitrogen Dioxide and Chlorine Dioxide Concurrent with the Nitrogen Dioxide Disproportionation
Robert H. Becker, Jeffrey S. Nicoson, and Dale W. Margerum
pp 7938 - 7944; DOI:
10.1021/ic0347891
PDF
A Stable Monomeric Nickel Borohydride
Patrick J. Desrochers, Stacey LeLievre, Rosemary J. Johnson, Brian T. Lamb, Andrea L. Phelps, A. W. Cordes, Weiwei Gu, and Stephen P. Cramer
pp 7945 - 7950; DOI:
10.1021/ic034687a
PDF
Synthesis and Characterization of Volatile, Thermally Stable, Reactive Transition Metal Amidinates
Booyong S. Lim, Antti Rahtu, Jin-Seong Park, and Roy G. Gordon
pp 7951 - 7958; DOI:
10.1021/ic0345424
PDF
RE2MAl6Si4 (RE = Gd, Tb, Dy; M = Au, Pt): Layered Quaternary Intermetallics Featuring CaAl2Si2-Type and YNiAl4Ge2-Type Slabs Grown from Aluminum Flux
Susan E. Latturner, Daniel Bilc, S. D. Mahanti, and Mercouri G. Kanatzidis
pp 7959 - 7966; DOI:
10.1021/ic0346432
PDF
Kinetics and Mechanistic Studies of Anticarcinogenic Bisperoxovanadium(V) Compounds: Ligand Substitution Reactions at Physiological pH and Relevance to DNA Interactions
Jung H. Hwang, Rhonda K. Larson, and Mahdi M. Abu-Omar
pp 7967 - 7977; DOI:
10.1021/ic0350180
PDF
Solid-State and Solution Properties of Cationic Lanthanide Complexes of a New Neutral Heptadentate N4O3 Tripodal Ligand
Florence Bravard, Yann Bretonnière, Raphaël Wietzke, Christelle Gateau, Marinella Mazzanti, Pascale Delangle, and Jacques Pécaut
pp 7978 - 7989; DOI:
10.1021/ic034692e
PDF
Why Is BCl3 a Stronger Lewis Acid with Respect to Strong Bases than BF3?
Fabienne Bessac and Gernot Frenking
pp 7990 - 7994; DOI:
10.1021/ic034141o
PDF
Solvent-Dependent Dynamics of the MQReII Excited-State Electron Transfer in [Re(MQ+)(CO)3(dmb)]2+
Davina J. Liard, Cornelis J. Kleverlaan, and Antonín Vlek, Jr.
pp 7995 - 8002; DOI:
10.1021/ic0346376
PDF
Reactivity at the -Diketiminate Ligand Nacnac- on Titanium(IV) (Nacnac- = [Ar]NC(CH3)CHC(CH3)N[Ar], Ar = 2,6-[CH(CH3)2]2C6H3). Diimine-alkoxo and Bis-anilido Ligands Stemming from the Nacnac- Skeleton
Falguni Basuli, John C. Huffman, and Daniel J. Mindiola
pp 8003 - 8010; DOI:
10.1021/ic034853e
PDF
Kinetics and Mechanism of the Oxidation of Alkylaromatic Compounds by a trans-Dioxoruthenium(VI) Complex
William W. Y. Lam, Shek-Man Yiu, Douglas T. Y. Yiu, Tai-Chu Lau, Wing-Ping Yip, and Chi-Ming Che
pp 8011 - 8018; DOI:
10.1021/ic034782j
PDF
Cationic Mn12 Single-Molecule Magnets and Their Polyoxometalate Hybrid Salts
Alicia Forment-Aliaga, Eugenio Coronado, Marta Feliz, Alejandro Gaita-Ariño, Rosa Llusar, and Francisco M. Romero
pp 8019 - 8027; DOI:
10.1021/ic034407r
PDF
Synthesis and Structure of a Water-Soluble Hexanuclear Silver(I) Nicotinate Cluster Comprised of a "Cyclohexane-Chair"-Type of Framework, Showing Effective Antibacterial and Antifungal Activities: Use of "Sparse Matrix" Techniques for Growing Crystals of Water-Soluble Inorganic Complexes
Irina Tsyba, Becky Bun-kit Mui, Robert Bau, Ryusuke Noguchi, and Kenji Nomiya
pp 8028 - 8032; DOI:
10.1021/ic030149m
PDF
Comments on the Electrostatic Minimum Potential (Vmin) as a Measure of the Electron-Donating Power of PZ3
Warren P. Giering, Alfred Prock, and Anthony L. Fernandez
pp 8033 - 8037; DOI:
10.1021/ic034223c
PDF
Study of Ruthenium(II) Complexes with Anticancer Drugs as Ligands. Design of Metal-Based Phototherapeutic Agents
Renzo Cini, Gabriella Tamasi, Sandra Defazio, Maddalena Corsini, Piero Zanello, Luigi Messori, Giordana Marcon, Francesca Piccioli, and Pierluigi Orioli
pp 8038 - 8052; DOI:
10.1021/ic0349095
PDF
Synthesis, Crystal Structure, and Photochromism of Novel Two-Dimensional Supramolecular Networks Based on Keggin-Type Polyoxoanion and Lanthanide Coordination Cations
Hong Zhang, Liying Duan, Yang Lan, Enbo Wang, and Changwen Hu
pp 8053 - 8058; DOI:
10.1021/ic0343962
PDF
Complexes of Guanidinium Ion (NH2)3C+ with Super Lewis Acidic XH4+ (X = B and Al): Comparison with XH3 Complexes and Protonated and Methylated Guanidinium Dications1
Golam Rasul, George A. Olah, and G. K. Surya Prakash
pp 8059 - 8064; DOI:
10.1021/ic030143x
PDF
Crystal and Molecular Structure and Magnetic Exchange Properties of Bis(di--ethoxo-bis(3,5-di-tert-butylsemiquinonato)dicopper(II)) Complex. A Synergy between DFT and Experimental Magnetochemistry
Alessandro Bencini, Andrea Dei, Claudio Sangregorio, Federico Totti, and Maria G. F. Vaz
pp 8065 - 8071; DOI:
10.1021/ic034447v
PDF
Structural and Magnetic Properties of Carboxylato-Bridged Manganese(II) Complexes Involving Tetradentate Ligands: Discrete Complex and 1D Polymers. Dependence of J on the Nature of the Carboxylato Bridge
Stéphanie Durot, Clotilde Policar, Giorgio Pelosi, Franco Bisceglie, Talal Mallah, and Jean-Pierre Mahy
pp 8072 - 8080; DOI:
10.1021/ic026130l
PDF
Formation of Crystalline Stibnite Bundles of Rods by Thermolysis of an Antimony(III) Diethyldithiocarbamate Complex in Ethylene Glycol
Changhua An, Kaibin Tang, Qing Yang, and Yitai Qian
pp 8081 - 8086; DOI:
10.1021/ic034534n
PDF
Structures and Redox Reactivities of Copper Complexes of (2-Pyridyl)alkylamine Ligands. Effects of the Alkyl Linker Chain Length
Takao Osako, Yoshiki Ueno, Yoshimitsu Tachi, and Shinobu Itoh
pp 8087 - 8097; DOI:
10.1021/ic034958h
PDF
Europium Luminescence of EF-Hand Helix-Turn-Helix Chimeras: Impact of pH and DNA-Binding on Europium Coordination
Sandhya Jain, Joel T. Welch, William D. Horrocks, Jr., and Sonya J. Franklin
pp 8098 - 8104; DOI:
10.1021/ic034736j
PDF
Selected-Control Synthesis of ZnO Nanowires and Nanorods via a PEG-Assisted Route
Zhengquan Li, Yujie Xiong, and Yi Xie
pp 8105 - 8109; DOI:
10.1021/ic034029q
PDF
Catalytic Asymmetric Sulfoxidation by Chiral Manganese Complexes: Acetylacetonate Anions as Chirality Switches
Sébastien Schoumacker, Olivier Hamelin, and Jacques Pécaut
pp 8110 - 8116; DOI:
10.1021/ic0346533
PDF
What Makes an N12 Cage Stable?
Lana Y. Bruney, Telia M. Bledson, and Douglas L. Strout
pp 8117 - 8120; DOI:
10.1021/ic034696j
PDF

Issue 25


A Non-Radical Chain Mechanism for Oxygen Atom Transfer with a Thiorhenium(V) Catalyst
Katalin Ösz and James H. Espenson
pp 8122 - 8124; DOI:
10.1021/ic034933i
PDF
Ni(III) Complex of an N-Confused Porphyrin Inner C-Oxide
Ziwei Xiao, Brian O. Patrick, and David Dolphin
pp 8125 - 8127; DOI:
10.1021/ic020701s
PDF
Energy Density Distribution in Bridged Cobalt Complexes
Markus Finger and Joachim Reinhold
pp 8128 - 8130; DOI:
10.1021/ic035011i
PDF
A Ditopic Azacryptate Proton Cage
Paula Morehouse, Md. Alamgir Hossain, José M. Llinares, Douglas Powell, and Kristin Bowman-James
pp 8131 - 8133; DOI:
10.1021/ic034972u
PDF
A Novel Hybrid of Bi-Based High-Tc Superconductor and Molecular Complex
Soon-Jae Kwon and Jin-Ho Choy
pp 8134 - 8136; DOI:
10.1021/ic034755t
PDF
Synthesis of Open and Closed Metallacages Using Novel Tripodal Ligands: Unusually Stable Silver(I) Inclusion Compound
Daniel L. Reger, Radu F. Semeniuc, and Mark D. Smith
pp 8137 - 8139; DOI:
10.1021/ic035192o
PDF
The Remarkable Reactivity of High Oxidation State Ruthenium and Osmium Polypyridyl Complexes
Thomas J. Meyer and My Hang V. Huynh
pp 8140 - 8160; DOI:
10.1021/ic020731v
PDF
Unusual Geometries and Questions of Oxidation State in Potential Sn(III) Chemistry
Pradeep Gutta and Roald Hoffmann
pp 8161 - 8170; DOI:
10.1021/ic034493v
PDF
A New Class of Oxo-Bridged High-Valent Hexamanganese Clusters Supported by Sterically Hindered Carboxylate Ligands
Sumitra Mukhopadhyay, Bhavesh A. Gandhi, Martin L. Kirk, and William H. Armstrong
pp 8171 - 8180; DOI:
10.1021/ic034641h
PDF
Octalkoxy-Substituted Phosphorus(V) Triazatetrabenzcorroles via Ring Contraction of Phthalocyanine Precursors
Joseph P. Fox and David P. Goldberg
pp 8181 - 8191; DOI:
10.1021/ic034792k
PDF
Tetraphosphinitoresorcinarene Complexes: Cationic Silver(I) and Copper(I) Halide Complexes as Mercurate(II) Anion Receptors
Dana J. Eisler and Richard J. Puddephatt
pp 8192 - 8202; DOI:
10.1021/ic034822j
PDF
[Mn2(saltmen)2Ni(pao)2(L)2](A)2 with L = Pyridine, 4-Picoline, 4-tert-Butylpyridine, N-Methylimidazole and A = ClO4-, BF4-, PF6-, ReO4-: A Family of Single-Chain Magnets
Hitoshi Miyasaka, Rodolphe Clérac, Kaori Mizushima, Ken-ichi Sugiura, Masahiro Yamashita, Wolfgang Wernsdorfer, and Claude Coulon
pp 8203 - 8213; DOI:
10.1021/ic034872o
PDF
Cobalt(II) Dioxygen Carriers Based on Simple Diamino Ligands: Kinetic and ab Initio Studies
Clara Comuzzi, Andrea Melchior, Pierluigi Polese, Roberto Portanova, and Marilena Tolazzi
pp 8214 - 8222; DOI:
10.1021/ic034798+
PDF
"Nanoscale Zippers" in Gd5(SixGe1-x)4: Symmetry and Chemical Influences on the Nanoscale Zipping Action
Wonyoung Choe, A. O. Pecharsky, Michael Wörle, and Gordon J. Miller
pp 8223 - 8229; DOI:
10.1021/ic034941z
PDF
Synthesis and Mesogenic Properties of Binuclear Copper(II) Complexes Derived from Salicylaldimine Schiff Bases
Reinhard Paschke, Stefan Liebsch, Carsten Tschierske, Michael A. Oakley, and Ekkehard Sinn
pp 8230 - 8240; DOI:
10.1021/ic0301021
PDF
One Metal and Forty Nitrogens. Ab Initio Predictions for Possible New High-Energy Pentazolides
Michal Straka and Pekka Pyykkö
pp 8241 - 8249; DOI:
10.1021/ic034702b
PDF
Coexistence of Water Dimer and Hexamer Clusters in 3D Metal-Organic Framework Structures of Ce(III) and Pr(III) with Pyridine-2,6-dicarboxylic Acid
Sujit K. Ghosh and Parimal K. Bharadwaj
pp 8250 - 8254; DOI:
10.1021/ic034976z
PDF
Synthesis and Structure of Polymeric Networks of Silver Hexafluoroacetylacetonate Complexes of THF, Toluene, and Vinyltrimethylsilane
William J. Evans, Dimitrios G. Giarikos, Daniel Josell, and Joseph W. Ziller
pp 8255 - 8261; DOI:
10.1021/ic034649r
PDF
The Pacman Effect: A Supramolecular Strategy for Controlling the Excited-State Dynamics of Pillared Cofacial Bisporphyrins
Christopher J. Chang, Zhi-Heng Loh, Yongqi Deng, and Daniel G. Nocera
pp 8262 - 8269; DOI:
10.1021/ic034750w
PDF
Transient Absorption Studies of the Pacman Effect in Spring-Loaded Diiron(III) -Oxo Bisporphyrins
Justin M. Hodgkiss, Christopher J. Chang, Bradford J. Pistorio, and Daniel G. Nocera
pp 8270 - 8277; DOI:
10.1021/ic034751o
PDF
Electron Deficiency in Tetrahedral Transition-Metal Clusters: Electronic Structure and Magnetic Properties of [Ru4(6-C6H6)4(3-H)4]2+
Régis Gautier, Frédéric Chérioux, Georg Süss-Fink, and Jean-Yves Saillard
pp 8278 - 8282; DOI:
10.1021/ic030053s
PDF
Novel Iron(III) Complexes of Tripodal and Linear Tetradentate Bis(phenolate) Ligands: Close Relevance to Intradiol-Cleaving Catechol Dioxygenases
Marappan Velusamy, Mallayan Palaniandavar, R. Srinivasa Gopalan, and G. U. Kulkarni
pp 8283 - 8293; DOI:
10.1021/ic020569w
PDF
Self-Assembly of a Mixed-Ligand Metal-Coordination Polymeric Network of Cadmium(II) Croconate with 4,4'-Bipyridine
Chih-Chieh Wang, Cheng-Han Yang, Shih-Min Tseng, Gene-Hsiang Lee, Yung-Ping Chiang, and Hwo-Shuenn Sheu
pp 8294 - 8299; DOI:
10.1021/ic0301876
PDF
Magnetic Property Studies of Manganese-Phosphate Complexes
C. V. Krishnamohan Sharma, Charles C. Chusuei, Rodolphe Clérac, Teresia Möller, Kim R. Dunbar, and Abraham Clearfield
pp 8300 - 8308; DOI:
10.1021/ic0300520
PDF
Solvent Effects on the Electrochemistry and Spectroelectrochemistry of Diruthenium Complexes. Studies of Ru2(L)4Cl Where L = 2-CH3ap, 2-Fap, and 2,4,6-F3ap, and ap Is the 2-Anilinopyridinate Anion
Karl M. Kadish, Li-Lun Wang, Antoine Thuriere, Lingamallu Giribabu, Rachel Garcia, Eric Van Caemelbecke, and John L. Bear
pp 8309 - 8319; DOI:
10.1021/ic034722d
PDF
A Novel Layered Niobium Oxychloride Compound Based on Nb2 Pairs and Nb6 Octahedral Clusters: Synthesis and Crystal and Electronic Structures of Nb10Cl16O7
Stéphane Cordier, Fakhili Gulo, Thierry Roisnel, Régis Gautier, Boris le Guennic, Jean François Halet, and Christiane Perrin
pp 8320 - 8327; DOI:
10.1021/ic0350990
PDF
Synthesis, Crystal Structure, Magnetic Properties, and Theoretical Studies of [{Cu(mepirizole)Br}2(-OH)(-pz)] (Mepirizole = 4-Methoxy-2-(5-methoxy-3-methyl-1H-pyrazol-1-yl)-6-methylpyrimidine; pz = Pyrazolate), a Novel -Pyrazolato--Hydroxo-Dibridged Copper(II) Complex
Emilio Escrivà, Julia García-Lozano, José Martínez-Lillo, Hugo Nuñez, Juan Server-Carrió, Lucía Soto, Rosa Carrasco, and Joan Cano
pp 8328 - 8336; DOI:
10.1021/ic034126j
PDF
Silver(I) Undecafluorodiantimonate(V)
Zoran Mazej and Primo Benki
pp 8337 - 8343; DOI:
10.1021/ic034616b
PDF
Attempted Syntheses of Lanthanide(III) Complexes of the Anisole- and Anilinosquarate Ligands
Patrice M. T. Piggot, Lincoln A. Hall, Andrew J. P. White, and David J. Williams
pp 8344 - 8352; DOI:
10.1021/ic034922p
PDF
Phosphate Diester Hydrolysis and DNA Damage Promoted by New cis-Aqua/Hydroxy Copper(II) Complexes Containing Tridentate Imidazole-rich Ligands
Marciela Scarpellini, Ademir Neves, Rosmari Hörner, Adailton J. Bortoluzzi, Bruno Szpoganics, César Zucco, René A. Nome Silva, Valderes Drago, Antônio S. Mangrich, Wilson A. Ortiz, Wagner A. C. Passos, Maurício C. B. de Oliveira, and Hernán Terenzi
pp 8353 - 8365; DOI:
10.1021/ic026277c
PDF
Chemistry of Cobalt Acetate. 7. Electrochemical Oxidation of 3-Oxo-Centered Cobalt(III) Acetate Trimers
James K. Beattie, Corina U. Beck, Peter A. Lay, and Anthony F. Masters
pp 8366 - 8370; DOI:
10.1021/ic0345525
PDF
A New Look at Bonding in Trialuminides: Reinvestigation of TaAl3
Cathie L. Condron, Gordon J. Miller, Joel D. Strand, Sergey L. Bud'ko, and Paul C. Canfield
pp 8371 - 8376; DOI:
10.1021/ic034927m
PDF
Enhancement of Luminescence Lifetimes of Mononuclear Ruthenium(II)-Terpyridine Complexes by Manipulation of the -Donor Strength of Ligands
Marco Duati, Stefania Tasca, Fiona C. Lynch, Holger Bohlen, Johannes G. Vos, Stefano Stagni, and Michael D. Ward
pp 8377 - 8384; DOI:
10.1021/ic034691m
PDF
Synthesis, Structure, and Acid-Base and Redox Properties of a Family of New Ru(II) Isomeric Complexes Containing the Trpy and the Dinucleating Hbpp Ligands
Cristina Sens, Montserrat Rodríguez, Isabel Romero, Antoni Llobet, Teodor Parella, and Jordi Benet-Buchholz
pp 8385 - 8394; DOI:
10.1021/ic0346836
PDF
Substituent Effects of -Diketiminate Ligands on the Structure and Physicochemical Properties of Copper(II) Complexes
Chizu Shimokawa, Seiji Yokota, Yoshimitsu Tachi, Nagatoshi Nishiwaki, Masahiro Ariga, and Shinobu Itoh
pp 8395 - 8405; DOI:
10.1021/ic0344766
PDF
Interlayer Interaction of Two-Dimensional Layered Spin Crossover Complexes [FeIIH3LMe][FeIILMe]X (X- = ClO4-, BF4-, PF6-, AsF6-, and SbF6-; H3LMe = Tris[2-(((2-methylimidazol-4-yl)methylidene)amino)ethyl]amine)
Masahiro Yamada, Makoto Ooidemizu, Yuichi Ikuta, Shutaro Osa, Naohide Matsumoto, Seiichiro Iijima, Masaaki Kojima, Françoise Dahan, and Jean-Pierre Tuchagues
pp 8406 - 8416; DOI:
10.1021/ic034439e
PDF
Bridging Fluorides and Hard/Soft Mismatch in d6 and d8 Complexes: The Case of [Tl(-F)3Ru(PPh3)3]
Claus Becker, Iris Kieltsch, Diego Broggini, and Antonio Mezzetti
pp 8417 - 8429; DOI:
10.1021/ic034888e
PDF
Luminescent Gold(I) and Silver(I) Complexes of 2-(Diphenylphosphino)-1-methylimidazole (dpim): Characterization of a Three-Coordinate Au(I)-Ag(I) Dimer with a Short Metal-Metal Separation
Vincent J. Catalano and Stephen J. Horner
pp 8430 - 8438; DOI:
10.1021/ic030200m
PDF
Equilibrium Studies in Solution Involving Nickel(II) Complexes of Flexidentate Schiff Base Ligands: Isolation and Structural Characterization of the Planar Red and Octahedral Green Species Involved in the Equilibrium
Suman Mukhopadhyay, Debdas Mandal, Dipesh Ghosh, Israel Goldberg, and Muktimoy Chaudhury
pp 8439 - 8445; DOI:
10.1021/ic0346174
PDF
Preparations of Pure ISeCN, ISCN, and INCO
Li Yimin, Qiao Zhimin, Sun Qiao, Zhao Jincai, Li Haiyang, and Wang Dianxun
pp 8446 - 8448; DOI:
10.1021/ic030158v
PDF
Theoretical Studies of the Complex [(BPMEN)Fe(II)(NCCH3)2]2+, Precursor of Non-Heme Iron Catalysts for Olefin Epoxidation and Cis-Dihydroxylation
David Quiñonero, Djamaladdin G. Musaev, and Keiji Morokuma
pp 8449 - 8455; DOI:
10.1021/ic0348392
PDF
Structural and Magnetic Properties of Three One-Dimensional Azido-Bridged Copper(II) and Manganese(II) Coordination Polymers
En-Qing Gao, Shi-Qiang Bai, Chuan-Feng Wang, Yan-Feng Yue, and Chun-Hua Yan
pp 8456 - 8464; DOI:
10.1021/ic034618w
PDF
New Dicationic Porphyrin Ligands Suited for Intercalation into B-Form DNA
Stephanie A. Bejune, Alexander H. Shelton, and David R. McMillin
pp 8465 - 8475; DOI:
10.1021/ic035092i
PDF
Lanthanide-Transition Metal Chalcogenido Cluster Materials
Anna Kornienko, Louise Huebner, Deborah Freedman, Thomas J. Emge, and John G. Brennan
pp 8476 - 8480; DOI:
10.1021/ic030204r
PDF
Interpolymetallic Assembly of d8-d10 Sulfide Aggregates from [Pt2(PPh3)4(-S)2] and Group 12 Metals
Zhaohui Li, Weiming Zheng, Huang Liu, K. F. Mok, and T. S. Andy Hor
pp 8481 - 8488; DOI:
10.1021/ic034884+
PDF
Interaction of Nitrogen Oxides with Sublimed Layers of (meso-Tetraphenylporphyrinato)cobalt(II); IR Evidence of Oxo-Transfer from (Nitro)porphyrinatocobalt(III) to Free Nitric Oxide
Tigran S. Kurtikyan, Arthur N. Mardyukov, and John A. Goodwin
pp 8489 - 8493; DOI:
10.1021/ic0347844
PDF
Increased Reactivity of the Cr(CO)3(C5Me5) Radical with Thiones versus Thiols: A Theoretical and Experimental Investigation
Kengkaj Sukcharoenphon, Damian Moran, Paul v. R. Schleyer, James E. McDonough, Khalil A. Abboud, and Carl D. Hoff
pp 8494 - 8503; DOI:
10.1021/ic034791s
PDF
High-Field, Multifrequency EPR Study of the [Mn(OH2)6]3+ Cation: Influence of -Bonding on the Ground State Zero-Field-Splitting Parameters
Philip L. W. Tregenna-Piggott, Hgni Weihe, and Anne-Laure Barra
pp 8504 - 8508; DOI:
10.1021/ic0347642
PDF
Reactivity of Ph2P(Se)CH2C6H4CH2P(Se)Ph2 with [M3(CO)12] (M = Ru or Fe). Synthesis and Characterization of the New Carbene Cluster [Ru3(3-Se)(3-H)(2-PPh2)(CO)6(2-CHC6H4CH2PPh2)]
Daniele Belletti, Claudia Graiff, Chiara Massera, Alex Minarelli, Giovanni Predieri, Antonio Tiripicchio, and Domenico Acquotti
pp 8509 - 8518; DOI:
10.1021/ic034887m
PDF
A New Type of Single-Helix Coordination Polymer with Mixed Ligands [M2(phen)2(e,a-cis-1,4-chdc)2(H2O)2]n (M = Co and Ni; phen = 1,10-phenanthroline; chdc = cyclohexanedicarboxylate)
Yanjuan Qi, Yonghui Wang, Changwen Hu, Minhua Cao, Li Mao, and Enbo Wang
pp 8519 - 8523; DOI:
10.1021/ic034796p
PDF
Low-Temperature Single-Crystal Raman and Neutron-Diffraction Study of the Hydrogenous Ammonium Copper(II) Tutton Salt and the Deuterated Analogue in the Metastable State
Christopher Dobe, Graham Carver, Hans-Beat Bürgi, Philip L. W. Tregenna-Piggott, Garry J. McIntyre, Maria A. Augustyniak-Jablokow, and Mark J. Riley
pp 8524 - 8533; DOI:
10.1021/ic0343511
PDF
Ligand Effect on Reversible Conversion between Copper(I) and Bis(-oxo)dicopper(III) Complex with a Sterically Hindered Tetradentate Tripodal Ligand and Monooxygenase Activity of Bis(-oxo)dicopper(III) Complex
Masayasu Mizuno, Hideki Hayashi, Shuhei Fujinami, Hideki Furutachi, Shigenori Nagatomo, Shigenori Otake, Kounosuke Uozumi, Masatatsu Suzuki, and Teizo Kitagawa
pp 8534 - 8544; DOI:
10.1021/ic0345166
PDF
Systematic Evaluation of Molecular Recognition Phenomena. 3. Selective Diphosphate Binding to Isomeric Hexaazamacrocyclic Ligands Containing Xylylic Spacers
Carmen Anda, Antoni Llobet, Arthur E. Martell, Bruno Donnadieu, and Teodor Parella
pp 8545 - 8550; DOI:
10.1021/ic034205v
PDF
Ligand Substitution in Cubic Clusters: Surprising Isolation of the Cocrystallization Products of Cu8(8-Se)[S2P(OEt)2]6 and Cu6[S2P(OEt)2]6
C. W. Liu, Chiu-Mine Hung, Bidyut Kumar Santra, Ju-Chun Wang, Hsien-Ming Kao, and Zhenyang Lin
pp 8551 - 8556; DOI:
10.1021/ic034621f
PDF
XAFS Studies of Anti-Inflammatory Dinuclear and Mononuclear Zn(II) Complexes of Indomethacin
Qingdi Zhou, Trevor W. Hambley, Brendan J. Kennedy, and Peter A. Lay
pp 8557 - 8566; DOI:
10.1021/ic034049s
PDF
Synthesis and Characterization of Transition-Metal Zintl Phases: Cs24Nb2In12As18 and Cs13Nb2In6As10 with Isolated Complex Anions
Franck Gascoin and Slavi C. Sevov
pp 8567 - 8571; DOI:
10.1021/ic034680t
PDF
Short-Range and Long-Range Magnetic Ordering in SrCuP2O7 and PbCuP2O7
Alexei A. Belik, Masaki Azuma, and Mikio Takano
pp 8572 - 8578; DOI:
10.1021/ic034825w
PDF
Dinuclear and Octanuclear Mn(II) Complexes with 2-C, 2-N(Pyrrolide), and -1:5-(Pyrrolide) Bridges: A Structural and Magnetic Study
Patrick Crewdson, Sandro Gambarotta, Glenn P. A. Yap, and Laurence K. Thompson
pp 8579 - 8584; DOI:
10.1021/ic0349205
PDF
Synthesis, Characterization, and Hydrolytic Behavior of Mixed-Ligand Diorganotin Esters, [R2Sn(O2CR')OSO2Me]2 (R = n-Pr, n-Bu; R' = C9H6N-2, 4-OMe-C9H5N-2, C9H6N-1)
Ravi Shankar, Mukesh Kumar, Raj K. Chadha, and Geeta Hundal
pp 8585 - 8591; DOI:
10.1021/ic035008z
PDF
Blue Dimetallic Complexes of Two Heavy Metal Ions CdII and HgII with an Extended Nitrogen Donor Ligand. Preparation, Spectral Characterization, and Crystallographic Studies
Srijit Das, Chen-Hsiung Hung, and Sreebrata Goswami
pp 8592 - 8597; DOI:
10.1021/ic034948g
PDF
Structure and Bonding in Solution of Dioxouranium(VI) Oxalate Complexes: Isomers and Intramolecular Ligand Exchange
ValĂ©rie Vallet, Henry Moll, Ulf Wahlgren, Zoltán Szabó, and Ingmar Grenthe
pp 8598 - 8598; DOI:
10.1021/ic035223f
PDF

Issue 26


Yttrium Polyoxometalates. Synthesis and Characterization of a Carbonate-Encapsulated Sandwich-Type Complex
Xikui Fang, Travis M. Anderson, Wade A. Neiwert, and Craig L. Hill
pp 8600 - 8602; DOI:
10.1021/ic0350842
PDF
An Adamantane-Based Coordination Framework with the First Observation of Discrete Metal Sulfonate Clusters
Dennis J. Hoffart, Adrien P. Côté, and George K. H. Shimizu
pp 8603 - 8605; DOI:
10.1021/ic0349398
PDF
Synthesis, Characterization, and Dioxygen Reactivity of Tetracarboxylate-Bridged Diiron(II) Complexes with Coordinated Substrates
Sungho Yoon and Stephen J. Lippard
pp 8606 - 8608; DOI:
10.1021/ic0350133
PDF
An Alternative Route to Highly Luminescent Platinum(II) Complexes: Cyclometalation with NCN-Coordinating Dipyridylbenzene Ligands
J. A. Gareth Williams, Andrew Beeby, E. Stephen Davies, Julia A. Weinstein, and Claire Wilson
pp 8609 - 8611; DOI:
10.1021/ic035083+
PDF
Blue Phosphors of Dinuclear and Mononuclear Copper(I) and Silver(I) Complexes of 3,5-Bis(trifluoromethyl)pyrazolate and the Related Bis(pyrazolyl)borate
Mohammad A. Omary, Manal A. Rawashdeh-Omary, Himashinie V. K. Diyabalanage, and H. V. Rasika Dias
pp 8612 - 8614; DOI:
10.1021/ic0347586
PDF
cis-{Pt(NH3)2(L)}2+/+ (L = Cl, H2O, NH3) Binding to Purines and CO: Does -Back-Donation Play a Role?
Mu-Hyun Baik, Richard A. Friesner, and Stephen J. Lippard
pp 8615 - 8617; DOI:
10.1021/ic035022b
PDF
Sequence Selective Hydrolysis of Linear DNA Using Conjugates of Zr(IV) Complexes and Peptide Nucleic Acids
Felix H. Zelder, Andriy A. Mokhir, and Roland Krämer
pp 8618 - 8620; DOI:
10.1021/ic034896v
PDF
Molybdenum Chalcogenobenzimidato Complexes: Radical Synthesis and Nitrile Extrusion via -EPh (E = S, Se, and Te) Elimination
Arjun Mendiratta, Christopher C. Cummins, Olga P. Kryatova, Elena V. Rybak-Akimova, James E. McDonough, and Carl D. Hoff
pp 8621 - 8623; DOI:
10.1021/ic035077d
PDF
La3+-Catalyzed Methanolysis of N-Aryl--lactams and Nitrocefin
Pedro J. Montoya-Pelaez, Graham T. T. Gibson, Alexei A. Neverov, and R. S. Brown
pp 8624 - 8632; DOI:
10.1021/ic0302736
PDF
A [2]Catenane Constructed around a Rhodium(III) Center Used as a Template
Pierre Mobian, Jean-Marc Kern, and Jean-Pierre Sauvage
pp 8633 - 8637; DOI:
10.1021/ic030181g
PDF
One-Dimensional CuBr42- Ion Array and CuBr3- Ion Chain Included in the Conducting Framework Composed of Bis(methylthio)tetrathiafulvalenothioquinone-1,3-dithiocarbonatodithiolemethide Molecules
Takuya Matsumoto, Yohsuke Kamada, Toyonari Sugimoto, Toshiji Tada, Satoru Noguchi, Hiroyuki Nakazumi, Takashi Kawakami, Kizashi Yamaguchi, and Motoo Shiro
pp 8638 - 8645; DOI:
10.1021/ic0300971
PDF
Structural Analysis of Nine-Coordinate Lanthanide Complexes: Steric Control of the Metal-Water Distance Across the Series
David Parker, Horst Puschmann, Andrei S. Batsanov, and Kanthi Senanayake
pp 8646 - 8651; DOI:
10.1021/ic030203z
PDF
Modeling the Syn Disposition of Nitrogen Donors at the Active Sites of Carboxylate-Bridged Diiron Enzymes. Enforcing Dinuclearity and Kinetic Stability with a 1,2-Diethynylbenzene-Based Ligand
Jane Kuzelka, Joshua R. Farrell, and Stephen J. Lippard
pp 8652 - 8662; DOI:
10.1021/ic034928e
PDF
Substituent and Isomer Effects on Structural, Spectroscopic, and Electrochemical Properties of Dirhodium(III,II) Complexes Containing Four Identical Unsymmetrical Bridging Ligands
Karl M. Kadish, Tuan D. Phan, Lingamallu Giribabu, Eric Van Caemelbecke, and John L. Bear
pp 8663 - 8673; DOI:
10.1021/ic034963l
PDF
2,6-Di(pyrimidin-4-yl)pyridine Ligands with Nitrogen-Containing Auxiliaries: The Formation of Functionalized Molecular Clefts upon Metal Coordination
J. Frantz Folmer-Andersen, Hassan Aït-Haddou, Vincent M. Lynch, and Eric V. Anslyn
pp 8674 - 8681; DOI:
10.1021/ic034823b
PDF
Structural Study on Highly Oxidized States of a Water Oxidation Complex [RuIII(bpy)2(H2O)]2(-O)4+ by Ruthenium K-Edge X-ray Absorption Fine Structure Spectroscopy
Kaoru Okamoto, Jun Miyawaki, Kensuke Nagai, Daiju Matsumura, Akihiro Nojima, Toshihiko Yokoyama, Hiroshi Kondoh, and Toshiaki Ohta
pp 8682 - 8689; DOI:
10.1021/ic034373n
PDF
Coordination Chemistry of a New Cofacial Binucleating Macropolycycle Derived from 1,4,7-Triazacyclononane
Lorenzo Tei, Massimiliano Arca, M. Carla Aragoni, Andrea Bencini, Alexander J. Blake, Claudia Caltagirone, Francesco A. Devillanova, Patrizia Fornasari, Alessandra Garau, Francesco Isaia, Vito Lippolis, Martin Schröder, Simon J. Teat, and Barbara Valtancoli
pp 8690 - 8701; DOI:
10.1021/ic0345065
PDF
Standard Absolute Entropy, , Values from Volume or Density. 1. Inorganic Materials
H. Donald Brooke Jenkins and Leslie Glasser
pp 8702 - 8708; DOI:
10.1021/ic030219p
PDF
Diastereoselectivity and Molecular Recognition in the Self-Assembly of Double-Stranded Dinuclear Metal Complexes of the Type [M2{(R*,S*)-tetraphos}2](PF6)2 (M = Ag and Au)
Christopher J. Blake, Vernon C. Cook, Max A. Keniry, Heather J. Kitto, A. David Rae, Gerhard F. Swiegers, Anthony C. Willis, Johann Zank, and S. Bruce Wild
pp 8709 - 8715; DOI:
10.1021/ic0348704
PDF
Crystal Structures and Magnetic Properties of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine (tppz)-Containing Copper(II) Complexes
José Carranza, Conor Brennan, Jorunn Sletten, Juan Modesto Clemente-Juan, Francesc Lloret, and Miguel Julve
pp 8716 - 8727; DOI:
10.1021/ic030244v
PDF
Thermal and Photo Control of the Linkage Isomerism of Bis(thiocyanato)(2,2'-bipyridine)platinum(II)
Shinobu Kishi and Masako Kato
pp 8728 - 8734; DOI:
10.1021/ic034524m
PDF
Trinuclear to Dinuclear: A Radii Dependence Lanthanide(III) Self-Assembly Coordination Behavior of an Amide-Type Tripodal Ligand
Xiaofeng Li, Weisheng Liu, Zhijun Guo, and Minyu Tan
pp 8735 - 8738; DOI:
10.1021/ic034268d
PDF
Dirhodium Formamidinate Compounds with Bidentate Nitrogen Chelating Ligands
Helen T. Chifotides, Kemal V. Catalan, and Kim R. Dunbar
pp 8739 - 8747; DOI:
10.1021/ic034737b
PDF
SrSn4: A Superconducting Stannide with Localized and Delocalized Bond Character
Stefan Hoffmann and Thomas F. Fässler
pp 8748 - 8754; DOI:
10.1021/ic0302128
PDF
Chemical Bonding Topology of Ternary Transition Metal-Centered Bismuth Cluster Halides: From Molecules to Metals
R. Bruce King
pp 8755 - 8761; DOI:
10.1021/ic030210n
PDF
A Study of the Phase Mg2Cu6Ga5, Isotypic with Mg2Zn11. A Route to an Icosahedral Quasicrystal Approximant
Qisheng Lin and John D. Corbett
pp 8762 - 8767; DOI:
10.1021/ic030191h
PDF
Synthesis and Characterization of the New Cluster Phase K39In80. Three K-In Compounds with Remarkably Specific and Transferable Cation Dispositions
Bin Li and John D. Corbett
pp 8768 - 8772; DOI:
10.1021/ic030201e
PDF
Reaction of Bare VO+ and FeO+ with Ammonia: A Theoretical Point of View
Sandro Chiodo, Olga Kondakova, Maria del Carmen Michelini, Nino Russo, and Emilia Sicilia
pp 8773 - 8782; DOI:
10.1021/ic0348650
PDF
Ground and Excited State Electronic Interactions in a Bis(phenanthroline) Copper(I) Complex Sandwiched between Two Fullerene Subunits
Yannick Rio, Gérald Enderlin, Cyril Bourgogne, Jean-François Nierengarten, Jean-Paul Gisselbrecht, Maurice Gross, Gianluca Accorsi, and Nicola Armaroli
pp 8783 - 8793; DOI:
10.1021/ic035146o
PDF
Solid-State Structure Dependence of the Molecular Distortion and Spectroscopic Properties of the Cu(I) Bis(2,9-dimethyl-1,10-phenanthroline) Ion
Andrey Yu. Kovalevsky, Milan Gembicky, Irina V. Novozhilova, and Philip Coppens
pp 8794 - 8802; DOI:
10.1021/ic0348805
PDF
Elucidation of a Sc(I) Complex by DFT Calculations and Reactivity Studies
Ana-Mirela Neculai, Christopher C. Cummins, Dante Neculai, Herbert W. Roesky, Gàbor Bunkòczi, Bernhardt Walfort, and Dietmar Stalke
pp 8803 - 8810; DOI:
10.1021/ic034947o
PDF
1H NMR Studies of Nickel(II) Complexes Bound to Oligonucleotides: A Novel Technique for Distinguishing the Binding Locations of Metal Complexes in DNA
Pratip K. Bhattacharya, Holly J. Lawson, and Jacqueline K. Barton
pp 8811 - 8817; DOI:
10.1021/ic0348291
PDF
Octahedral Niobium Chloride Clusters as Building Blocks of Templated Prussian Blue Framework Analogues
Bangbo Yan, Huajun Zhou, and Abdessadek Lachgar
pp 8818 - 8822; DOI:
10.1021/ic034514l
PDF
Mono-, Di-, and Tetranuclear Ruthenium(II) Complexes Containing 3-(Pyridin-2-yl)-as-triazino[5,6-f]1,10-phenanthroline: Synthesis, Characterization, and Electrochemical and Photophysical Properties
Hui Chao, Zhi-Ren Qiu, Li-Rong Cai, Hao Zhang, Xiao-Yuan Li, Kam-Sing Wong, and Liang-Nian Ji
pp 8823 - 8830; DOI:
10.1021/ic034769z
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Synthesis, Characterization, and X-ray Crystal Structure of In(DOTA-AA) (AA = p-Aminoanilide): A Model for 111In-Labeled DOTA-Biomolecule Conjugates
Shuang Liu, Zhengjie He, Wen-Yuan Hsieh, and Phillip E. Fanwick
pp 8831 - 8837; DOI:
10.1021/ic0349914
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Self-Assemblies of New Rigid Angular Ligands and Metal Centers toward the Rational Construction and Modification of Novel Coordination Polymer Networks
Dong Mok Shin, In Su Lee, and Young Keun Chung
pp 8838 - 8846; DOI:
10.1021/ic0345929
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Synthesis and Characterization of Ru2(DMBA)4X2 (X = CN, N3, N(CN)2, I): Controlling Structural, Redox, and Magnetic Properties with Axial Ligands
Wei-Zhong Chen and Tong Ren
pp 8847 - 8852; DOI:
10.1021/ic035106k
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Synthesis, Characterization, and Crystal Structure of the Pd(phen)(bdt) Complex. A DFT and TDDFT Study of Its Ground Electronic and Excited States Compared to Those of Analogous Complexes
Christodoulos Makedonas, Christiana A. Mitsopoulou, Fernando J. Lahoz, and Ana I. Balana
pp 8853 - 8865; DOI:
10.1021/ic034978j
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Syntheses, Solid-State Structures, and Solution Studies by VT 31P NMR of [Zn{Se2P(OEt)2}2] and [Zn2{Se2P(OiPr)2}4]
Bidyut Kumar Santra, Ben-Jie Liaw, Chiu-Mine Hung, C. W. Liu, and Ju-Chun Wang
pp 8866 - 8871; DOI:
10.1021/ic034845y
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A Chiral Alkyltris(pyrazolyl)borate Ligand: Synthesis of [(Ipc)B(pz)3Mn(CO)3] and [(Ipc)B(pz)3Ru(p-cymene)]PF6 (Ipc = Isopinocampheyl)
Philip J. Bailey, Pedro Pinho, and Simon Parsons
pp 8872 - 8877; DOI:
10.1021/ic035061n
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Complexes of Schiff Bases and Intermediates in the Copper-Catalyzed Oxidative Heterocyclization by Atmospheric Oxygen
Martin E. Bluhm, Michael Ciesielski, Helmar Görls, Olaf Walter, and Manfred Döring
pp 8878 - 8885; DOI:
10.1021/ic034773a
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Anion Control of the Self-Assembly of 2,3-Diarylpyrazines with Silver(I) Salts
Nate Schultheiss, Douglas R. Powell, and Eric Bosch
pp 8886 - 8890; DOI:
10.1021/ic034994g
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Gold(I) Phosphido Complexes: Synthesis, Structure, and Reactivity
Diana M. Stefanescu, Holming F. Yuen, David S. Glueck, James A. Golen, Lev N. Zakharov, Christopher D. Incarvito, and Arnold L. Rheingold
pp 8891 - 8901; DOI:
10.1021/ic035006e
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On the Origin of the Optical Activity in the d-d Transition Region of Tris-Bidentate Co(III) and Rh(III) Complexes
Francisco E. Jorge, Jochen Autschbach, and Tom Ziegler
pp 8902 - 8910; DOI:
10.1021/ic034997t
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